Excess enthalpies of mixing tetrahydrofuran and tetrahydropyran with some chloroalkanes at 26.9°C

Excess enthalpies of mixing H _m ^E of tetrahydrofuran and tetrahydropyran with trichloromethane, tetrachloromethane, 1,2-dichloroethane, 1,1,2-trichloroethane and 1,1,2,2-tetrachloroethane have been determined at 26.9°C and are found to be negative over the entire composition range for both sets of the ether mixtures. H _m ^E decreases in the sequence; dichloroethane > tetrachloromethane > trichloroethane > trichloromethane > tetrachloroethane. The results are explained on the basis of strong O...H-C and weak Cl...O specific interactions. Flory's theory has been used to correlate the experimental data with good agreement found between the theoretical and experimental values of H _m ^E .     

MITATT mode in DDR heterostructure Impatt

Large signal characterisation of double heterostructure DDR Impatt diode has been carried out in the millimeter-wave range considering the MITATT mode of operation. The structure of the device is p⁺-p₂-p₁-n₁-n₂-n⁺ where impact ionisation and tunneling takes place in the p₁-n₁ region. In this study we have considered two well-known heterostructures, e.g., InP/GaInAs/InP and InP/InGaAsP/InP and one nonconventional structure GaAs/InP/GaAs. The theoretical results of the performances of these devices as regards of output power, efficiency, and negative conductance revealed that the structures are quite promising as the source of power in the millimeter-wave range. The analysis may be used for other mm wave DDR heterostructure Impatts.     

Working group report: Flavor physics and model building

This is the report of flavor physics and model building working group at WHEPP-9. While activites in flavor physics have been mainly focused on B-physics, those in model building have been primarily devoted to neutrino physics. We present summary of working group discussions carried out during the workshop in the above fields, and also briefly review the progress made in some projects subsequently.     

Bianchi type-V model with a perfect fluid and A-term

A self-consistent system of gravitational field with a binary mixture of perfect fluid and dark energy given by a cosmological constant has been considered in Bianchi Type-V universe. The perfect fluid is chosen to be obeying either the equation of state p=γρ with γ ε |0,1| or a van der Waals equation of state. The role of A-term in the evolution of the Bianchi Type-V universe has been studied.     

Mössbauer hyperfine interactions in natural wolframites

Powdered samples of Indian Natural Wolframites, (Fe_xMn_1?x) WO₄ with x=0.95 to 0.41, obtained from seven different locations of two quartz-wolframite deposits of Degana and Sirohi in Rajasthan, have been investigated by Mössbauer spectroscopy down to 20K and magnetic susceptibility down to 77K. The Mössbauer spectra from 300K to 30K clearly indicate multiple sites which is at variance with the reported work. Below 50K a weak magnetic interaction with H_int～45Koe is observed. The spectra above transition temperature are resolved in three doublets and explained on the basis of reported crystal structure. The values of isomer shift, quadrupole splitting and magnetic hyperfine field have been attributed to high spin ferrous ions with octahedral symmetry. Relatively small value of Q.S. (～1.5 mm/sec. at 300K) indicate a strong contribution of the lattice term to the electric field gradient.     

A highly selective and sensitive thorium(IV) PVC membrane electrode based on a dithio-tetraaza macrocyclic compound.

A poly(vinyl chloride)-based membrane composed of dithio-tetraaza macrocyclic compound as a neutral carrier with sodium tetraphenylborate (NaTPB) as an anion excluder and nitrobenzene (NB) as plasticizer was prepared and investigated as a Th(IV)-selective electrode. The electrode exhibits a Nernstian slope of 14.2 +/- 0.3 mV per decade over a wide concentration range (1.0 x 10(-6) to 1.0 x 10(-1) M) with a detection limit of 8.0 x 10(-7) M between pH 3.5 and 9.5. The response time of the sensor is about 10 s and it can be used over a period of 5 months without any divergence in potential. The proposed membrane sensor revealed a good selectivity for Th(IV) over a wide variety of other metal ions and proved to be a better electrode in many respects than those reported in the literature. It was successfully applied as an electrode indicator as well as in the direct determination of thorium ions in standard and real samples.     

A high spin isomer in 153Eu

A search for new isomers of nanosecond lifetimes were carried out in ¹⁵³Eu via the ¹⁵⁰Nd(⁷Li,xnγ) reaction. The single particle angular momentum alignment and dynamical moment of inertia estimated from the experimental data indicate a configuration change at rotational energy ħω∼ 0.30 MeV. A decrease of B(E2) values is also observed at the same frequency. An isomeric level is identified at an excitation energy of 3100 keV (J^π=35/2⁻) which corresponds to this frequency. The lifetime of the level is found to be 8.6 ± 1.3 nanosecond. Received: 22 April 1997 / Revised version: 26 September 1997     

PIC simulation of effect of energy-dependent foil transparency in an axially-extracted vircator

We have performed two-dimensional, relativistic, electromagnetic, particle-in-cell simulations for an axially extracted vircator. With a copper foil anode, the output frequency of the vircator is found to be strongly dependent upon the variation of foil transparency with electron energy. Using an average transparency for all electron energies yields results that are markedly different from those obtained using the actual variation. However, the output power shows only mild sensitivity. Using the full energy-dependent form of the transparency, we get fairly good agreement with published experimental results. Increasing the energy resolution for the calculation of foil transparency increases the accuracy of calculation of the dominant frequency, although the frequency tends to saturate beyond a certain resolution. However, an increase in the resolution must necessarily be accompanied by an increase in the number of simulation particles, in order to limit statistical fluctuations to an acceptable level. A physical explanation has also been provided for these trends.     

Study of interactions of various ionic species with solvents toward the design of receptors

In earlier studies, the interactions of isolated ionic species with various solvents were investigated using ab initio calculations. The ionic species investigated included cations (proton, hydronium, ammonium, and metal cations) and anions (single electron, hydroxide, and halide anions). However in the present study, we investigate the interactions of these ionic species with the solvent in the presence of other competing ionic species. We also elaborate on how the information obtained from these extensive studies have been employed in designing and synthesizing various kinds of novel ionophores and receptors.