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51.
Excess enthalpies of mixing H
m
E
of tetrahydrofuran and tetrahydropyran with trichloromethane, tetrachloromethane, 1,2-dichloroethane, 1,1,2-trichloroethane and 1,1,2,2-tetrachloroethane have been determined at 26.9°C and are found to be negative over the entire composition range for both sets of the ether mixtures. H
m
E
decreases in the sequence; dichloroethane > tetrachloromethane > trichloroethane > trichloromethane > tetrachloroethane. The results are explained on the basis of strong O...H-C and weak Cl...O specific interactions. Flory's theory has been used to correlate the experimental data with good agreement found between the theoretical and experimental values of H
m
E
. 相似文献
52.
53.
R. U. Khan P. Chakrabarti B. B. Pal 《Applied Physics A: Materials Science & Processing》1987,42(4):303-309
Large signal characterisation of double heterostructure DDR Impatt diode has been carried out in the millimeter-wave range considering the MITATT mode of operation. The structure of the device is p+-p2-p1-n1-n2-n+ where impact ionisation and tunneling takes place in the p1-n1 region. In this study we have considered two well-known heterostructures, e.g., InP/GaInAs/InP and InP/InGaAsP/InP and one nonconventional structure GaAs/InP/GaAs. The theoretical results of the performances of these devices as regards of output power, efficiency, and negative conductance revealed that the structures are quite promising as the source of power in the millimeter-wave range. The analysis may be used for other mm wave DDR heterostructure Impatts. 相似文献
54.
M K Parida Nita Sinha B Adhikary B Allanach A Alok K S Babu B Brahmachari D Choudhury E J Chun P K Das A Ghosal D Hitlin W S Hou S Kumar H N Li E Ma S K Majee G Majumdar B Mishra G Mohanty S Nandi H Pas M K Parida S D Rindani J P Saha N Sahu Y Sakai S Sen C Sharma C D Sharma S Shalgar N N Singh S Uma Sankar N Sinha R Sinha F Simonetto R Srikanth R Vaidya 《Pramana》2006,67(5):849-860
This is the report of flavor physics and model building working group at WHEPP-9. While activites in flavor physics have been
mainly focused on B-physics, those in model building have been primarily devoted to neutrino physics. We present summary of working group discussions
carried out during the workshop in the above fields, and also briefly review the progress made in some projects subsequently. 相似文献
55.
A self-consistent system of gravitational field with a binary mixture of perfect fluid and dark energy given by a cosmological
constant has been considered in Bianchi Type-V universe. The perfect fluid is chosen to be obeying either the equation of
state p=γρ with γ ε |0,1| or a van der Waals equation of state. The role of A-term in the evolution of the Bianchi Type-V universe has been
studied. 相似文献
56.
J. S. Saini A. K. Singh V. K. Garg S. K. Jaireth K. Chandra 《Hyperfine Interactions》1987,35(1-4):907-911
Powdered samples of Indian Natural Wolframites, (FexMn1?x) WO4 with x=0.95 to 0.41, obtained from seven different locations of two quartz-wolframite deposits of Degana and Sirohi in Rajasthan, have been investigated by Mössbauer spectroscopy down to 20K and magnetic susceptibility down to 77K. The Mössbauer spectra from 300K to 30K clearly indicate multiple sites which is at variance with the reported work. Below 50K a weak magnetic interaction with Hint~45Koe is observed. The spectra above transition temperature are resolved in three doublets and explained on the basis of reported crystal structure. The values of isomer shift, quadrupole splitting and magnetic hyperfine field have been attributed to high spin ferrous ions with octahedral symmetry. Relatively small value of Q.S. (~1.5 mm/sec. at 300K) indicate a strong contribution of the lattice term to the electric field gradient. 相似文献
57.
A poly(vinyl chloride)-based membrane composed of dithio-tetraaza macrocyclic compound as a neutral carrier with sodium tetraphenylborate (NaTPB) as an anion excluder and nitrobenzene (NB) as plasticizer was prepared and investigated as a Th(IV)-selective electrode. The electrode exhibits a Nernstian slope of 14.2 +/- 0.3 mV per decade over a wide concentration range (1.0 x 10(-6) to 1.0 x 10(-1) M) with a detection limit of 8.0 x 10(-7) M between pH 3.5 and 9.5. The response time of the sensor is about 10 s and it can be used over a period of 5 months without any divergence in potential. The proposed membrane sensor revealed a good selectivity for Th(IV) over a wide variety of other metal ions and proved to be a better electrode in many respects than those reported in the literature. It was successfully applied as an electrode indicator as well as in the direct determination of thorium ions in standard and real samples. 相似文献
58.
J.M. Chatterjee S. Basu-Roy S.S. Ghugre S. Chattopadhyay R.P. Singh G.O. Rodrigues R.K. Chattopadhyay R.K. Bhowmik 《The European Physical Journal A - Hadrons and Nuclei》1998,1(1):55-59
A search for new isomers of nanosecond lifetimes were carried out in 153Eu via the 150Nd(7Li,xnγ) reaction. The single particle angular momentum alignment and dynamical moment of inertia estimated from the experimental
data indicate a configuration change at rotational energy ħω∼ 0.30 MeV. A decrease of B(E2) values is also observed at the
same frequency. An isomeric level is identified at an excitation energy of 3100 keV (Jπ=35/2−) which corresponds to this frequency. The lifetime of the level is found to be 8.6 ± 1.3 nanosecond.
Received: 22 April 1997 / Revised version: 26 September 1997 相似文献
59.
Singh G. Chaturvedi S. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》2004,32(6):2210-2216
We have performed two-dimensional, relativistic, electromagnetic, particle-in-cell simulations for an axially extracted vircator. With a copper foil anode, the output frequency of the vircator is found to be strongly dependent upon the variation of foil transparency with electron energy. Using an average transparency for all electron energies yields results that are markedly different from those obtained using the actual variation. However, the output power shows only mild sensitivity. Using the full energy-dependent form of the transparency, we get fairly good agreement with published experimental results. Increasing the energy resolution for the calculation of foil transparency increases the accuracy of calculation of the dominant frequency, although the frequency tends to saturate beyond a certain resolution. However, an increase in the resolution must necessarily be accompanied by an increase in the number of simulation particles, in order to limit statistical fluctuations to an acceptable level. A physical explanation has also been provided for these trends. 相似文献
60.
N. Jiten Singh Adriana C. Olleta Anupriya Kumar Mina Park Hai-Bo Yi Indrajit Bandyopadhyay Han Myoung Lee P. Tarakeshwar Kwang S. Kim 《Theoretical chemistry accounts》2006,115(2-3):127-135
In earlier studies, the interactions of isolated ionic species with various solvents were investigated using ab initio calculations.
The ionic species investigated included cations (proton, hydronium, ammonium, and metal cations) and anions (single electron,
hydroxide, and halide anions). However in the present study, we investigate the interactions of these ionic species with the
solvent in the presence of other competing ionic species. We also elaborate on how the information obtained from these extensive
studies have been employed in designing and synthesizing various kinds of novel ionophores and receptors. 相似文献