Inter‐laboratory comparison: Quantitative surface analysis of thin Fe‐Ni alloy films

An international interlaboratory comparison of the measurement capabilities of four National Metrology Institutes (NMIs) and one Designated Institute (DI) in the determination of the chemical composition of thin Fe‐Ni alloy films was conducted via a key comparison (K‐67) of the Surface Analysis Working Group of the Consultative Committee for Amount of Substance. This comparison was made using XPS (four laboratories) and AES (one laboratory) measurements. The uncertainty budget of the measured chemical composition of a thin alloy film was dominated by the uncertainty of the certified composition of a reference specimen which had been determined by inductively coupled plasma mass spectrometry using the isotope dilution method. Pilot study P‐98 showed that the quantification using relative sensitivity factors (RSFs) of Fe and Ni derived from an alloy reference sample results in much more accurate result in comparison to an approach using RSFs derived from pure Fe and Ni films. The individual expanded uncertainties of the participants in the K‐67 comparison were found to be between 2.88 and 3.40 atomic %. The uncertainty of the key comparison reference value (KCRV) calculated from individual standard deviations and a coverage factor (k) of 2 was 1.23 atomic %. Copyright © 2011 John Wiley & Sons, Ltd.     

Functional organogels from highly efficient organogelator based on perylene bisimide semiconductor

A new n-type semiconducting perylene bisimide dye has been synthesized that gelates a broad variety of organic solvents to afford well-defined nano- and mesoscopic helical fibers and bundles.     

Heuristic methods for the sectoring arc routing problem

The sectoring arc routing problem (SARP) is introduced to model activities associated with the streets of large urban areas, like municipal waste collection. The aim is to partition the street network into a given number of sectors and to build a set of vehicle trips in each sector, to minimize the total duration of the trips. Two two-phase heuristics and one best insertion method are proposed. In the two-phase methods, phase 1 constructs the sectors using two possible heuristics, while phase 2 solves a mixed capacitated arc routing problem (MCARP) to compute the trips in each sector. The best insertion method determines sectors and trips simultaneously. In addition to solution cost, some evaluation criteria such as imbalance, diameter and dispersion measures are used to compare algorithms. Numerical results on large instances with up to 401 nodes and 1056 links (arcs or edges) are reported and analysed.     

Covalent Capture: Merging Covalent and Noncovalent Synthesis

Coming together : The act of bringing the right molecules together is enough to induce irreversible or reversible formation of a covalent bond. The covalent capture strategy, in which a supramolecular interaction leads to the formation of a covalent bond (see scheme), can be utilized in very different biological and synthetic systems and can be used for numerous applications.

     

Persistent ATP-Concentration Gradients in a Hydrogel Sustained by Chemical Fuel Consumption

We show the formation of macroscopic ATP-concentrations in an agarose gel and demonstrate that these gradients can be sustained in time at the expense of the consumption of a chemical fuel. The approach relies on the spatially controlled activation of ATP-producing and ATP-consuming reactions through the local injection of enzymes in the matrix. The reaction-diffusion system is maintained in a stationary non-equilibrium state as long as chemical fuel, phosphocreatine, is present. The reaction-diffusion system is coupled to a supramolecular system composed of monolayer protected gold nanoparticles and a fluorescent probe. As a result of this coupling, fluorescence signals emerge spontaneously in response to the ATP-concentration gradients. We show that the approach permits the rational formation of complex fluorescence patterns that change over time as a function of the evolution of the ATP-concentrations present in the system.