Synthesis of YBCO Nanopowders and Properties of Ceramics on Their Basis

Crystallography Reports - The structure, morphology, density, and resistivity of nanostructured superconducting YBCO-based ceramics, fabricated from nanopowders prepared by burning nitrate-organic...     

Interfaces in superconducting hybrid heterostructures with an antiferromagnetic interlayer

The structural, X-ray diffraction, and electrophysical studies of hybrid superconducting hetero-structures with an interlayer of cuprate antiferromagnetic Ca_{1 ? x} Sr _x CuO₂ (CSCO) with the upper electrode Nb/Au and the lower electrode Y_Ba₂Cu₃O_{7 ? δ} (YBCO) have been carried out. It has been experimentally shown that the epitaxial growth of two cuprates, YBCO and CSCO, results in the formation of an interface on which the enrichment of the CSCO interlayer with charge carriers proceeds to a depth of about 20 nm. In this case, the conduction of the enriched CSCO region proves to be closer to metallic, whereas the CSCO film deposited onto the NdGaO₃ substrate is a Mott insulator with hopping conduction.     

Characteristics of the process of reorientation of bipolar drops of a nematic with rigidly fixed poles

The director configuration in a bipolar drop of a nematic with rigidly fixed poles is calculated as a function of the electric field directed perpendicular to the symmetry axis of the drop. It is shown that the reorientation of the drop is a dual process: a threshold process in the region where the initial director orientation is orthogonal to the electric field, and a nonthreshold process elsewhere in the drop. A relation for determining the critical field is obtained. Experimental investigations of the characteristics of scattered light for a film of polymer-encapsulated liquid crystals confirm the computational results. Pis’ma Zh. éksp. Teor. Fiz. 67, No. 9, 696–700 (10 May 1998)     

119Sn and 57Fe M?ssbauer study of the local structure of perovskite-type ferrites CaFe2 ? x N x O5 ( N = Sc, Al) and manganite CaMn7O12

Anion-deficient substituted ferrites Ca₂Fe_{2 − x} N _x O₅ (N = Sc³⁺, Al³⁺) and mixed manganite CaMn₇O₁₂ have been investigated by ¹¹⁹Sn and ⁵⁷Fe probe M?ssbauer spectroscopy. The mechanism of charge compensation for heterovalent impurity Sn⁴⁺ ions in the structure of the ferrite Ca₂Fe₂O₅ has been established. The presence of nonequivalent crystallographic positions of manganese cations, caused by their charge ordering in the structure of the manganite CaMn₇O₁₂, is shown. Magnetic ordering of Mn³⁺ and Mn⁴⁺ cations in the octahedral sublattice of CaMn₇O₁₂ at T < T _M2 ≈ 90 K is established. Original Russian Text ? A.V. Sobolev, I.A. Presnyakov, K.V. Pokholok, V.S. Rusakov, T.V. Gubaidulina, A.V. Baranov, G. Demazeau, 2007, published in Izvestiya Rossiiskoi Akademii Nauk Seriya Fizicheskaya, 2007, Vol. 71, No. 9, pp. 1347–1354.     

Interference quenching of light transmitted through a monolayer film of polymer-dispersed nematic liquid crystal

A theoretical study of light transmission through a polymer with a monolayer ensemble of bipolar nematic droplets under applied electric film is performed. The possibility of interference quenching of monochromatic coherent light directly transmitted through the film is predicted theoretically and realized in the experiment.     

Physical and Chemical Properties of Magnetite and Magnetite-Polymer Nanoparticles and Their Colloidal Dispersions

The properties of polymer-coated magnetite nanoparticles, which have the potential to be used as effective magnetic resonance contrast agents, have been studied. The magnetite particles were synthesized by using continuous synthesis in an aqueous solution. The polymer-coated magnetite nanoparticles were synthesized by seed precipitation polymerization of methacrylic acid and hydroxyethyl methacrylate in the presence of the magnetite nanoparticles. The particle size was measured by laser light scattering. It was shown that the particle size, variance, magnetic properties, and stability of aqueous magnetite colloidal dispersion strictly depend on the nature of the stabilizing agent. The average hydrodynamic radius of the magnetite particles was found to be 5.7 nm in the stable aqueous colloidal dispersion. An inclusion of the magnetite particle into a hydrophilic polymeric shell increases the stability of the dispersion and decreases the influence of the stabilizing agent on the magnetic and structural properties of the magnetite particles as was shown by X-ray diffraction and M?ssbauer and IR spectroscopy, as well as by vibrating sample magnetometry. The variation in the polymeric shell size and the polymer net density can be useful tools for evaluation of the polymer-coated magnetite particles as effective contrast agents. Copyright 1999 Academic Press.     

Light absorption in hydrogen plasma on the bound-free and free-free transitions of the H-H+ system

Radiative transitions in the proton-hydrogen atom system are theoretically analyzed over a wide range of wavelengths and temperatures of equilibrium hydrogen plasma. The light absorption at T～1500–3500 K due to photodissociation and transitions in the H ₂ ⁺ ion continuum is shown to make a contribution that is comparable with the photoabsorption in the electron-hydrogen atom system near the maximum of the Planck distribution.     

Evolution of Phase Composition and Structure in Sapphire Implanted with <Superscript>64</Superscript>Zn<Superscript>+</Superscript> Ions and Heat-Treated in Oxygen

Single-crystal Al₂O₃ substrates are implanted with ⁶⁴Zn⁺ ions using doses of 5 × 10¹⁶ cm^–2 and an energy of 100 keV. The samples are annealed in oxygen with a stepwise increase in temperature from 400 to 1000°C. The changes on the surface and in the bulk of the sample are analyzed via scanning electron microscopy, energy-dispersive analysis, transmission electron microscopy, and Auger electron spectroscopy.