An ab-initio Investigation: The Physical Properties of ScIr2 Superconductor

Physics of the Solid State - Using ab initio technique the physical properties of ScIr2 superconductor have been investigated with Tc 1.03 K with a MgCu2-type structure. We have carried out the...     

Design of Hamming Code Checker Using Titanium-Diffused Lithium Niobate-Based Waveguide

ABSTRACT

This work presents an electro-optic effect-based design for the widely used Hamming code for checking single bit errors in the received data. The structure is based on Mach-Zehnder Interferometer, designed using Titanium-diffused Lithium Niobate-based waveguides. The proposed device has been successfully tested using the beam propagation method. For a received 7-bit code, the three simultaneously generated check bits are combined to check the error position. Critical performance parameters like extinction ratio (24.39dB), contrast ratio (25.711dB), insertion loss (0.041dB), and amplitude modulation (0.079dB) calculated for the overall device are within acceptable limits for the feasibility of the device.     

Synthesis,Optical Investigation and Biological Properties of Europium(III) Complexes with 2-(4-Chlorophenyl)-1-(2-Hydroxy-4-Methoxyphenyl)Ethan-1-one and Ancillary Ligands

Synthesis and photoluminescence behaviour of six novel europium complexes with novel β-hydroxyketone ligand, 2-(4-chlorophenyl)-1-(2-hydroxy-4-methoxyphenyl)ethan-1-one (CHME) and 2,2′-bipyridine (bipy) or neocuproine (neo) or 1,10-phenanthroline (phen) or 5,6-dimethyl-1,10-phenanthroline (dmphen) or bathophenanthroline (bathophen) were reported in solid state. The free ligand CHME and europium complexes, Eu(CHME)₃.2H₂O [1] Eu(CHME)₃.bipy [2], Eu(CHME)₃.neo [3], Eu(CHME)₃.phen [4], Eu(CHME)₃.dmphen [5] and Eu(CHME)₃.bathophen [6]were characterized by elemental analysis, FT-IR and ¹H-NMR. The photoluminescence emission spectra exhibited four characteristic peaks arising from the ⁵D₀ → ⁷F_J (J = 1–4) transitions of the europium ion in the solid state on monitoring excitation at λ_ex = 395 nm. The luminescence decay curves of these europium complexes possess single exponential behaviour indicating the presence of a single luminescent species and having only one site symmetry in the complexes. The luminescence quantum efficiency (η) and the experimental intensity parameters, Ω ₂ and Ω ₄ of europium complexes have also been calculated on the basis of emission spectra and luminescence decay curves. In addition, the antimicrobial and antioxidant activities were also studied of the investigated complexes.     

Generation of an arbitrary chirped microwave waveform with high time-bandwidth product for increasing range resolution of RADAR by using photonic technique

An approach for photonic generation of an arbitrary chirped microwave waveform with an increased time-bandwidth product (TBWP) is proposed and experimentally demonstrated. In the proposed model, light from the mode locked laser is splitted into two parts by using 1 × 2 power splitter: one is sent to linearly chirped fiber Bragg grating (LCFBG) through circulator and the other is time delayed by fiber delay line. The optical pulse in upper arm is time stretched by the LCFBG. Meanwhile, the optical pulse in lower arm experiences a time delay and then stretched by the dispersive single mode fiber. Temporal interference pattern is generated with an increasing or decreasing free spectral range by combination of two time-stretched optical pulses. Finally, the temporal interference pattern which is obtained at the output of optical coupler is transformed into an arbitrary chirped microwave waveform by using a photo-detector. The main advantage of this proposed model is high TBWP in the range of 750–1000 which ultimately results in an increased range resolution of radio detection and ranging.     

Buckling-driven morphological transformation of droplets of a mixed colloidal suspension during evaporation-induced self-assembly by spray drying

Morphological transformation during evaporation-induced self-assembly of a mixed colloidal suspension in micrometric droplets has been investigated. It has been demonstrated that a buckling-driven shape transition of drying droplets of mixed colloidal suspension takes place during evaporation-induced self-assembly. Further, it is also shown that the distortion modulations get significantly amplified with enhancement in volume fraction of anisotropic soft colloidal component of the mixed colloids. It has been argued that the reduction in elastic modulus of formed shell, at the boundary of a drying droplet, and the anisotropic nature of one of the colloidal components facilitate the deformation process. Hierarchical structures of these assembled colloidal grains have been probed using electron microscopy and scattering techniques.     

Experimental measurements of acoustical properties of snow and inverse characterization of its geometrical parameters

Snow is a sound absorbing porous sintered material composed of solid matrix of ice skeleton with air (+water vapour) saturated pores. Investigation of snow acoustic properties is useful to understand the interaction between snow structure and sound waves, which can be further used to devise non-destructive way for exploring physical (non-acoustic) properties of snow. The present paper discusses the experimental measurements of various acoustical properties of snow such as acoustic absorption coefficient, surface impedance and transmission losses across different snow samples, followed by inverse characterization of different geometrical parameters of snow. The snow samples were extracted from a natural snowpack and transported to a nearby controlled environmental facility at Patsio, located in the Great Himalayan range of India. An impedance tube system (ITS), working in the frequency range 63–6300 Hz, was used for acoustic measurements of these snow samples. The acoustic behaviour of snow was observed strongly dependent upon the incident acoustic frequency; for frequencies smaller than 1 kHz, the average acoustic absorption coefficient was found below than 0.4, however, for the frequencies more than 1 kHz it was found to be 0.85. The average acoustic transmission loss was observed from 1.45 dB cm⁻¹ to 3.77 dB cm⁻¹ for the entire frequency range. The real and imaginary components of normalized surface impedance of snow samples varied from 0.02 to 7.77 and −6.05 to 5.69, respectively. Further, the measured acoustic properties of snow were used for inverse characterization of non-acoustic geometrical parameters such as porosity, flow resistivity, tortuosity, viscous and thermal characteristic lengths using the equivalent fluid model proposed by Johnson, Champoux and Allard (JCA). Acoustically derived porosity and flow resistivity were also compared with experimentally measured values and good agreement was observed between them.