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41.
We report here a methodology of chemo- and regio-selective aryl bromination and iodination using respective N-halosuccinimides at room temperature in the absence of any solvents, catalyst/additives under ball-milling condition. However, for chlorination ceric ammonium nitrate was used as additive. The coupled product succinimide, produced from the reactions, was recycled via regeneration of NBS. This methodology works with the electron-donor substituted or unsubstituted arenes. 相似文献
42.
This paper demonstrates the use of copper electrode for the treatment of sugar processing industry wastewater (SPIW) in terms of chemical oxygen demand (COD) by applying electrocoagulation (EC) method. EC process was carried out in batch mode with electrode effective area of 0.0112 m2, supplied current intensity (CI) of 44.64 A/m2 - 223.21 A/m2, electrode gap (EG) of 0.5–2.5 cm, electrolyte (NaCl) dose (ED) of 0.5–2.5 g/L to treat SPIW with initial chemical oxygen demand (COD) of 6000 mg/L. The maximum COD removal 73% of SPIW is achieved at optimized condition of SPIW pH: 7, CI: 89.28 A/m2, EG: 1.5 cm & ED: 1.5 g/L. Sludge and scum generated during EC process were characterized by FTIR, TGA/DTA/DTG, proximate & ultimate analysis to find its applicability and their disposal. Additionally, economic study of EC treatment process at optimum condition suggest treatment cost was 11.2 US$/m3 and it indicate economic results as comparison to other available treatment processes. 相似文献
43.
We report results of hyperpolarizability calculations on CdnXn (X: S, Se and Te; n = 1–10) clusters. Our results show that the geometric configurations of different types of clusters under
investigation are quite similar at specific values of n. Both static and frequency dependent components of first and second
order hyperpolarizability tensors of CdnSn, CdnSen and CdnTen are compared. It is observed that in general nonlinear optical coefficients show identical variation in all the cluster materials.
The present investigation also manifests the improvement of these coefficients due to the introduction of asymptotically correct
generalized gradient approximation functional over the local density functional and normal gradient corrected functional.
Symmetrized fragment orbital analysis has been performed to provide explanation of the observed hyperpolarizability variation.
We also analyse how geometries with closely lying energy values influence the hyperpolarizabilities of these cluster materials. 相似文献
44.
New urea-based sensors show a strong affinity for F−, CH3COO−, and H2PO4− with an appreciable color change in the presence of excess F−. The position of the nitro group in the urea derivative influences the relative affinity toward anionic analytes. Spectral and ab initio studies showed the difference in the deprotonation sites for the ortho- and meta/para-isomers in these cases. Photophysical studies confirmed the resonance energy transfer in the case of the ortho-isomer. The ortho-isomer can act as a dual emission probe for F−. 相似文献
45.
Dr. Rakesh Puttreddy Prof. Dr. Kari Rissanen Dr. Prasenjit Mal 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(17):6390-6393
Subcomponent self‐assembly from components A , B , C , D , and Fe2+ under solvent‐free conditions by self‐sorting leads to the construction of three structurally different metallosupramolecular iron(II) complexes. Under carefully selected ball‐milling conditions, tetranuclear [Fe4( AD 2)6]4? 22‐component cage 1 , dinuclear [Fe2( BD 2)3]2? 11‐component helicate 2 , and 5‐component mononuclear [Fe( CD 3)]2+ complex 3 were prepared simultaneously in a one‐pot reaction from 38 components. Through subcomponent substitution reaction by adding subcomponent B , the [Fe4( AD 2)6]4? cage converts quantitatively to the [Fe2( BD 2)3]2? helicate, which, in turn, upon addition of subcomponent C , transforms to [Fe( CD 3)]2+, following the hierarchical preference based on the thermodynamic stability of the complexes. 相似文献
46.
47.
Impact of Metal Ions in Porphyrin‐Based Applied Materials for Visible‐Light Photocatalysis: Key Information from Ultrafast Electronic Spectroscopy
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Prasenjit Kar Samim Sardar Dr. Erkki Alarousu Dr. Jingya Sun Prof. Zaki S. Seddigi Prof. Saleh A. Ahmed Dr. Ekram Y. Danish Dr. Omar F. Mohammed Prof. Samir Kumar Pal 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(33):10475-10483
Protoporphyrin IX‐zinc oxide (PP‐ZnO) nanohybrids have been synthesized for applications in photocatalytic devices. High‐resolution transmission electron microscopy (HRTEM), X‐ray diffraction (XRD), and steady‐state infrared, absorption, and emission spectroscopies have been used to analyze the structural details and optical properties of these nanohybrids. Time‐resolved fluorescence and transient absorption techniques have been applied to study the ultrafast dynamic events that are key to photocatalytic activities. The photocatalytic efficiency under visible‐light irradiation in the presence of naturally abundant iron(III) and copper(II) ions has been found to be significantly retarded in the former case, but enhanced in the latter case. More importantly, femtosecond (fs) transient absorption data have clearly demonstrated that the residence of photoexcited electrons from the sensitizer PP in the centrally located iron moiety hinders ground‐state bleach recovery of the sensitizer, affecting the overall photocatalytic rate of the nanohybrid. The presence of copper(II) ions, on the other hand, offers additional stability against photobleaching and eventually enhances the efficiency of photocatalysis. In addition, we have also explored the role of UV light in the efficiency of photocatalysis and have rationalized our observations from femtosecond‐ to picosecond‐resolved studies. 相似文献
48.
Samantaray MK Pang K Shaikh MM Ghosh P 《Dalton transactions (Cambridge, England : 2003)》2008,(36):4893-4902
An unique long-range 1,7-bromination reaction is observed in gold(iii) complexes of N-(aryl)imino functionalized N-heterocyclic carbene with the bromination occurring at two different carbon (sp(2) and sp(3)) centers spatially separated by ca. 6.4 A but existing in extended conjugation to each other. In particular, the unusual distant 1,7-brominated gold(iii) complexes [1-R-3-{N-(p-bromo-2,6-di-i-propylphenylimino)-2-phenyl-1-bromoethyl}imidazol-2-ylidene]AuBr(3) [R = Me (), i-Pr (), t-Bu (), -CH(2)Ph ()] were synthesized cleanly at room temperature under ambient conditions from the reactions of molecular bromine with the gold(i) complexes [1-R-3-{N-(2,6-di-i-propylphenylimino)-2-phenylethyl}imidazol-2-ylidene]AuCl [R = Me (), i-Pr (), t-Bu (), -CH(2)Ph ()]. All of the 1,7-bromination products (, , and ) have been structurally verified by X-ray diffraction studies. 相似文献
49.
Jammi S Rout L Saha P Akkilagunta VK Sanyasi S Punniyamurthy T 《Inorganic chemistry》2008,47(12):5093-5098
Chiral copper(II) coordination polymers 1a-c have been prepared by one-pot synthesis in high yield. Their single-crystal X-ray analysis showed that repeating units are connected to each other by carboxylate linker and copper(II) atoms are pentacoordinated with distorted square-pyramidal geometry for 1a-b and square-planar geometry for 1c. These polymers have catalyzed the kinetic resolution of secondary alcohols by acylation with up to 90% ee ( s = 50). 相似文献
50.
A cryptand with six secondary amino groups has been derivatized by reacting with acid chlorides of different chain lengths (C(7), C(10) and C(18)) to get three cryptand based hexa-tailed neutral amphiphiles (L(1)-L(3)). The cavity of the cryptand head group accommodates two Cu(II) ion giving another set of three amphiphiles. These amphiphiles and its copper complexes can aggregate spontaneously as giant vesicular microcapsules in 10% ethanolic water medium. In all cases vesicles formed are mostly unilamellar in nature. Vesicular microcapsules prepared from L(1)-L(3) can encapsulate hydrophilic dye 5(6)-carboxyfluorescein (CF). Stability of microcapsules, CF encapsulation efficiencies and release rates were dependent on the hydrophobic chain length of the amphiphiles. Results show the permeability of the L(2) and L(3) bilayer is lower than that of phosphatidylcholine vesicles and the loading capacity is approximately 3 times greater. Microcapsules have been characterized by optical microscopy, freeze fracture scanning electron microscopy and confocal fluorescence microscopy. 相似文献