全文获取类型
收费全文 | 19606篇 |
免费 | 835篇 |
国内免费 | 72篇 |
专业分类
化学 | 13270篇 |
晶体学 | 292篇 |
力学 | 676篇 |
综合类 | 3篇 |
数学 | 1662篇 |
物理学 | 4610篇 |
出版年
2024年 | 64篇 |
2023年 | 202篇 |
2022年 | 581篇 |
2021年 | 649篇 |
2020年 | 639篇 |
2019年 | 689篇 |
2018年 | 683篇 |
2017年 | 602篇 |
2016年 | 880篇 |
2015年 | 661篇 |
2014年 | 973篇 |
2013年 | 1650篇 |
2012年 | 1435篇 |
2011年 | 1509篇 |
2010年 | 970篇 |
2009年 | 776篇 |
2008年 | 915篇 |
2007年 | 945篇 |
2006年 | 727篇 |
2005年 | 658篇 |
2004年 | 481篇 |
2003年 | 416篇 |
2002年 | 342篇 |
2001年 | 232篇 |
2000年 | 184篇 |
1999年 | 158篇 |
1998年 | 105篇 |
1997年 | 130篇 |
1996年 | 150篇 |
1995年 | 122篇 |
1994年 | 100篇 |
1993年 | 134篇 |
1992年 | 135篇 |
1991年 | 118篇 |
1990年 | 91篇 |
1989年 | 96篇 |
1988年 | 79篇 |
1987年 | 74篇 |
1986年 | 70篇 |
1985年 | 109篇 |
1984年 | 85篇 |
1983年 | 79篇 |
1982年 | 78篇 |
1981年 | 52篇 |
1980年 | 77篇 |
1979年 | 87篇 |
1978年 | 76篇 |
1977年 | 81篇 |
1976年 | 60篇 |
1975年 | 45篇 |
排序方式: 共有10000条查询结果,搜索用时 93 毫秒
101.
A poly(vinyl chloride)-based membrane composed of dithio-tetraaza macrocyclic compound as a neutral carrier with sodium tetraphenylborate (NaTPB) as an anion excluder and nitrobenzene (NB) as plasticizer was prepared and investigated as a Th(IV)-selective electrode. The electrode exhibits a Nernstian slope of 14.2 +/- 0.3 mV per decade over a wide concentration range (1.0 x 10(-6) to 1.0 x 10(-1) M) with a detection limit of 8.0 x 10(-7) M between pH 3.5 and 9.5. The response time of the sensor is about 10 s and it can be used over a period of 5 months without any divergence in potential. The proposed membrane sensor revealed a good selectivity for Th(IV) over a wide variety of other metal ions and proved to be a better electrode in many respects than those reported in the literature. It was successfully applied as an electrode indicator as well as in the direct determination of thorium ions in standard and real samples. 相似文献
102.
Jai Kumar Singhal 《Pramana》2004,62(5):1029-1040
We examine the effects of mixing induced light heavy charged lepton neutral currents on the partial wave amplitude for the
process l+l− →ZZ (withl = e,μ or τ). By imposing the constraints that the amplitude should not exceed the perturbative unitarity limit at high energy (√s
= Λ), we obtain bounds on light heavy charged lepton mixing parameter sin2(2θ
L
a
) where θ
L
a
is the mixing angle of the ordinary charged lepton with its exotic partner. For Λ = 1 TeV, no bound is obtained on sin2 (2θ
L
a
) form
E < 0.69 TeV. However, sin2 (2θ
L
a
) ≤ 1.52×10−5 form
E = 5 TeV, sin2 (2θ
L
a
) ≤ 2.41 ×10−7 form
E = 10 TeV. Similarity for Λ = ∞ no bound is obtained on sin2 (2θ
L
a
) for mE < 1.97 TeV and sin2 (2θ
L
a
) ≤ 0.15 form
E = 5 TeV and sin2 (2θ
L
a
) ≤ 3.88×10-2 form
E = 10 TeV. 相似文献
103.
Mixed thin films of (CdO)1−x(PbO)x and (CdS)1−x(PbS)x (x=0.25) were prepared on glass substrates by spray pyrolysis technique for various substrate temperatures 300, 320 and 340 °C. Structural and optical properties were studied. XRD studies reveal the formation of mixed films. The substrate temperature of 340 °C seems to be critical for the formation of CdO-PbO mixed films. It is observed that (CdS)1−x(PbS)x mixed films were formed at all the three substrate temperatures. The direct band gap value of (CdO)1−x(PbO)x and (CdS)1−x(PbS)x mixed films is about 2.6 and 2.37 eV, respectively. 相似文献
104.
Multicharacteristic critical components exist in many systems. Such components could be a part of an aircraft, space shuttle or a gas ignition system. A component is critical if it causes disaster or a very high cost upon failure. In this paper, a new inspection plan for critical multicharacteristic components is presented. A mathematical model that depicts the plan is developed. An algorithm is proposed for finding the optimal number of repeat inspections and the sequence of characteristics for inspection that minimizes expected total cost per accepted component. The expected cost consists of the cost of inspection and the cost of misclassifications. The inspection plan and the model developed generalize existing models in the literature and provide a more realistic formulation. An example is given to demonstrate the plan and the model. 相似文献
105.
N. Jiten Singh Adriana C. Olleta Anupriya Kumar Mina Park Hai-Bo Yi Indrajit Bandyopadhyay Han Myoung Lee P. Tarakeshwar Kwang S. Kim 《Theoretical chemistry accounts》2006,115(2-3):127-135
In earlier studies, the interactions of isolated ionic species with various solvents were investigated using ab initio calculations.
The ionic species investigated included cations (proton, hydronium, ammonium, and metal cations) and anions (single electron,
hydroxide, and halide anions). However in the present study, we investigate the interactions of these ionic species with the
solvent in the presence of other competing ionic species. We also elaborate on how the information obtained from these extensive
studies have been employed in designing and synthesizing various kinds of novel ionophores and receptors. 相似文献
106.
A. Konjhodzic A. Adamczyk F. Vagizov Z. Hasan E E. Alp W. Sturhahn Jiyong Zhao J J. Carroll 《Hyperfine Interactions》2006,170(1-3):83-89
With the decrease in size of devices, rapid characterization of nano-devices is an inevitable necessity. It is shown that Mössbauer spectroscopy using synchrotron radiation from the advanced photon source provides such a tool of investigation. Results are presented and compared for conventional Mössbauer and Nuclear Forward Scattering for 151Eu-doped magnesium sulfide as an example, especially at low concentrations. 相似文献
107.
Sk. Asrof Ali Yunusa Umar B. F. Abu‐Sharkh Hasan A. Al‐Muallem 《Journal of polymer science. Part A, Polymer chemistry》2006,44(19):5480-5494
The cycloterpolymerizations of single‐, twin‐, and triple‐tailed hydrophobes with hydrophilic monomer N,N‐diallyl‐N‐carboethoxymethylammonium chloride and sulfur dioxide afforded a series of cationic polyelectrolytes (CPEs) in excellent yields. These CPEs, upon the acidic hydrolysis of the pendent ester groups, gave the corresponding pH‐responsive cationic acid salts, which, upon a treatment with sodium hydroxide, were converted to polybetaines (PBs), anionic polyelectrolytes (APEs), and PB/APE polymers containing various proportions of zwitterionic (PB) and anionic fractions (APE) in the polymer chain. At a shear rate of 0.36 s−1 at 30 °C, salt‐free water solutions of the CPEs (2 g/dL) containing 8, 4, and 2.67 mol % of the single‐, twin‐, and triple‐tailed hydrophobes (all having 8 mol % octyloxy tails) had apparent viscosity values of 70, 2800, and 396,000 cps, respectively. The PB/APE polymer with a ratio of 33:67 for the zwitterionic and anionic fractions in the polymer chain gave the highest viscosity value. The superior viscosity behavior of the polymers containing the triple‐tailed hydrophobe was attributed to the blocky nature of the comonomer. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5480–5494, 2006 相似文献
108.
Poly(ortho‐phenylene ethynylene)s (PoPEs) have been synthesized via an in situ activation/coupling AB′ polycondensation protocol. The resulting polymers have been characterized by several analytical methods and are shown to have no structural defects. Although the Sonogashira–Hagihara polycondensation reaction is less efficient than for the preparation of the corresponding meta‐ and para‐linked polymers, presumably because of steric hindrance caused by the ortho substituents, the process can be accelerated by the use of microwave irradiation. Optical spectroscopy indicates solvent‐dependent conformational changes between extended transoid and helical cisoid conformations, providing the first experimental evidence for solvophobically driven folding of the PoPE backbone. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1619–1627, 2006 相似文献
109.
110.
A series of new thermoplastic polyesters based on 3,4‐ethylenedioxythiophene (EDOT) with flexible aliphatic spacers have been synthesized and characterized for the first time. The thermal properties of these polyesters based on EDOT are comparable to those of conventional polyesters based on the 1,4‐phenyl unit, indicating that EDOT is a viable replacement for the phenyl units. The glass‐transition and melting‐transition temperatures decrease monotonically with an increase in the spacer length. Theoretical calculations have revealed that the core angle for EDOT is comparable to that of unsubstituted thiophene and hence should be compatible with the formation of the mesophase. This has been confirmed experimentally by the synthesis of a main‐chain, thermotropic, liquid‐crystalline polyester based on EDOT that exhibits fluid birefringence. In fact, this is the first report in which a main‐chain, liquid‐crystalline polymer based on 3,4‐disubstituted thiophene has been successfully designed and synthesized. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3479–3486, 2006 相似文献