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51.
52.
Mifsud N Mellon V Perera KP Smith DW Echegoyen L 《The Journal of organic chemistry》2004,69(18):6124-6127
Electron paramagnetic resonance (EPR) spectroscopy was successfully used for the first time to follow the Bergman cyclization of bis-ortho-diynyl arene (BODA) compounds. Five BODA monomers with different spacer (X) and terminal groups (R) were compared. In situ polymerization via EPR spectroscopy yielded first-order rate expressions. Monomers with spacer -O- or -C(CF(3))(2) and terminal group R = Ph exhibited similar kinetic behavior upon thermal polymerization, whereas monomers with pyridine and thiophene terminal groups gave significantly higher rates of polymerization over phenyl-terminated derivatives. A model compound, 1,2-bis(phenylethynyl)benzene, was used to probe the polymerization mechanism, and radical intermediates were found to be stable indefinitely at room temperature. 相似文献
53.
Christian P Rajaraman G Harrison A Helliwell M McDouall JJ Raftery J Winpenny RE 《Dalton transactions (Cambridge, England : 2003)》2004,(16):2550-2555
We report a carboxylate triangle consisting of three manganese(II) centres which is made from manganese(II) carbonate and pivalic acid. The magnetic exchange within the triangle is extremely weak, and antiferromagnetic. Several models have been used to fit the magnetic data, and the best fit uses two weak antiferromagnetic coupling constants of J(1)=-0.588 cm(-1) and J(2)=-0.855 cm(-1). Exchange interactions between the metal centres has been calculated using DFT adopting all the three possible Heisenberg models for a trinuclear system and the results are compared with experimental values. Spin density distribution is used to analyse the nature of the coupling between the metal centres. EPR spectroscopy has been used to explore the nature of the ground state. Recrystallisation of the trinuclear compound from MeCN gives a polymer, while oxidation in air leads to a known compound--an edge-sharing bitetrahedral (MnIII2MnII4) cage. 相似文献
54.
Direct detection of ion pairs by fluorescence enhancement 总被引:1,自引:0,他引:1
Sensor 1 signals the simultaneous presence of sodium and phosphate with an increased fluorescence signal in the manner of a photoionic AND logic gate. 相似文献
55.
56.
Venkatapuram Padmavathi Sanapalli Nagi Reddy Guda Dinneswara Reddy Bhumireddy Chinnachennaiahgari Venkatesh Adivireddy Padmaja 《Journal of heterocyclic chemistry》2011,48(5):1197-1201
A new class of bis heterocycles—sulfone linked pyrazolyl oxadiazoles thiadiazoles were prepared from E‐phenylsulfonylethenesulfonylacetic acid and studied their antimicrobial activities. J. Heterocyclic Chem., (2011). 相似文献
57.
Anodic dissolution of copper in glycine solution at various hydrogen peroxide concentrations was investigated. The dissolution
rate increases, reaches a maximum, and then decreases with hydrogen peroxide concentration. Anodic polarization studies and
electrochemical impedance spectroscopy (EIS) studies were carried out to determine the mechanistic pathway of anodic dissolution
of copper in glycine system at three different hydrogen peroxide concentrations: one at low hydrogen peroxide concentration
in the active dissolution region, another in the maximum dissolution region, and the third at the high hydrogen peroxide concentration
in the post-peak-dissolution region. The EIS data in complex plane plots show presence of two capacitance loops and one negative
capacitance loop. The impedance plot patterns strongly depend on the hydrogen peroxide concentration in solution. Reaction
mechanism analysis technique was employed to model the EIS data. A three-step mechanism with two intermediate adsorbates and
a parallel dissolution by catalytic mechanism simulates EIS patterns which match the experimental trends. The intermediates
are likely to be cupric and cuprous oxides. The essential features of impedance spectra at various overpotentials at three
different hydrogen peroxide concentrations are captured by the proposed mechanism. The results also show that the film present
on the copper surface in glycine and hydrogen peroxide solutions does not passivate the surface. 相似文献
58.
We investigate the ratio of spin precession frequency to orbital frequency for a spinning charged particle confined to circular
orbit in the equatorial plane of a compact object, with a uniform magnetic field, as described by the Wald and the Ernst potentials.
In order to see the difference in behaviours for particles with differentg values we consider the cases of electron and proton separately. 相似文献
59.
We prove a local-global principle for the problem of representations of quadratic forms by quadratic forms over ℤ, in codimension
≥5. The proof uses the ergodic theory of p-adic groups, together with a fairly general observation on the structure of orbits of an arithmetic group acting on integral
points of a variety. 相似文献
60.