全文获取类型
收费全文 | 655篇 |
免费 | 20篇 |
国内免费 | 1篇 |
专业分类
化学 | 419篇 |
晶体学 | 17篇 |
力学 | 2篇 |
数学 | 53篇 |
物理学 | 185篇 |
出版年
2024年 | 4篇 |
2023年 | 6篇 |
2022年 | 11篇 |
2021年 | 12篇 |
2020年 | 12篇 |
2019年 | 9篇 |
2018年 | 6篇 |
2017年 | 8篇 |
2016年 | 20篇 |
2015年 | 18篇 |
2014年 | 18篇 |
2013年 | 53篇 |
2012年 | 55篇 |
2011年 | 38篇 |
2010年 | 19篇 |
2009年 | 21篇 |
2008年 | 35篇 |
2007年 | 27篇 |
2006年 | 30篇 |
2005年 | 26篇 |
2004年 | 23篇 |
2003年 | 23篇 |
2002年 | 16篇 |
2001年 | 3篇 |
2000年 | 6篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1995年 | 6篇 |
1994年 | 3篇 |
1993年 | 7篇 |
1992年 | 4篇 |
1991年 | 6篇 |
1990年 | 4篇 |
1989年 | 8篇 |
1988年 | 4篇 |
1987年 | 9篇 |
1986年 | 7篇 |
1985年 | 7篇 |
1984年 | 9篇 |
1983年 | 7篇 |
1981年 | 10篇 |
1980年 | 8篇 |
1979年 | 5篇 |
1978年 | 11篇 |
1977年 | 5篇 |
1976年 | 11篇 |
1975年 | 7篇 |
1973年 | 4篇 |
1958年 | 4篇 |
1957年 | 4篇 |
排序方式: 共有676条查询结果,搜索用时 15 毫秒
31.
Relaxation dynamics of plasmons in Au−SiO2 core-shell nanoparticles have been followed by femtosecond pump-probe technique. The effect of excitation pump energy and surrounding medium on the time constants associated with the hot electron relaxation has been elucidated. A gradual increase in the electron-phonon relaxation time with pump energy is observed and can be attributed to the higher perturbation of the electron distribution in AuNPs at higher pump energy. Variation in time constants for the electron-phonon relaxation in different solvents is rationalized on the basis of their thermal conductivities, which govern the rate of dissipation of heat of photoexcited electrons in the nanoparticles. On the other hand, phonon-phonon relaxation is found to be much less effective than electron-phonon relaxation for the dissipation of energy of the excited electron and the time constants associated with it remain unaffected by thermal conductivity of the solvent. 相似文献
32.
The minimal supersymmetric standard model with soft breaking has a large landscape of supersymmetric particle mass hierarchies. This number is reduced significantly in well-motivated scenarios such as minimal supergravity and alternatives. We carry out an analysis of the landscape for the first four lightest particles and identify at least 16 mass patterns, and provide benchmarks for each. We study the signature space for the patterns at the CERN Large Hadron Collider by analyzing the lepton+ (jet> or =2) + missing P{T} signals with 0, 1, 2, and 3 leptons. Correlations in missing P{T} are also analyzed. It is found that even with 10 fb{-1} of data a significant discrimination among patterns emerges. 相似文献
33.
Francescone David Akula Sujeet Altunkaynak Baris Nath Pran 《Journal of High Energy Physics》2015,2015(1):1-48
Journal of High Energy Physics - We consider the AdS 2 /CFT 1 holographic correspondence near the horizon of rotating five-dimensional black holes preserving four supersymmetries in $$... 相似文献
34.
Archana Chaudhary Ram Gopal Meena Nagar Rakesh Bohra 《Journal of Sol-Gel Science and Technology》2014,69(1):102-106
Some oxime modified complexes of the type [Zr{OPri}4?n{L}n] {where, n = 1–4 and LH=(CH3)2C=NOH (1–4) and C9H16C=NOH (5–8)} have been synthesized by the reaction of [Zr(OPri)4·PriOH] with oximes, in anhydrous refluxing benzene. These synthesized complexes were characterized by elemental analyses, molecular weight measurements, ESI-mass, FT-IR and NMR (1H and 13C{1H}) spectral studies. The ESI-mass spectral studies indicate dimeric nature for [Zr{OPri}2{ONC(CH3)2}2] (2), [Zr{OPri}3{ONC10H16}] (5) and [Zr{OPri}{ONC10H16}3] (7) and monomeric nature for [Zr{ONC10H16}4] (8). Oximato ligands appear to bind the zirconium in side on manner in all the complexes. Thermogravimetric curves of (2) and (8) exhibit multi-step decomposition with the formation of ZrO2, under nitrogen atmosphere. Sol–gel transformations of precursors (5), (6), (7) and (8) in organic medium, yielded nano-sized tetragonal phase of zirconia samples (a), (b), (c) and (d), respectively, on sintering at ~600 °C. All these samples were characterized by Powder XRD patterns and EDX analyses. Surface morphologies of these samples were investigated by SEM images. 相似文献
35.
Gopal Lamichhane Prakash Raj Pandeya Ramakanta Lamichhane Su-jin Rhee Hari Prasad Devkota Hyun-Ju Jung 《Molecules (Basel, Switzerland)》2022,27(3)
Background: Ponciri Fructus, a crude drug consisting of the dried immature fruits of Poncirus trifoliata (L.) Raf., is a popular folk medicine used for the treatment of allergy and gastrointestinal disorders in Korea and China. In this study, the anti-adipogenic activity of extracts and isolated compounds were evaluated using 3T3-L1 preadipocytes. Methods: Dried immature fruits were extracted and fractionated into n-hexane, ethyl acetate (EtOAc), n-butanol and water-soluble fractions. The ethanol extract and fractions were tested for anti-adipogenic activity in the 3T3-L1 cell line. The active fractions (n-hexane and EtOAc fractions) were further subjected to chromatographic techniques to isolate and identify active compounds. Furthermore, the isolated compounds were evaluated for their anti-adipogenic activity. Results: Altogether, seven compounds, including two flavonoids, one phytosteroid and four coumarin derivatives, were isolated. Ethanol extract, n-hexane fraction, EtOAc fraction and three isolated compounds (phellopterin, oxypeucedanin and poncirin) showed significant anti-adipogenic activity as observed by reduced lipid deposition in differentiated 3T3-L1 cells. Further, oxypeucedanin downregulated the key adipogenic markers, such as peroxisome proliferator-activated receptors proteins γ (PPAR-γ), sterol response element binding proteins-1 (SREBP-1), CCAAT/enhancer binding proteins-α (C/EBP-α), adipocyte-specific lipid binding proteins (FABP-4), adipocyte fatty acid binding proteins (aP2), lipoprotein lipase (LPL) and leptin. Conclusion: This study indicated that the ethanol extract, hexane fraction and ethyl acetate fraction of P. trifoliata fruits possess strong anti-adipogenic activity, containing the active compounds such as phellopterin, oxypeucedanin and poncirin. Further research is recommended to explore their efficacy and safety in animal and clinical models. 相似文献
36.
Gopal Krishan M. S. Rao C. P. Kumar Prabhat Semwal 《Journal of Radioanalytical and Nuclear Chemistry》2015,303(3):2221-2225
37.
The effect of pressure on the conductivity of fast ion conducting AgI-Ag2O-MoO3 glasses has been investigated down to 150 K. The observed variation of conductivities appears to support the application
of cluster model to the ionic glasses.
Contribution No. 258 from the Solid State and Structural Chemistry Unit. 相似文献
38.
39.
40.
Electrical resistance measurements are reported for amorphous In20Te80 and Cu25Au5Te70 alloys up to a pressure of 80 Kbar using a Bridgman anvil apparatus and a four lead arrangement to measure resistances. The amorphous samples are produced by liquisol quenching. The resistance shows time dependent changes which are analysed in detail. The contention that there is a pressure-induced transformation from the amorphous to the crystalline phase is confirmed by X-ray diffraction of samples recovered after they were pressurised to 35 Kbar in a hydrostatic environment. 相似文献