全文获取类型
收费全文 | 254篇 |
免费 | 10篇 |
国内免费 | 1篇 |
专业分类
化学 | 185篇 |
晶体学 | 5篇 |
力学 | 5篇 |
数学 | 12篇 |
物理学 | 58篇 |
出版年
2024年 | 1篇 |
2023年 | 2篇 |
2022年 | 5篇 |
2021年 | 4篇 |
2020年 | 6篇 |
2019年 | 15篇 |
2018年 | 7篇 |
2017年 | 4篇 |
2016年 | 14篇 |
2015年 | 12篇 |
2014年 | 16篇 |
2013年 | 14篇 |
2012年 | 21篇 |
2011年 | 24篇 |
2010年 | 8篇 |
2009年 | 9篇 |
2008年 | 13篇 |
2007年 | 16篇 |
2006年 | 7篇 |
2005年 | 9篇 |
2004年 | 3篇 |
2003年 | 3篇 |
2002年 | 8篇 |
2001年 | 2篇 |
2000年 | 6篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 4篇 |
1989年 | 1篇 |
1987年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1977年 | 1篇 |
1972年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有265条查询结果,搜索用时 0 毫秒
261.
Carbon quantum dots (CQDs) are a new class of fluorescence small carbon nanoparticles with a particle size of less than 10 nm and have vast applications in the field of bioimaging, biosensing and disease-detection. These are promising materials for nano-biotechnology since it has smaller particle size, excellent biocompatibility and excitation wavelength dependent photoluminescence (PL) behavior, photo induced electron transfer, chemical inertness and low toxicity. These materials have excellent fluorescent properties such as broad excitation spectra, narrow and tunable emission spectra, and high photostability against photo bleaching and blinking than other fluorescent semiconductor quantum dots. This review article demonstrate the recent progress in the synthesis, functionalization and technical applications of carbon quantum dots using electrochemical oxidation, combustion/thermal, chemical change, microwave heating, arc-discharge, and laser ablation methods from various natural resources. Natural carbon sources are used for the preparation of CQDs due to its low cost, environmental friendly and widely available. 相似文献
262.
Chen G Pramanik BN Bartner PL Saksena AK Gross ML 《Journal of the American Society for Mass Spectrometry》2002,13(11):1313-1321
Electrospray ionization (ESI) quadrupole ion-trap tandem mass spectrometry (MS/MS) was utilized to characterize a class of complex oligosaccharide antibiotics (everninomicins) that include SCH 27899, everninomicin-D, amino everninomicin (SCH 27900), and SCH 49088 (containing a hydroxylamino-ether sugar). The addition of sodium chloride (approximately 1 microg/mL) facilitates the formation of abundant metal complex ions, and this was used because protonation does not readily occur for most of these compounds. The multiple-stage mass analysis (MS(n)) of the sodiated species provides an important series of fragment ions that are specific for sugar sequence and for some sugar-ring opening. These data suggest a general charge-remote fragmentation pattern with the sodium cation residing in a specific, central location of the sugar chain and fragmentation occurring to trim the end of the molecule. For protonated everninomicin (SCH 27900), however, the proton appears to be mobile during the collisional activation process, opening different fragmentation pathways depending on the proton location. The use of water and acetonitrile with 0.1% acetic acid as the solvent in ESI-MS promotes rapid hydrolysis of the central ortho ester, resulting in the formation of abundant sodiated products that are hydrated. These product ions of the hydrated molecules are likely formed by the same charge-remote fragmentation processes as those that occur for the unhydrolyzed precursor. 相似文献
263.
Cladek Laura Henriot Kevin Krause Ben Łaba Izabella Pramanik Malabika 《Mathematische Zeitschrift》2018,289(3-4):1033-1057
Mathematische Zeitschrift - Consider the discrete maximal function acting on finitely supported functions on the integers, $$begin{aligned} mathcal {C}_Lambda f(n) := sup _{lambda in Lambda... 相似文献
264.
Das PK Pramanik R Bagchi S 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2003,59(8):1681-1688
Solvation characteristics in homogeneous and heterogeneous media have been probed by monitoring the band width of ICT band of 2,6-di-phenyl-4(2,4,6-triphenyl-1-pyridino) phenolate, the indicator solute for E(T)(30) scale, in pure, mixed binary solvents and aqueous micellar solution. Non-ideal solvation behaviour is observed in all the binary solvent mixtures. Index of preferential solvation has been calculated as a function of solvent composition. Study in micellar media indicates that the dye is located at the micelle-water interface. The effects of variation of micelle concentration, temperature and electrolyte concentration have also been studies. 相似文献
265.
An easy and inexpensive method has been developed to access 1,2-disubstituted benzimidazoles following a one-pot sequential coupling/reduction/cyclization process under metal-free neutral conditions. 相似文献