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171.
We obtain L2 decay estimates in λ for oscillatory integral operators Tλ whose phase functions are homogeneous polynomials of degree m and satisfy various genericity assumptions. The decay rates obtained are optimal in the case of (2+2)-dimensions for any m, while in higher dimensions the result is sharp for m sufficiently large. The proof for large m follows from essentially algebraic considerations. For cubics in (2+2)-dimensions, the proof involves decomposing the operator near the conic zero variety of the determinant of the Hessian of the phase function, using an elaboration of the general approach of Phong and Stein [D.H. Phong, E.M. Stein, Models of degenerate Fourier integral operators and Radon transforms, Ann. of Math. (2) 140 (1994) 703-722]. 相似文献
172.
Aggregates of hexaphenylbenzene derivatives 3, having pyrene groups form network of fluorescent nanofibres in presence of mercury ions. Further, fluorescent nanofibres of 3-Hg2+ supramolecular ensemble exhibit sensitive and pronounced response towards the picric acid. In addition, the solution coated paper strips of 3-Hg2+ supramolecular ensemble can detect picric acid in the range of 2.29 fg/cm2, thus, providing a simple, portable and low cost method for detection of picric acid in solution and in contact mode. 相似文献
173.
Abhishek Pramanik Dr. Samit Majumder Rampada Das Prof. Sasankasekhar Mohanta 《欧洲无机化学杂志》2023,26(22):e202300058
A fluorescent dinuclear cadmium(II) based discrete metal complex of composition [CdII2L(μ-Cl)Cl2]( 1 ) is used {HL=2,6-bis[2-(methylamino)ethyliminomethyl]-4-Ethylphenol} for the specific recognition of 2,4,6-trinitrophenol (picric acid; PA) via fluorescence quenching phenomenon among various nitroaromatic compounds through a chemodosimetric approach. It has been established that 1 is a chemodosimeter in pure water. We have successfully been able to isolate three compounds: chemodosimeter 1 ; an intermediate complex 2 of composition [CdII(LH2)Cl2](Picrate) and final association complex 3 of composition [NH3(CH2CH2)NH2CH3](Picrate)2. Compounds have been characterised by CHN elemental analyses, single crystal X-ray crystallography, PXRD, NMR and FTIR. Selective interaction of 1 with PA was evaluated by fluorescence, UV-Vis and life time measurements. Fluorescence quenching of 1 occurs definitely due to the formation of compound 3 via intermediate 2 involving partial decomplexation, hydrolysis and proton transfer phenomena in solution during the course of sensing. The quenching constant (Ksv), association constant (Ka) and detection limit (LOD) of the complex 1 for picric acid are ∼1.55×105 M−1, ∼1.8×1010 M−2 and ∼0.47 μM (0.108 ppm), respectively. Mechanism of sensing is proposed and the very rare case of isolation and characterization of intermediate in picric acid sensing is discussed. 相似文献
174.
175.
Dinda Soumitra Sarkar Koushik Panda Bikash Kumar Pramanik Kausikisankar Ganguly Sanjib 《Transition Metal Chemistry》2022,47(1):31-38
Transition Metal Chemistry - By using a multifunctional diarylazooxime ligand LNOH 1, incorporating electron deficient azo chromophore in conjunction with a pendant π-electron-rich naphthyl... 相似文献
176.
A magnetically separable core–shell CoFe2O4@SiO2‐SO3H nanocatalyst has been successfully exploited as a heterogeneous acid catalyst in the synthesis of diversely substituted biologically important spiro fused pyrrolo/indolo[1,2‐a]quinoxaline derivatives through the condensation of N‐(2‐aminophenyl)pyrroles/indoles and various cyclic conjugated 1,2‐diones in ethanol under ultrasonic irradiation. Room temperature synthesis, short reaction time, wide substrate scope, good to excellent yield of products and use of a magnetically separable and recyclable nanocatalyst make this method attractive and practicable. 相似文献
177.
Arjunolic acid, the major extractable constituent of the heavy wood ofTerminalia Arjuna, has the potential to be used as a rigid and functional molecular framework for the construction of nanosized supramolecular
architectures and nanomaterials. The nanosized triterpenoid, arjunolic acid, showed efficient gelation of various organic
solvents at low concentrations. The low molecular mass gelator molecules self-assembled in the solvents to form fibers of
nanometer diameters. The movement of the solvent molecules was hindered inside the fibrous network leading to the formation
of a gel 相似文献
178.
179.
A. Goswami M. Saha Sarkar U. Datta Pramanik P. Banerjee P. Basu P. Bhattacharya S. Bhattacharya M. L. Chatterjee S. Sen B. Dasmahapatra 《Zeitschrift für Physik A Hadrons and Nuclei》1995,353(3):231-232
The level structure of104Ag has been studied through the103Rh (α, 3nγ) reaction at Eα=40 and 45 MeV. The principal features of the proposed level scheme are in agreement with those obtained earlier through heavy ion reaction. Two quasiparttcle-plus-rotor model calculation has been performed, and the results are compared with experimental data. 相似文献
180.
We have deposited relatively thick (∼60 nm) Ge layers on Br-passivated Si(111) substrates by thermal evaporation under high
vacuum conditions at room temperature. Ge has grown in a layer-plus-island mode although it is different from the Stranski-Krastanov
growth mode observed in epitaxial growth. Both the islands and the layer are nanocrystalline. This appears to be a consequence
of reduction of surface free energy of the Si(111) substrate by Br-passivation. The size distribution of the Ge nanoislands
has been determined. The Br-Si(111) substrates were prepared by a liquid treatment, which may not produce exactly reproducible
surfaces. Nevertheless, some basic features of the nanostructural island growth are reasonably reproducible, while there are
variations in the details of the island size distribution. 相似文献