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排序方式: 共有291条查询结果,搜索用时 15 毫秒
91.
A. Sánchez A. Zapardiel F.López de Prado E. Bermejo M. Moreno J. A. Pérez‐López M. Chicharro 《Electroanalysis》2007,19(16):1683-1688
A new analytical methodology for the electrochemical detection of the herbicide maleic hydrazide (3,6‐dihydroxypyridazine) by flow injection analysis is presented. This method is supported by the novel application of a palladium‐dispersed carbon paste electrode as an amperometric sensor for this herbicide. Maleic hydrazide shows anodic electrochemical activity on carbon‐based electrodes (glassy carbon or carbon paste electrodes) in all the pH range. This electrochemical activity is enhanced using metal‐dispersed carbon paste electrodes, especially at Pd‐dispersed CPE which displays good oxidation signals at 690 mV (0.050 M phosphate buffer pH 7.0), 140 mV lower than at unmodified electrodes. Under the optimized conditions, the electroanalytical performance of Pd‐dispersed CPE in flow injection analysis was excellent, with good reproducibility (RSD 3.3%) and a wide linear range (1.9×10?7 to 1.0×10?4 mol L?1). A detection limit of 1.4×10?8 mol L?1 (0.14 ng maleic hydrazide) was obtained for a sample loop of 100 μL at a fixed potential of 700 mV in 0.050 M phosphate buffer solution at pH 7.0 and a flow rate of 2.0 mL min?1. The proposed method was applied for the maleic hydrazide detection in natural drinking water samples. 相似文献
92.
The herbicide 4-amino-3,5,6-trichloropicolinic acid (picloram), chemically anchored on silica gel surface (SiPi), has been used for divalent cation M(2+) (Cu, Ni, Zn, and Cd) adsorption from aqueous solutions at room temperature. The series of adsorption isotherms were adjusted to a modified Langmuir equation from data obtained by suspending the solid with MCl(2) solutions, which gave the maximum number of moles adsorbed as 9.27, 7.54, 5.12, and 1.54 x 10(-4) molg(-1) for Cu, Ni, Zn, and Cd, respectively. The minimum cation retention capacity from aqueous solution was observed at pH 1, increasing up to pH 4, and was maintained constant at pH 5 for all cations. The maximum retention capacity followed the sequence Cu>Ni>Zn>Cd. SiPi-M (Cu, Ni) interactions presented endothermic enthalpic values, which contrasted with exothermic values for SiPi-M (Zn, Cd) interactions. The anchored herbicide was also used to separate the cations when loaded in a column. Their resolutions were determined as the ability of this surface to separate cations, to give Rs(Cd-Zn)=2.33, Rs(Cd-Ni)=3.16, Rs(Cd-Cu)=7.21, Rs(Zn-Ni)=1.31, Rs(Zn-Cu)=2.55, and Rs(Ni-Cu)=0.72. 相似文献
93.
This work was aimed at identifying nucleotide polymorphic sites in a 359 bp region of the cytochrome b (cytb) mitochondrial gene of Iberian cattle (Bos taurus). This region is widely used as target in polymerase chain reaction-restriction fragment length polymorphism (PCR-RFLP) species identification studies in foodstuffs destined for human and animal consumption. Two different coexisting restriction patterns were observed in four of the six animals studied when the 359 bp DNA fragment was cleaved with PalI, HinfI, MvaI, RsaI, or MboI. The amplification of both genotypes with the mitochondrial-specific primers L14735 and H15149 revealed the absence of nuclear pseudo-cytb genes, confirming the existence of mitochondrial heteroplasmy. The two coexisting mtDNA fragments were selectively sequenced in PCR extracts in which one genotype predominated over the other, both exhibiting a sequence variation of 10.4%. From the 37 nucleotide mismatches observed between genotypes, 32 were transitions and five were transversions. While 31 of the nucleotide mismatches between genotypes resulted to be conservative at the amino acid level, six changes implied amino acid substitutions, five of them being located in the variable transmembrane region. Genetic analysis suggests the presence of an Asian background in the mitochondria of Iberian cattle: while one of the genotypes matched the published sequence for Bos taurus, the other genotype clustered with a B. primigenius indicus animal and close to an Asian Bos taurus animal. These results also suggest that a number of current PCR-RFLP species identification methods based on cytb sequences may not be reliable for the accurate detection and identification of bovine material: an alternative battery of enzymes consisting of MmeI, NlaIV, and AluI is proposed. 相似文献
94.
Igor V. Mastikhin Bruce J. Balcom Pablo J. Prado Christopher B. Kennedy 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1999,136(2):159
A technique for imaging materials with short transverse relaxation times and prepared longitudinal magnetization is proposed. The technique is single-point ramped imaging withT1-enhancement (SPRITE) MRI with centrick-space sampling. The effects of transient state behavior on image resolution and signal/noise are estimated. Centric sampling in the basic SPRITE sequence gives increased signal-to-noise and permits a quantitative determination of the MR parameters associated with longitudinal spin preparation. Spin-lock and inversion recovery preparation experiments are presented. 相似文献
95.
Luís A. S. De A. Prado Eduardo Radovanovic Heloise O. Pastore Inez V. P. Yoshida Iris L. Torriani 《Journal of polymer science. Part A, Polymer chemistry》2000,38(9):1580-1589
Poly(phenylsilsesquioxane) (PPSQ) polymers that were obtained from different synthetic routes were comparatively studied. The polymers were characterized by infrared and solid‐state 29Si NMR spectroscopies. According to the results of X‐ray diffraction and thermogravimetric analyses, the materials richest in silanol showed a less organized network and lower weight loss temperature. The morphology of the products was influenced by the preparation conditions. PPSQ, with a morphology rich in spherical particles, was achieved with an n‐hexadecyltrimethylammonium bromide template in the reaction medium, whereas the morphology of this polymer obtained in the absence of the template was featureless. Small‐angle X‐ray scattering analyses revealed that the PPSQ samples showed a predominance of surface‐fractal behavior. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 1580–1589, 2000 相似文献
96.
97.
The Babichev–Dokuchaev–Eroshenko model for the accretion of dark energy onto black holes has been extended to deal with black holes with non-static metrics. The possibility that for an asymptotic observer a black hole with large mass will rapidly increase and eventually engulf the Universe at a finite time in the future has been studied by using reasonable values for astronomical parameters. It is concluded that such a phenomenon is forbidden for all black holes in quintessential cosmological models. 相似文献
98.
99.
Prado Martín-Moruno Az-Eddine L. Marrakchi Salvador Robles-Pérez Pedro F. González-Díaz 《General Relativity and Gravitation》2009,41(12):2797-2811
In this paper we study the accretion of dark energy onto a black hole in the cases that dark energy is equipped with a positive
cosmological constant and when the space-time is described by a Schwarzschild-de Sitter metric. While the first case is the
same as the usual accretion procedure for a more complicated fluid, the second one give rise to a consistent cosmic scenario
for the mentioned phenomenon. 相似文献
100.
WANG Yue BI Xiao-Jun CUI Shu-Wang DING Lin-Kai DAN Zeng-Luo-Bu DING Xiao-Hong FAN Chao FENG Cun-Feng FENG Zhao-Yang FENG Zhen-Yong GAO Xiao-Yu GENG Qing-Xi GUO Hong-Wei HE Hui-Hai HE Mao HU Hai-Bing HU Hong-Bo HUANG Qing JIA Huan-Yu LA Ba-Ci-Ren LE Gui-Ming LI Ai-Feng LI Jin-Yu LOU Yu-Qing LU Hong LU Sui-Ling MENG Xian-Ru MU Jun REN Jing-Ru TAN You-Heng WANG Bo WANG Hui WANG Yong-Gang WU Han-Rong XUE Liang YANG Xian-Chu YE Zong-Hai YU Guang-Ce YUAN Ai-Fang ZHANG Hui-Min ZHANG Ji-Long ZHANG Nai-Jian ZHANG Xue-Yao ZHANG Yong ZHANG Yi ZHA Xi-Sang-Zhu ZHOU Xun-Xiu YUAN Qiang 《中国物理C(英文版)》2008,32(11)
Using the data taken from Tibet Ⅱ High Density (HD) Array (1997 February--1999 September) and Tibet-Ⅲ array (1999 November--2005 November), our previous northern sky survey for TeV γ-ray point sources has now been updated by a factor of 2.8 improved statistics. From 0.0° to 60.0° in declination (Dec) range, no new TeV γ-ray point sources with sufficiently high significance were identified while the well-known Crab Nebula and Mrk421 remain to be the brightest TeV T-ray sources within the field of view of the Tibet air shower array. Based on the currently available data and at the 90% confidence level (C.L.), the flux upper limits for different power law index assumption are re-derived, which are approximately improved by 1.7 times as compared with our previous reported limits. 相似文献