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921.
Applying tight-binding approximation and spin pairing of like charge carriers in a pair of excitons created in a lattice, the possibility of forming a bound exciton-exciton state is studied. It is found that, provided there exists strong exciton-lattice interaction, such a bound state may be formed and its energy may lie within the valence band deforming the material into a crystalline solid with no energy gap. Lowering of the energy is calculated in naphthalene and anthracene crystals where some experimental results are known. The excess energy released after the formation of such bound state can be adequate, depending on the material, to desorb neutral atoms or eject of electrons from surfaces. 相似文献
922.
We utilize the unifying framework of families of convexity spaces for the treatment of various notions of planar convexity and the associated convex hulls. Our major goal is to prove the refinement and decomposition theorems for families of convexity spaces. These general theorems are then applied to two examples: restricted-oriented convex sets andNESW-convex sets. The applications demonstrate the usefulness of these general theorems, since they give rise to simple algorithms for the computation of the associated convex hulls of polygons. 相似文献
923.
Using the symbolic computation program MAPLE, we compute several terms of an asymptotic expansion for the distribution function of the logistic midrange. 相似文献
924.
925.
O. V. Gusev V. V. Krivykh P. V. Petrovskii M. I. Rybinskaya 《Russian Chemical Bulletin》1987,36(7):1532-1534
Conclusions The allyl ligand in neutral molybdenum and cobalt complexes is readily exchanged by dienes in the presence of a strong protic acid with the formation of cationic complexes. This exchange is facilitated by an increase in the basicity of the starting compounds.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1655–1657, July, 1987. 相似文献
926.
927.
Population balance equations combined with a three-dimensional two-fluid model are employed to predict subcooled boiling flow at low pressure in a vertical annular channel. The MUSIG (MUltiple-SIze-Group) model implemented in the computer code CFX4.4 is further developed to accommodate the wall nucleation at the heated wall and condensation in the subcooled boiling regime. Comparison of model predictions against local measurements is made for the void fraction, bubble Sauter mean diameter and gas and liquid velocities covering a range of different mass and heat fluxes and inlet subcooling temperatures. Additional comparison using empirical relationships for the active nucelation site density and local bubble diameter is also investigated. Good agreement is achieved with the local radial void fraction, bubble Sauter diameter and liquid velocity profiles against measurements. However, significant weakness of the model is evidenced in the prediction of the vapour velocity. Work is in progress to circumvent the deficiency through the consideration of additional momentum equations or developing an algebraic slip model to account for bubble separation. 相似文献
928.
Donald J. Wink 《Foundations of Chemistry》2006,8(2):111-151
The rich and ongoing debate about constructivism in chemistry education includes questions about the relationship, for better or worse, between applications of the theory in pedagogy and in epistemology. This paper presents an examination of the potential to use connections of epistemological and pedagogical constructivism to one another. It examines connections linked to the content, processes, and premises of science with a goal of prompting further research in these areas. 相似文献
929.
O. V. Bakbardina I. Yu. Pukhnyarskaya M. A. Gazalieva S. D. Fazylov E. M. Makarov 《Russian Journal of Applied Chemistry》2006,79(10):1726-1728
S-Amino derivatives of O-alkyldithiocarbonic acid were prepared by oxidative condensation of certain alkaloids with sodium xanthates. Some of the compounds synthesized exhibit fungicidal activity. 相似文献
930.
A. P. Avdeenko S. A. Konovalova O. N. Ludchenko 《Russian Journal of Organic Chemistry》2006,42(5):683-688
Reactions of halogens with N-arylsulfonyl-1,4-benzoquinone monoimines occur with the formation of a halogenonium ion that either transforms into a carbocation where the first halogen atom adds to the carbon in the ortho-position relative to the carbonyl carbon, or the halogenonium ion adds directly the second halogen atom. 相似文献