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81.
Pickering AL Mitterbauer C Browning ND Kauzlarich SM Power PP 《Chemical communications (Cambridge, England)》2007,(6):580-582
Capped boron nanoparticles have been synthesized at room temperature by a simple route that does not involve the use of flammable boranes. 相似文献
82.
We show that planar embeddable -connected Laman graphs are generically non-soluble. A Laman graph represents a configuration of points on the Euclidean plane with just enough distance specifications between them to ensure rigidity. Formally, a Laman graph is a maximally independent graph, that is, one that satisfies the vertex-edge count together with a corresponding inequality for each subgraph. The following main theorem of the paper resolves a conjecture of Owen (1991) in the planar case. Let be a maximally independent -connected planar graph, with more than 3 vertices, together with a realisable assignment of generic distances for the edges which includes a normalised unit length (base) edge. Then, for any solution configuration for these distances on a plane, with the base edge vertices placed at rational points, not all coordinates of the vertices lie in a radical extension of the distance field.
83.
84.
Mark Niemeyer Philip P. Power 《Angewandte Chemie (International ed. in English)》1998,37(9):1277-1279
A “one-legged thallium” is observed in the arylthallium(I ) compound 2,6-Trip2C6H3Tl (Trip=2,4,6-iPr3C6H2), which was synthesized from the corresponding organolithium compound and thallium chloride. X-ray structure analysis reveals that 2,6-Trip2C6H3Tl is monomeric in the solid state and contains a singly coordinated thallium atom (see space-filling model on the right). 相似文献
85.
The minimum-uncertainty states for systems with many degrees of freedom are investigated. The limiting situation, relevant to the electromagnetic field, is discussed and it is pointed out that the states that minimize Δp Δq do not tend to the coherent states. These latter, including the vacuum state, are minimum-uncertainty states for the transverse electric and magnetic fields. In an appendix a direct method to obtain the wave functional for the vacuum is presented. 相似文献
86.
李应求 《数学年刊A辑(中文版)》2003,(4)
在随机环境中马氏链的研究领域,引入了一类π-不可约、常返和瞬时性的概念,给出了π-不可约链是瞬时链的一个充要条件,引入了双无限随机环境中马氏链不变函数的概念,讨论了它们的存在性及基本性质。最后,利用不变函数的性质,给出了π-不可约链是瞬时链的一个判别准则,此准则与不变函数有关。 相似文献
87.
在交叉缔合的均相状态方程的基础上,结合密度梯度理论(density gradient theory,DGT),建立了适用于CO2-甲醇和CO2-乙醇二元体系界面性质研究的状态方程,对CO2-乙醇体系表面张力的关联结果与实验值吻合良好.阐明了CO2分子与甲醇分子和乙醇分子之间的交叉缔合作用对二元体系表面张力计算结果的影响,以及界面相中CO2与醇羟基之间的交叉缔合与温度和压力之间的关系. 相似文献
88.
The use of novel water-in-oil microemulsions in microemulsion electrokinetic chromatography 总被引:3,自引:0,他引:3
We describe the novel use of water-in-oil (W/O) microemulsions to achieve unique separations in microemulsion electrokinetic chromatography (MEEKC). The choice and concentration of the buffer type, surfactant and co-surfactant were all examined and optimized. Separations of a range of neutral and acidic analytes was shown to be markedly different to that obtained by (oil-in-water) O/W MEEKC. Neutral solutes are separated by virtue of their solubility (log P) values in O/W MEEKC with the more water-insoluble solutes migrating last. This separation process does not occur in W/O, as neutral solutes are not separated in order of log P. 相似文献
89.
90.
Tong Xiaojiao Zhou Shuzi Dept. of Appl.Math. Hunan Univ. Changsha . Dept.of Math. Changsha Univ.of Electric Power Changsha 《高校应用数学学报(英文版)》2000,(2)
§ 1 IntroductionIn this paper we study the following nonlinear equality constrained optimization prob-lem:minimize f(x) ,subjectto h(x) =0 ,(P)where h(x) =(h1 (x) ,h2 (x) ,...,hm(x) ) T,f and hi(i=1 ,2 ,...,m) are Rn→R twice conti-nously differentiable(m≤n) .Many authors have studied the problem(P) with trustregion method(see,references[1~ 3 ] ) .These methods have the same property:to enforce strict monotonicity for meritfunction at every iteration.Paper[4 ] shows thatstrictmonotonic … 相似文献