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51.
Susruta Majumdar 《合成通讯》2013,43(23):3537-3548
We report a novel synthesis of N‐alkyl‐N‐alkyloxycarbonylaminomethyl (NANAOCAM) prodrugs of acetaminophen, theophylline, and 6‐mercaptopurine by alkylation of the corresponding drug molecule with N‐alkyl‐N‐alkyloxycarbonylaminomethyl chlorides in good yield. Most of the alkylating agents were efficiently synthesized by chloromethylation of N‐alkyl carbamic acid alkyl esters, which in turn were made from alkyl amines and alkyl chloroformates. In cases where the alkyl chloroformates were not available, synthesis of N‐alkyl carbamic acid alkyl esters was accomplished by converting an alcohol to a chloroformate or to an activated acylating agent such as acyl imidazoles or p‐nitrophenylcarbonate esters, followed by their reaction with alkyl amines. 相似文献
52.
The present paper reports for the first time an exact analytic expression that can be used for obtaining fracture stress σF, when fracture occurs in the elastic limit and also when fracture occurs after general yield (σF > σY) in a brittle solid. The present paper may provide a new basis to fracture-safe design of brittle materials. 相似文献
53.
AC Conduction and Time–Temperature Superposition Scaling in a Reduced Graphene Oxide–Zinc Sulfide Nanocomposite
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Koushik Chakraborty Poulomi Das Sankalpita Chakrabarty Dr. Tanusri Pal Dr. Surajit Ghosh 《Chemphyschem》2016,17(10):1518-1523
We report, herein, the results of an in depth study and concomitant analysis of the AC conduction [σ′(ω): f=20 Hz to 2 MHz] mechanism in a reduced graphene oxide–zinc sulfide (RGO–ZnS) composite. The magnitude of the real part of the complex impedance decreases with increase in both frequency and temperature, whereas the imaginary part shows an asymptotic maximum that shifts to higher frequencies with increasing temperature. On the other hand, the conductivity isotherm reveals a frequency‐independent conductivity at lower frequencies subsequent to a dispersive conductivity at higher frequencies, which follows a power law [σ′(ω)∝ωs] within a temperature range of 297 to 393 K. Temperature‐independent frequency exponent ′s′ indicates the occurrence of phonon‐assisted simple quantum tunnelling of electrons between the defects present in RGO. Finally, this sample follows the “time–temperature superposition principle”, as confirmed from the universal scaling of conductivity isotherms. These outcomes not only pave the way for increasing our elemental understanding of the transport mechanism in the RGO system, but will also motivate the investigation of the transport mechanism in other order–disorder systems. 相似文献
54.
V. N. Singh P. Majumdar 《The European Physical Journal B - Condensed Matter and Complex Systems》2011,83(2):147-155
In addition to the well known ferromagnetism, double perovskites are also
expected to exhibit antiferromagnetic (AF) order driven by electron
delocalisation. This has been seen in model Hamiltonian studies and confirmed
via ab initio calculations. The AF phases should occur, for example, on
sufficient electron doping of materials like Sr2FeMoO6 (SFMO) via La
substitution for Sr. Clear experimental indication of such AF order is limited,
possibly because of increase in antisite disorder with La doping on SFMO,
although intriguing signatures of non ferromagnetic behaviour are seen. We
study the survival of electronically driven antiferromagnetism in the presence
of spatially correlated antisite disorder in a two dimensional model
and extract the signals in magnetism
and transport. We discover that A and G type AF order, that is predicted in
the clean limit, is actually suppressed less strongly than ferromagnetism
by antisite disorder. The AF phases are metallic, and, remarkably, more conducting
that the ferromagnet for similar antisite disorder. We also highlight the phase
coexistence window that connects the ferromagnetic regime to the A type
antiferromagnetic phase, and comment on the situation in three dimensions. 相似文献
55.
A.P. Srivastava D. Srivastava K. Sudarshan S.K. Sharma P.K. Pujari B. Majumdar K.G. Suresh G.K. Dey 《Journal of magnetism and magnetic materials》2012
Amorphous ribbons of different thicknesses of Co64.5Fe3.5Si16B14Ni2 alloy were synthesized using the melt spinning technique by varying wheel speed. The effect of cooling rate on the ribbon thickness and their soft magnetic properties have been studied. The amorphous structure has been characterized in terms of structural free volume and medium range order (MRO) by positron annihilation spectroscopy and fluctuation electron microscopy techniques. Positron lifetime spectra of amorphous samples showed two lifetime components. The first component was found to be correlated with MRO whereas, the second lifetime component was found to be associated with nanovoid type of defects, and the second component was strongly dependent on processing conditions. It could be established that the coercivity of the amorphous samples produced by the rapid solidification technique mainly depends on the defects formed during processing rather than change induced in MRO. 相似文献
56.
Motivated by a computer science algorithm known as "linear probing with hashing," we study a new type of percolation model whose basic features include a sequential "dropping" of particles on a substrate followed by their transport via a "pushing" mechanism. Our exact solution in one dimension shows that, unlike the ordinary random percolation model, the drop-push model has nontrivial spatial correlations generated by the dynamics itself. The critical exponents in the drop-push model are also different from those of the ordinary percolation. The relevance of our results to computer science is pointed out. 相似文献
57.
Under a notion of splitting the existence of a unique invariant probability, and a geometric rate of convergence to it in an appropriate metric, are established for Markov processes on a general state space S generated by iterations of i.i.d. maps on S. As corollaries we derive extensions of earlier results of Dubins and Freedman;(17) Yahav;(30) and Bhattacharya and Lee(6) for monotone maps. The general theorem applies in other contexts as well. It is also shown that the Dubins–Freedman result on the necessity of splitting in the case of increasing maps does not hold for decreasing maps, although the sufficiency part holds for both. In addition, the asymptotic stationarity of the process generated by i.i.d. nondecreasing maps is established without the requirement of continuity. Finally, the theory is applied to the random iteration of two (nonmonotone) quadratic maps each with two repelling fixed points and an attractive period-two orbit. 相似文献
58.
Flows in a gas-agitated reactor have been predicted by a finite difference procedure. The free-convection phenomena in the gas-liquid mixtures have been accounted for by the calculation of a void fraction determined from the gas flow rate. Computations have been performed for two different situations: first, with the allowance of slip between gas and liquid phases, and second, without any slip. Reasonable agreement has been achieved between the measurements. 相似文献
59.
Summary Silver can be separated as its Bismuthiol II complex from OsO4
4
2–
, Os4+, Ir4+, Ru3+, Rh3+ with thiosulphate or complexone III as the masking agent at a pH between 5 and 9. Au3+ can be kept in solution only by thiosulphate at a pH 8–9 and cyanide complexes palladium at a PH of about 6. Separation from platinum in presence of a mixture of tartaric acid and complexone III is possible only to a limited extent.Part VI see Z. analyt. Chem. 155, 86 (1957) 相似文献
60.
We report the integration of inorganic nanotubes into metal-oxide-solution field effect transistors (FETs) which exhibit rapid field effect modulation of ionic conductance. Surface functionalization, analogous to doping in semiconductors, can switch the nanofluidic transistors from p-type to ambipolar and n-type field effect transistors. Transient study reveals the kinetics of field effect modulation is controlled by ion-exchange step. Nanofluidic FETs have potential implications in subfemtoliter analytical technology and large-scale nanofluidic integration. 相似文献