全文获取类型
收费全文 | 130篇 |
免费 | 1篇 |
专业分类
化学 | 67篇 |
晶体学 | 2篇 |
力学 | 3篇 |
数学 | 3篇 |
物理学 | 56篇 |
出版年
2021年 | 1篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2017年 | 1篇 |
2016年 | 3篇 |
2015年 | 1篇 |
2014年 | 3篇 |
2013年 | 7篇 |
2012年 | 4篇 |
2011年 | 1篇 |
2010年 | 3篇 |
2009年 | 3篇 |
2008年 | 6篇 |
2007年 | 5篇 |
2006年 | 3篇 |
2005年 | 6篇 |
2004年 | 2篇 |
2003年 | 1篇 |
2002年 | 5篇 |
2001年 | 3篇 |
2000年 | 9篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1996年 | 4篇 |
1995年 | 4篇 |
1994年 | 8篇 |
1993年 | 4篇 |
1992年 | 7篇 |
1991年 | 5篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1978年 | 1篇 |
1976年 | 2篇 |
1974年 | 2篇 |
1965年 | 2篇 |
排序方式: 共有131条查询结果,搜索用时 135 毫秒
11.
12.
A. Efraty J.A. Potenza L. Zyontz J. Daily M.H.A. Huang B. Toby 《Journal of organometallic chemistry》1978,145(3):315-327
The crystal structure on dicarbonylbis(tetraphenylcyclobutadiene)molybdenum has been determined from three-dimensional X-ray data collected by counter methods. The structure consists of monomeric units with each Mo atom bonded to two carbonyl and two Ph4C4 groups. Excluding phenyl substituents, the local symmetry about Mo is very nearly C2υ. Both cyclobutadiene (CBD) groups are asymmetrically bonded to Mo, and the spread in Mo—C(CBD) distances (2.26 to 2.38 Å;) is significantly larger than that found with other structures containing substituted cyclobutadiene groups. The carbonyl groups show several short intramolecular C?C contacts with the cyclobutadiene C atoms (2.68 to 3.03 Å;) and with each other (2.63 Å;). They appear to be wedged between the Ph4C4 groups and to be responsible for the asymmetric bonding of the cyclobutadiene groups. The mass spectrum, which shows the characteristic fragmentation pattern of cyclobutadienemetal complexes, suggests a relatively high thermal stability for the title compound. Crystallographic data are as follows: space group P21/n; unit cell a 20.15(2), b 18.82(3), c 11.03(1) Å;, β 91.59(6)°; V 4181 Å;3; dcalc for Z = 4 is 1.380 and dobs is 1.365(7) g/cm3. A total of 1659 reflections with F2 ≥ 2σ were used to refine the structure to final values of RF = 0.063 and RwF = 0.041. 相似文献
13.
Second-harmonic-generated holograms directly provide the outputs of logical gates AND and NAND operating on optical bits encoded as amplitude modulations in the object and reference wave fronts. By use of a Nd:YAG laser and a beta-barium borate crystal, we realized a real-time half-adder of two one-digit binary numbers. The feasibility of highly parallel operation is also discussed. 相似文献
14.
The problem of scattering in multimode optical fibres is treated in a rigorous way by means of both a ray and a statistical approach. These two methods are interlaced and harmonized. Applications to microbending, ellipticity, core radius and maximum numerical aperture variations, and fluctuations of index profile shape are performed. Useful results about power distribution and fibre attenuation are derived in each case. 相似文献
15.
16.
17.
18.
Z.M. Babar Wan Mohd Azizi Solachuddin JA Ichwan Qamar Uddin Ahmed Abul Kalam Azad Imranul Mawa 《Natural product research》2019,33(15):2266-2270
The current study provides a way of extraction for both active NSO and WSE from Nigella sativa seeds using 98% methanol. About 1?kg of ground seeds was macerated by 1:2.5 w/v (g/mL) for 72?hours. After rotary evaporation and 7 days of continuous drying and chilling at 50 and 4?°C, NSO and WSE were obtained at the same instant. Solubility tests of 24 solvents and 11 thin layer chromatographic analyses while 2, 2-diphenyl-1-picrylhydrazyl free radical scavenging assay of NSO (73.66) , WSE (33.32) and NSO?+?WSE (78.22) against ascorbic acid (IC50?=?4.28?mg/mL) was performed. WSE was found to be highly soluble in water and 5% NaOH exhibiting the same Rf value of 0.95 for EtOH:DMSO (9:1) against the honey. WSE has revealed more than twofold higher anti-oxidant activity than others. Formulation of WSE with Tualang honey may provide better targeted hydrophilic drug delivery systems. 相似文献
19.
Six flavonol glycosides were isolated and identified from the aerial parts of Anthyllis barba-jovis L. (Leguminosae), together with two coumarins and D-pinitol, a taxonomic marker of Leguminosae family. The structural elucidation of all compounds was based on their (1)H- and (13)C-NMR spectral data and bidimensional experiments. The total flavonoid content was also determined, according to the method described in the Italian pharmacopoeia. In order to complete the phytochemical investigation on A. barba-jovis, the essential oils from flowers and seeds were obtained by hydrodistillation and analysed by GC-MS; fresh flowers were analysed also directly by solid phase micro extraction (SPME). 相似文献
20.
Robert T. Stibrany Joseph A. Potenza 《Acta Crystallographica. Section C, Structural Chemistry》2009,65(8):o406-o409
The structures of 1H‐phenanthro[9,10‐d]imidazole, C15H10N2, (I), and 3,6‐dibromo‐1H‐phenanthro[9,10‐d]imidazole hemihydrate, C15H8Br2N2·0.5H2O, (II), contain hydrogen‐bonded polymeric chains linked by columns of π–π stacked essentially planar phenanthroimidazole monomers. In the structure of (I), the asymmetric unit consists of two independent molecules, denoted (Ia) and (Ib), of 1H‐phenanthro[9,10‐d]imidazole. Alternating molecules of (Ia) and (Ib), canted by 79.07 (3)°, form hydrogen‐bonded zigzag polymer chains along the a‐cell direction. The chains are linked by π–π stacking of molecules of (Ia) and (Ib) along the b‐cell direction. In the structure of (II), the asymmetric unit consists of two independent molecules of 3,6‐dibromo‐1H‐phenanthro[9,10‐d]imidazole, denoted (IIa) and (IIb), along with a molecule of water. Alternating molecules of (IIa), (IIb) and water form hydrogen‐bonded polymer chains along the [110] direction. The donor–acceptor distances in these N(imine)...H—O(water)...H—N(amine) hydrogen bonds are the shortest thus far reported for imidazole amine and imine hydrogen‐bond interactions with water. Centrosymmetrically related molecules of (IIa) and (IIb) alternate in columns along the a‐cell direction and are canted by 48.27 (3)°. The present study provides the first examples of structurally characterized 1H‐phenanthroimidazoles. 相似文献