Stereoselective photooxidation of enecarbamates: reactivity of ozone vs singlet oxygen

[reaction: see text]. Oxazolidinone-functionalized enecarbamates show contrasting behavior upon oxidation by singlet oxygen and by ozone. The observed stereoselectivity difference indicates that the oxidation with ozone is subject to classic steric effects, whereas the very high selectivity in the photooxidation with singlet oxygen is derived from vibrational deactivation.     

Projective embeddings of complex supermanifolds

We generalize the Kodaira Embedding Theorem and Chow's Theorem to the context of families of complex supermanifolds. In particular, we show that every family of super Riemann surfaces is a family of projective superalgebraic varieties.Research supported in part by NSF grant DMS-8704401Research supported in part by NSF grant DMS-4253943Research also supported in part by NSF grant DMS-4253943     

Algebraic recurrence relations for the finite-order scattering and transmission functions

In preceding papers (cf. Bellmanet al.(^1,2,3,), integral recurrence for the finite-order scattering and transmission functions have been given in connection with integral recurrence relations for the finite order X- and Y-functions with the aid of an initial-value method. In the present paper, it is shown how to find algebraic recurrence relations for the finite-order scattering and transmission functions in terms of finite-order X- and Y-functions without referring to an initial-value method. These recurrence relations are suitable for the numerical computation of the finite-order scattering and transmission functions by use of a digital computer. Furthermore, in Tables 1–3, a numerical example of the finite-order reflection functions for optical thickness 0·2 with albedo = 1 is listed. Table 4 furnishes an example of the cumulative reflection functions for optical thickness 0·2 with three different albedos.     

Microwave absorption of oxygen measured with a Fabry-Perot spectrometer

A Fabry-Perot interferometer in the semiconfocal configuration has been used as a microwave spectrometer by the method of Q-reduction. The Q can be determined with conventional laboratory equipment to within 2% accuracy, corresponding to 0.3 dB/km at 58.82 GHz. Absolute of pure oxygen and dry air at fixed frequencies has been measured as a function of pressure from 0 to 1 atm at room temperature. The measured absorption of dry air can be explained if the overlap of the oxygen lines is properly taken into account.     

Numerical results for finite order X and Y functions of radiative transfer

It is well known that, in the theory of radiative transfer, Chandrasekhar's X and Y functions play an important role in the diffuse reflection and transmission problem (cf. Chandrashekhar⁽¹⁾). In a preceding paper (cf. Bellmanet al.⁽¹⁰⁾), graphs and selected tables of these functions covering wide ranges of slab thickness and albedos for single scattering have been provided. In this paper, making use of a system of coupled integral recurrence relations for finite order X and Y functions (cf. Bellmanet al.⁽¹⁴⁾), numerical results for these basic functions are tabulated up to optical thickness τ = 2.0 from τ = 0.1, assuming the conservative case of isotropic scattering. The maximum order of these functions is taken to be fifteenth. It is shown that the accuracy obtained is satisfactory in the domain under consideration. Furthermore, numerical results for Chandrasekhar's approximation for X and Y functions are also tabulated for stabs of small optical thickness.     

Fish and Chips: a microfluidic perfusion platform for monitoring zebrafish development

We have developed a multi-channel microfluidic perfusion platform for culturing zebrafish embryos and capturing live images of various tissues and organs inside the embryo. The Fish and Chips was micro-fabricated in silicon and glass for reproducibility and accuracy of the microfluidic structure. The microfluidic platform consists of three parts: a microfluidic gradient generator, a row of eight fish tanks, in which the fish embryos are individually placed, and eight output channels. The fluidic gradient generator supports dose-dependent drug and chemical studies. A unique perfusion system ensures a uniform and constant flow of media to the fish tank while the wastes are efficiently removed. The fish tanks restrict the embryo movements, except rotationally, for live imaging of internal tissues and organs. The embryos showed developmental abnormalities under the influence of the drug valproic acid (VPA).     

Mechanical Properties of Thermo-Reversible Colloid Liquid Crystal Composites

Abstract

The mechanical properties of concentrated dispersions of sterically-stabilised colloidal particles in nematic hosts are explored using a combination of optical microscopy and viscoelastic shear measurements. Starting from an initially homogeneous dispersion in an isotropic host, it is found that the kinetics of the isotropic-nematic transition lead to the formation of a percolated particle network that imparts surprising mechanical rigidity to the resulting colloid/liquid crystal composite. Specifically, the viscoelastic storage modulus G′ is observed to rise by approximately 5 orders of magnitude within a few degrees of the bulk isotropic-nematic transition temperature. Using 4-4′pentyl cyano-biphenyl as the solvent, the composite at room temperature is a self-supporting soft solid over a wide range of particle concentrations. The particle microstructure depends sensitively on thermal treatment and particle concentration and it is found that faster cooling enhances the visoelastic moduli of the composite. Also, several classes of network topology have been identified. In all cases studied to date, the particles can be redispsersed upon heating the solvent through the nematic-isotropic transition. The formation of the composite is therefore thermally reversible. A rigorous theory to account for the observed mechanical properties is not currently available.     

Structure determination of Pt‐coated Au dumbbells via fluctuation X‐ray scattering

A fluctuation X‐ray scattering experiment has been carried out on platinum‐coated gold nanoparticles randomly oriented on a substrate. A complete algorithm for determining the electron density of an individual particle from diffraction patterns of many particles randomly oriented about a single axis is demonstrated. This algorithm operates on angular correlations among the measured intensity distributions and recovers the angular correlation functions of a single particle from measured diffraction patterns. Taking advantage of the cylindrical symmetry of the nanoparticles, a cylindrical slice model is proposed to reconstruct the structure of the nanoparticles by fitting the experimental ring angular auto‐correlation and small‐angle scattering data obtained from many scattering patterns. The physical meaning of the refined structure is discussed in terms of their statistical distributions of the shape and electron density profile.     

Shear banding and flow-concentration coupling in colloidal glasses

We report experiments on hard-sphere colloidal glasses that show a type of shear banding hitherto unobserved in soft glasses. We present a scenario that relates this to an instability due to shear-concentration coupling, a mechanism previously thought unimportant in these materials. Below a characteristic shear rate γ(c) we observe increasingly nonlinear and localized velocity profiles. We attribute this to very slight concentration gradients in the unstable flow regime. A simple model accounts for both the observed increase of γ(c) with concentration, and the fluctuations in the flow.     

Total Synthesis of (±)- Cis -5-Hydroxycalamenene

A total synthesis of (±)-cis-5-hydroxycalamenene 1 has been achieved from tetralone 5, which in turn was prepared from 5-methoxy-α-tetralone 3. Grignard reaction of compound 5 with isopropylmagnesium chloride, followed by dehydration and aromatization, provided the substituted naphthalene 7 whose conversion to (±)-cis-5-hydroxycalamenene 1 was accomplished by demethylation, formylation, and hydrogenation.