Electronegativity as a unifying concept in the determination of Fermi energies and photoelectric thresholds

The method proposed by Nethercot for the determination of the Fermi energies and photoelectric thresholds of simple binary compounds has been successfully applied to some AB₂ compounds and metals.     

Computing nonnegative rank factorizations

The existence of nonnegative generalized inverses in terms of nonnegative rank factorizations is considered. An algorithm is presented which computes a nonnegative rank factorization of a nonnegative matrix when a nonnegative 1-inverse exists.     

Time domain investigation on vibrational dephasing and spectral diffusion in CO-doped solid N2

Infrared picosecond accumulated photon echo experiments have been performed for the first time, using the Orsay Free Electron Laser, on the v = 0-->v = 1 transition of CO in solid nitrogen. The vibrational dephasing time is found to be exceptionally long ( T2>/=120 ns) at low temperature. The analysis of the observed spectral diffusion leads one to assume different energy transfer mechanisms depending on the CO concentration.     

Simple synthesis of 1,3-cyclopentanedione derived probes for labeling sulfenic acid proteins

Facile, two-step synthesis and kinetic characterization of new chemical probes for selective labeling of sulfenic acid (-SOH) in proteins are presented. The synthesis route relies on the simple and highly efficient Michael addition of thiol containing tags or linkers to 4-cyclopentene-1,3-dione, the unsaturated derivative of 1,3-cyclopentanedione.     

eHydrogenation: Hydrogen-free Electrochemical Hydrogenation

Hydrogenation reactions are staple transformations commonly used across scientific fields to synthesise pharmaceuticals, natural products, and various functional materials. However, the vast majority of these reactions require the use of a toxic and costly catalyst leading to unpractical, hazardous and often functionally limited conditions. Herein, we report a new, general, practical, efficient, mild and high-yielding hydrogen-free electrochemical method for the reduction of alkene, alkyne, nitro and azido groups. Finally, this method has been applied to deuterium labelling.