Zur quantitativen Bestimmung des Molybd?ns

Ohne Zusammenfassung     

Das Atomgewicht des Molybd?ns

Ohne Zusammenfassung     

Great expectations: Specific lexical anticipation influences the processing of spoken language

Background  

Recently several studies have shown that people use contextual information to make predictions about the rest of the sentence or story as the text unfolds. Using event related potentials (ERPs) we tested whether these on-line predictions are based on a message-level representation of the discourse or on simple automatic activation by individual words. Subjects heard short stories that were highly constraining for one specific noun, or stories that were not specifically predictive but contained the same prime words as the predictive stories. To test whether listeners make specific predictions critical nouns were preceded by an adjective that was inflected according to, or in contrast with, the gender of the expected noun.     

Lithium‐Aluminate‐Catalyzed Hydrophosphination Applications

Synthesized, isolated, and characterized by X‐ray crystallography and NMR spectroscopic studies, lithium phosphidoaluminate iBu₃AlPPh₂Li(THF)₃ has been tested as a catalyst for hydrophosphination of alkynes, alkenes, and carbodiimides. Based on the collective evidence of stoichiometric reactions, NMR monitoring studies, kinetic analysis, and DFT calculations, a mechanism involving deprotonation, alkyne insertion, and protonolysis is proposed for the [iBu₃AlHLi]₂ aluminate catalyzed hydrophosphination of alkynes with diphenylphosphine. This study enhances further the development of transition‐metal‐free, atom‐economical homogeneous catalysis using common sustainable main‐group metals.     

Microwave heating of ceramic composites

The microwave heating of a ceramic composite is modelled andanalysed. The composite consists of many small ceramic particlesembedded in a ceramic cement. The composite is assumed to bewell insulated, and each particle is assumed to be in imperfectthermal contact with the surrounding cement. Based on thesetwo assumptions an asymptotic theory exploiting the small Biotnumber and small non-dimensional contact conductance is developed.Our asymptotic theory yields a set of nonlinear partial differentialequations which govern the temperature in the composite. Theseare reduced to a set of coupled nonlinear ordinary differentialequations in which the surface area of each particle entersas a parameter. Recent experiments with such composites haveshown that the steady-state temperature of the composite isstrongly dependent upon the radii of the embedded particles.Our model captures this effect. In fact, our analysis showsthat the assumption of imperfect thermal contact between theparticles and the ceramic cement is essential for this trendto be established.     

Mean Flow Structures Inside the Human Upper Airway

The lattice Boltzmann method (LBM) was used to conduct a direct numerical simulation study of the airflow inside an idealised human upper airway. Results from both a modest resolution (18 million control volumes, 320 Gb data set) and an extreme resolution (148 million control volumes, 800 Gb data set) LBM simulation were compared to those from experimental results (Johnstone, A.: Hot wire measurements in an oropharyngeal pathway. M.Sc. Thesis, Queen’s University, Kingston, ON, Canada, 2002; Johnstone et al., Expt Fluids 37(5): 673–689, 2004). A coarse resolution simulation (2.4 million control volumes, 105 Gb data set) was used to record the entire time-varying flow field; the nature of the mean structures in the three-dimensional flow field was studied using this data set. For the mean statistics, the LBM calculations yield better results than do the Reynolds averaged Navier–Stokes methods (Ball et al., Comput Fluids, 2007); the LBM reproduces significant detail of experimentally observed flow features. The flow is three-dimensional, obviously, and the interrogation of the mean flow structure is found to be unsteady so that sagittal plane and time-integrated measurements alone are insufficient to verify the accuracy of computational predictions of this flow.