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1.
2.
Harihara Padhy Duryodhan Sahu Dhananjaya Patra Murali Krishna Pola Jen‐Hsien Huang Chih‐Wei Chu Kung‐Hwa Wei Hong‐Cheu Lin 《Journal of polymer science. Part A, Polymer chemistry》2011,49(15):3417-3425
Two β‐cyano‐thiophenevinylene‐based polymers containing cyclopentadithiophene ( CPDT‐CN ) and dithienosilole ( DTS‐CN ) units were synthesized via Stille coupling reaction with Pd(PPh3)4 as a catalyst. The effects of the bridged atoms (C and Si) and cyano‐vinylene groups on their thermal, optical, electrochemical, charge transporting, and photovoltaic properties were investigated. Both polymers possessed the highest occupied molecular orbital (HOMO) levels of about ?5.30 eV and the lowest unoccupied molecular orbital (LUMO) levels of about ?3.60 eV, and covered broad absorption ranges with narrow optical band gaps (ca. 1.6 eV). The bulk heterojunction polymer solar cell (PSC) devices containing an active layer of electron‐donor polymers ( CPDT‐CN and DTS‐CN ) blended with an electron‐acceptor, that is, [6,6]‐phenyl‐C61‐butyric acid methyl ester (PC61BM) or [6,6]‐phenyl‐C71‐butyric acid methyl ester (PC71BM), in different weight ratios were explored under 100 mW/cm2 of AM 1.5 white‐light illumination. The PSC device based on DTS‐CN: PC71BM (1:2 w/w) exhibited a best power conversion efficiency (PCE) value of 2.25% with Voc = 0.74 V, Jsc = 8.39 mA/cm2, and FF = 0.36. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011. 相似文献
3.
Věra JandováZdeněk Bastl Jan ŠubrtJosef Pola 《Journal of Analytical and Applied Pyrolysis》2011,92(2):287-291
Pulsed infrared laser-irradiation of titanium monoxide leads to ablation and when carried out in gaseous benzene (1-5 Torr) to simultaneous dielectric breakdown of benzene into low molecular carbonaceous species which allow carbothermal reduction of ablated TiOx particles and their protection by carbonaceous shell. The deposited particles are characterized by Fourier transform infrared Raman and X-ray photoelectron spectroscopy and by electron microscopy and shown to be stable towards oxidation in air. The reported process can find use in protection of gas-phase produced reactive nanoparticles by carbon phase. 相似文献
4.
V. Dřínek M. Urbanová Z. Bastl I. Gregora V. Vorlíček J. Šubrt J. Pola 《Applied Physics A: Materials Science & Processing》1998,66(5):503-509
2 laser radiation in the gas phase results in the deposition of carbonaceous films composed of a graphitic and monohydrogenated
carbon, in which H is dominantly bonded to sp3 sites. The films incorporate oxygen in the topmost layers. The technique is suitable for the preparation of thin C-based
films at low substrate temperatures.
Received: 23 July 1997/Accepted: 18 November 1997 相似文献
5.
6.
V. Drinek H. Niino J. Pola A. Yabe 《Applied Physics A: Materials Science & Processing》2001,73(4):527-530
An organosilicon compound, hexamethylcyclotrisilazane (HMCTS), was photolyzed in a solid film at 84 K with an ArF excimer
laser. A polymeric film was prepared as a result of polymerization and/or crosslinking using a reactive species such as 1-(methylsilyl)methanimine,
generated by photolysis. At room temperature in air, the film changed into a polymer having siloxane units. However, fragments
generated by laser irradiation of HMCTS in the frozen film made a similar polymer film having a siloxane structure on a PVA
film in air. The polymeric film with siloxane units prepared by the cryogenic laser ablation method displayed hydrophobic
properties.
Received: 23 May 2001 / Accepted: 30 May 2001 / Published online: 30 August 2001 相似文献
7.
Marian ?enkiewicz Marta Rauchfleisz Julian Polański W?odzimierz Engelgard 《Applied Surface Science》2007,253(22):8992-8999
The aim of this article was to show the effects of an electron radiation dose and presence of a compatibilizer on the oxidation of composites made of blends of low-density polyethylene (LDPE), high-density polyethylene (HDPE), polypropylene (PP), polystyrene (PS), and poly(ethylene terephthalate) (PET) as well as of blends of LDPE, HDPE, and PP. As the compatibilizers, the styrene-ethylene/butylene-styrene elastomer grafted with maleic anhydride (SEBS-g-MA) and trimethylol propane trimethylacrylate (TMPTA) were used; they were added in the amounts of 5, 10, and 15 wt% and 1, 2, and 3 wt%, respectively. The oxidation of the surface layer (SL) was investigated by the X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). It was found that the extent of the composite oxidation increased with the increasing dose of the electron radiation. The addition of the compatibilizers enhanced the oxidation of the SL but hindered the oxidation of the bulk of the material. 相似文献
8.
B. Machura A. ?witlicka D. Tabak J. Polański 《Journal of organometallic chemistry》2011,696(3):731-738
The molecular structure of 7-acetamido-2-methyl-quinoline-5,8-dione has been determined and the reactivity of 7-acetamido-2-methyl-quinoline-5,8-dione (1) and 6-acetamido-2-methyl-quinoline-5,8-dione (2) towards Re(CO)5Cl has been examined. Two novel tricarbonyl rhenium complexes, fac-[Re(CO)3(7-acetamido-2-methyl-quinoline-5,8-dione)Cl]·CHCl3 (3·CHCl3) and fac-[Re(CO)3(6-acetamido-2-methyl-quinoline-5,8-dione)Cl]2·CHCl3 (4·CHCl3), have been synthesized and characterized spectroscopically and structurally. The electronic spectrum of 3 was investigated at the TDDFT level employing B3LYP functional in combination with LANL2DZ. 相似文献
9.
Manuela Zanetti Devid Maniglio Cristian Fasoli Marco Pola Elisa Borga Claudio Corradi Mauro Dalla Serra Salvatore Iannotta Antonella Motta Tullio Toccoli 《Electroanalysis》2014,26(8):1653-1659
We report the fabrication of a microfluidic apparatus and the realization of a sensors based on PEDOT : PSS, a biocompatible semiconductor polymer used in substitution of standard electrodes for electrophysiological studies and for detection of nanopores in membrane. This gives the possibility to study the mechanisms of ions balance and molecular transport though cell membranes. In particular the apparatus is based on two chambers connected through an aperture in a PTFE sheet where lipid bilayer are formed using Montal‐Mueller method, and the pore‐forming proteins activity is detected by polymeric electrodes. This methodology could be applied to examine different membrane proteins for the purpose of biosensing, drug screening and nanopore technologies. 相似文献
10.
Excimer laser‐induced photolysis of gaseous diethyl selenium and diethyl tellurium (C2H5)2M (M = Se, Te) is controlled by cleavage of both M? C bonds, it yields C1–C4 hydrocarbons (ethene as major product) and results in chemical vapour deposition of selenium films and nanosized tellurium powder. The selenium and tellurium properties were characterized by X‐ray photoelectron spectroscopy and Scanning electron Microscopy techniques. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献