Intercalation of Toluidines into α-Zirconium Hydrogenphosphate

Intercalates of o-, m-, and p-toluidine into α-Zr(HPO₄)₂ · H₂O were prepared and characterized by powder X-ray diffraction, thermogravimetric analysis and infrared spectroscopy. As follows from IR, toludine molecules are protonated in the interlayer space. Toluidine molecules are arranged in a bimolecular way in the intercalates containing more than 1.5 toluidine molecules per Zr atom. On the other hand, a monolayer of the toluidine molecules is supposed in the intercalates with less than one toluidine molecule per Zr atom.     

The free energy of a reaction coordinate at multiple constraints: a concise formulation

The free energy as a function of the reaction coordinate (rc) is the key quantity for the computation of equilibrium and kinetic quantities. When it is considered as the potential of mean force, the problem is the calculation of the mean force for given values of the rc. We reinvestigate the PMCF (potential of mean constraint force) method which applies a constraint to the rc to compute the mean force as the mean negative constraint force and a metric tensor correction. The latter allows for the constraint imposed to the rc and possible artefacts due to multiple constraints of other variables which for practical reasons are often used in numerical simulations. Two main results are obtained that are of theoretical and practical interest. First, the correction term is given a very concise and simple shape which facilitates its interpretation and evaluation. Secondly, a theorem describes various rcs and possible combinations with constraints that can be used without introducing any correction to the constraint force. The results facilitate the computation of free energy by molecular dynamics simulations.     

First observation of a superdeformed nucleus produced in an α xn reaction channel

Excited states in the neutron deficient ¹⁴⁵ Dy nucleus have been identified by means of the reaction ¹¹²Sn(³⁵ Cl,pn) at 159 MeV. The level scheme above the 11/2 ^? state and up to spin I～37/2 was obtained using γ-ray spectroscopy methods. The level structure is discussed in terms of the coupling of a h _11/2 neutron hole with the N=80 core excitations.     

Two proton high-spin excitations and dipole bands in192Hg

The¹⁹²Hg nucleus was populated in the¹⁶⁰Gd(³⁶S, 4n) reaction at a beam energy of E=159 MeV. Emittedγ-rays were detected with the EUROGAM array comprising 43 Compton-suppressed large volume Ge detectors. The level scheme of¹⁹²Hg has been extended up to an excitation energy of E=10.4 MeV and spin I=34 ?. Two new structures, made of competing ΔI=1 and ΔI=2 transitions have been observed and their connexions with the low-lying levels established. Their lowest levels are located at 6.304 MeV and 6.879 MeV excitation energy. The experimental results are compared with mean-field HF+BCS calculations. It is proposed that the new structures originate from deformation-aligned quasi-proton excitations π(i_13/2 * h_9/2)_K=11 andπ (h_9/2) _K=8 ² , coupled to rotation-aligned quasi-neutron ν(i_13/2)ⁿ and quasi-proton π(h_11/2)² excitations.     

ACTION SPECTRUM FOR ENHANCEMENT OF PHOTOTROPISM BY Arabidopsis thaliana SEEDLINGS

Fluence-response relationships have been measured at wavelengths from 350 to 760 nm for the enhancement of phototropism in Arabidopsis thulium L. (Heynh) strain “Estland” by an irradiation at each of these wavelengths, given 2 h prior to a 450 nm inductive unilateral irradiation. Action spectra have been constructed from these fluence-response relationships based on: (i) the fluence required to obtain a curvature of 25° (corresponding to an enhancement of 15°), (ii) the fluence required to obtain 50% of the maximum enhancement and (iii) the fluence threshold for enhancement by a pre-irradiation. The action spectra exhibit two maxima, one at 669 nm and a second at 378 nm. The height of the maximum at 669 nm is approximately 4 times the height of the maximum at 378 nm. Based on the action spectra, it is concluded that the enhancement of phototropism in A. thaliana is mediated by phytochrome.     

Analysis of multiple photoreceptor pigments for phototropism in a mutant of Arabidopsis thaliana

The shape of the fluence-response relationship for the phototropic response of the JK224 strain of Arabidopsis thaliana depends on the fluence rate and wavelength of the actinic light. At low fluence rate (0.1 micromole m-2 s-1), the response to 450-nm light is characterized by a single maximum at about 9 micromoles m-2. At higher fluence rate (0.4 micromole m-2 s-1), the response shows two maxima, at 4.5 and 9 micromoles m-2. The response to 510-nm light shows a single maximum at 4.5 micromoles m-2. Unilateral preirradiation with high fluence rate (25 micromoles m-2 s-1) 510-nm light eliminates the maximum at 4.5 micromoles m-2 in the fluence response curve to a subsequent unilateral 450-nm irradiation, while the second maximum at 9 micromoles m-2 is unaffected. Based on these results, it is concluded that a single photoreceptor pigment has been altered in the JK224 strain of Arabidopsis thaliana.     

Dipole bands and multi-quasiparticle excitations in 193Pb

The nucleus ¹⁹³Pb was populated via the ¹⁶⁸Er(³⁰Si,5n) reaction at a beam energy of 159 MeV and studied with the EUROGAM II spectrometer. Five new dipole Δ I = 1 cascades have been found. These structures have been connected to the level scheme which has been considerably extended up to a spin of ? and an excitation energy of about 8 MeV. Angular distribution coefficients, a₂, have been measured and confirm the dipole character of the in-band transitions. B(M1)/B(E2) ratios have been extracted for the two most intense cascades. The ¹⁹³Pb dipole bands are discussed in comparison with those known in odd lead isotopic series and the structure of the band heads is analyzed in terms of microscopic HF+BCS calculations. The proposed configurations are based on a high-K two quasiproton excitation, π ([505]9/2^t? ? [606]13/2⁺)_K=11^t -, coupled to one or three rotation aligned quasineutrons involving the i_13/2, p _3/2, f_5/2 and/or h{9/2} subshells. The main difference, compared with the heavier lead isotopes, is the presence of large Ω orbitals from the ν (i_13/2) shell near the Fermi surface which are responsible for the increasing band-head spin as A decreases.     

Dipole bands and multi-quasiparticle excitations in193Pb

The nucleus¹⁹³Pb was populated via the¹⁶⁸Er(³⁰Si,5n) reaction at a beam energy of 159 MeV and studied with the EUROGAM II spectrometer. Five new dipoleΔI=1 cascades have been found. These structures have been connected to the level scheme which has been considerably extended up to a spin of 61/2? and an excitation energy of about 8 MeV. Angular distribution coefficients,α ₂, have been measured and confirm the dipole character of the in-band transitions. B(M1)/B(E2) ratios have been extracted for the two most intense cascades. The¹⁹³Pb dipole bands are discussed in comparison with those known in odd lead isotopic series and the structure of the band heads is analyzed in terms of microscopic HF-BCS calculations. The proposed configurations are based on a high-K two quasiproton excitation,π([505]9/2^??[606]13/2⁺) _K =11^?, coupled to one or three rotation aligned quasineutrons involving thei _13/2,p _3/2,f _5/2 and/orh _9/2 subshells. The main difference, compared with the heavier lead isotopes, is the presence of largeΩ orbitals from theν (i _13/2) shell near the Fermi surface which are responsible for the increasing band-head spin as A decreases.