全文获取类型
收费全文 | 643篇 |
免费 | 19篇 |
专业分类
化学 | 354篇 |
晶体学 | 8篇 |
力学 | 18篇 |
数学 | 120篇 |
物理学 | 162篇 |
出版年
2022年 | 4篇 |
2021年 | 6篇 |
2020年 | 8篇 |
2019年 | 8篇 |
2018年 | 19篇 |
2017年 | 18篇 |
2016年 | 21篇 |
2015年 | 18篇 |
2014年 | 30篇 |
2013年 | 52篇 |
2012年 | 39篇 |
2011年 | 35篇 |
2010年 | 25篇 |
2009年 | 27篇 |
2008年 | 31篇 |
2007年 | 33篇 |
2006年 | 24篇 |
2005年 | 22篇 |
2004年 | 22篇 |
2003年 | 13篇 |
2002年 | 14篇 |
2001年 | 12篇 |
2000年 | 10篇 |
1999年 | 16篇 |
1998年 | 13篇 |
1996年 | 9篇 |
1995年 | 17篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1991年 | 6篇 |
1990年 | 6篇 |
1989年 | 5篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1985年 | 11篇 |
1984年 | 9篇 |
1983年 | 2篇 |
1982年 | 7篇 |
1981年 | 6篇 |
1980年 | 7篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 6篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1973年 | 2篇 |
1972年 | 3篇 |
1969年 | 2篇 |
1933年 | 2篇 |
排序方式: 共有662条查询结果,搜索用时 31 毫秒
61.
Małgorzata Jóźwiak 《Journal of solution chemistry》2017,46(1):234-246
The enthalpies of solution of the cyclic ethers 1,4-dioxane, 12-crown-4 and 18-crown-6 in mixtures of ethanol and water have been measured within the whole mole fraction range at T = 298.15 K. The enthalpy of solvation has been calculated. In pure ethanol and pure water, the solvation enthalpy of the investigated cyclic ethers depends linearity on the number of –CH2CH2– groups in the cyclic ether molecules. Based on the analysis of the preferential solvation model proposed by Waghorne, it can be concluded that the 1,4-dioxane, 15C5 and 18C6 molecules are preferentially solvated by water molecules in the range of low water content in these mixtures. The effect of base–acid properties of ethanol–water mixtures on the enthalpy of solution of cyclic ethers in these mixtures has been analyzed. The enthalpy of solution of cyclic ethers correlates with the acidic properties of ethanol–water mixtures in the range of high and medium water content. The results presented are compared with analogous data obtained for the methanol–water and propan-1-ol–water mixtures. 相似文献
62.
Anna Śmiechowska Witold Przychodzeń Jarosław Chojnacki Piotr Bruździak Jacek Namieśnik Agnieszka Bartoszek 《Structural chemistry》2010,21(5):955-964
Adducts of natural allyl, phenethyl, and benzyl isothiocyanates and 2-amino-1-methylbenzimidazole were synthesized. After
optimization of the reaction conditions, the target 2-benzimidazolylthioureas were obtained in reasonable yields. The detailed
molecular and crystal structures of these compounds were characterized by spectroscopic and X-ray methods. Spectral analysis
demonstrated that N-(1-methylbenzimidazolyl)-N′-allylthiourea, N-(1-methylbenzimidazolyl)-N′-benzylthiourea, and N-(1-methylbenzimidazolyl)-N′-phenethylthiourea exist in solution in an unprecedented three tautomeric forms, whose structures were corroborated unambiguously. 相似文献
63.
Z. Brzeźniak F. Flandoli M. Neklyudov B. Zegarliński 《Journal of statistical physics》2011,144(6):1171-1185
We analyse certain conservative interacting particle system and establish ergodicity of the system for a family of invariant
measures. Furthermore, we show that convergence rate to equilibrium is exponential. This result is of interest because it
presents counterexample to the standard assumption of physicists that conservative system implies polynomial rate of convergence.
The system in question is stochastic rather than deterministic. 相似文献
64.
65.
Bogdan Kaźmierczak Kazimierz Piechór 《Mathematical Methods in the Applied Sciences》2011,34(3):325-337
We study traveling wave solutions to a system of four non‐linear partial differential equations, which arise in a tissue interaction model for skin morphogenesis. Under the assumption that the strength of attachment of the epidermis to the basal lamina is sufficiently large, we prove the existence and uniqueness (up to a translation) of traveling wave solutions connecting two stationary states of the system with the dermis and epidermis cell densities being positive. We discuss the problem of the minimal wave speed. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
66.
Adam Liwo Jarosław Pillardy Rajmund Kaźmierkiewicz Ryszard J. Wawak Małgorzata Groth Cezary Czaplewski Stanisaw Ołdziej Harold A. Scheraga 《Theoretical chemistry accounts》1999,101(1-3):16-20
A united-residue model of polypeptide chains developed in our laboratories with united side-chains and united peptide groups
as interaction sites is presented. The model is designed to work in continuous space; hence efficient global-optimization
methods can be applied. In this work, we adopted the distance-scaling method that is based on continuous deformation of the original
rugged energy hypersurface to obtain a smoothed surface. The method has been applied successfully to predict the structures
of simple motifs, such as the three-helix bundle structure of the 10-58 fragment of staphylococcal protein A in de novo folding
simulations and more complicated motifs in inverse-folding simulations.
Received: 24 April 1998 / Accepted: 4 August 1998 / Published online: 2 November 1998 相似文献
67.
Physics of Atomic Nuclei - The theory of neutrino oscillations rests on the assumption, that the interaction basis and the physical (mass) basis of neutrino states are different. Therefore neutrino... 相似文献
68.
The reaction of benzylthioarylboronic acids protected as N‐butyldiethanolamine esters or as triisopropoxyborates with organolithium bases or lithium diisopropylamide (LDA) has been investigated. The benzylic lithiation occurs selectively using LDA at − 68 °C. The stability of the resultant borio‐lithio intermediates is strongly influenced by the position of the boron atom in the phenyl ring. The reaction with various electrophiles affords new arylboronic acids substituted in the benzylic position. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
69.
The title complex, denoted as [Cu(Msap)2], is a deep brown solid soluble in common solvents like chloroform, toluene, benzene, dioxane, acetone, methanol, ethanol,
2-propanol, dimethylformamide, dimethyl sulfoxide, and acetonitrile that is a necessary condition for solvatochromism observation.
The complex has been characterized by elemental analysis, molar conductivity, ultraviolet, and visible spectroscopy. The available
X-ray data for similar compounds show that copper atom adopts planar coordination geometry. The molar conductivities indicate
their non-electrolytic properties. The electronic spectra have been used to study the coordination properties of donor atoms
and their bonding abilities, as well as solvatochromism. The results obtained show that the interactions of metal with donors
depend on solvent polarity and the color changes are subtle. 相似文献
70.
The performance of three-colour HgCdTe photovoltaic heterostructure detector is examined theoretically. In comparison with
two-colour detectors with two back-to-back junctions, three-colour structure contains an absorber of intermediate wavelength
placed between two junctions and electronic barriers are used to isolate this intermediate region. This structure was first
proposed by British workers.
Three-detector structures with different localizations of separating barriers are analyzed. The calculation results are presented
in the form of spatial distributions of bandgap energy and quantum efficiency.
Enhanced original computer programs are applied to solve the system of non-linear continuity equations for carriers and Poisson
equations. In addition, the numerical analysis includes the dependence of absorption coefficient on Burstein effect as well
as interference effects in heterostructure with metallic electrical contacts.
It is shown that the performance of the detector is critically dependent on the barrier’s doping level and position in relation
to the junction. This behaviour is serious disadvantage of the considered three-colour detector. A small shift of the barrier
location and doping level causes serious changes in spectral responsivity. 相似文献