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1.
Silvio De Bernardini Georg Graf Colin A. Leach Peter Bühlmayer Felix Waldmeier Christoph Tamm 《Helvetica chimica acta》1983,66(2):639-651
The modified nucleoside Πd (1) was used in the synthesis of the oligonucleotide d (TpTpΠpCpGpTpCpApApApApTpC). Diester methodology being unsatisfactory, the triester synthesis was investigated with the unnatural nucleoside. An improved method of nucleoside phosphorylation was developed for the synthesis of the fully-protected nucleotide 2e. This molecule could be cleanly and selectively deprotected, and allowed the efficient synthesis of the desired oligonucleotide. 相似文献
2.
In contrast to earlier reports [2] [8], the pure Cu2+ complex of phthalocyanine-tetrasulfonic acid (I) is found to be inactive in the decomposition of H2O2. The Cu2+ complexes of 1, 4, 8, 11-tetraazacyclotetradecan (II) and 2, 12-dimethyl-3,7,11,17-tetraazabicyclo [11.3.1]-heptadeca-1(17), 2,11,13,15-pentaen (III) are equally inactive. The results confirm that only Cu2+ complexes with a not «saturated» coordination sphere catalyse the decomposition of H2O2. 相似文献
3.
Sachin S. Pathak R. D. Bhanushali I. C. Pius S. K. Mukerjee 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(3):1641-1648
Titania–silica microspheres have been prepared by sol–gel process. Internal gelation route, which use hexamethylenetetramine as the source of ammonia was used for the preparation spherical gel particles. A cationic surfactant, cetrimide was added in the feed broth for introducing meso-porosity in the gel network. Further paraffin oil emulsion was incorporated in the feed broth before gelation for the formation of larger pores in the gel network. The spherical gel particles thus obtained were washed and heat treated under controlled conditions to remove the entrapped surfactant, paraffin oil and other organic compounds resulting in highly porous intact titania–silica microspheres. The material was characterized by surface area, porosity and by SEM photomicrographs. The ion exchange property of this material was studied using the sorption of plutonium on this material from carbonate medium by distribution coefficient studies and ion exchange column loading and elution experiments. 相似文献
4.
R. D. Bhanushali Sachin S. Pathak I. C. Pius S. K. Mukerjee 《Journal of Radioanalytical and Nuclear Chemistry》2010,284(3):647-651
Based on the Linssi database and UniSampo/Shaman software, an automated analysis platform has been setup for the analysis
of large amounts of gamma-spectra from the primary coolant monitoring systems of a CANDU reactor. Thus, a database inventory
of gaseous and volatile fission products in the primary coolant of a CANDU reactor has been established. This database is
comprised of 15,000 spectra of radioisotope analysis records. Records from the database inventory were retrieved by a specifically
designed data-mining module and subjected to further analysis. Results from the analysis were subsequently used to identify
the reactor coolant half-life of 135Xe and 133Xe, as well as the correlations of 135Xe and 88Kr activities. 相似文献
5.
Permanent capillary gravity waves on the free surface of a two dimensional inviscid fluid of infinite depth are investigated. An application of the hodograph transform converts the free boundary-value problem into a boundary-value problem for the Cauchy-Riemann equations in the lower halfplane with nonlinear differential boundary conditions. This can be converted to an integro-differential equation with symbol –k
2+4|k|–4(1+), where is a bifurcation parameter. A normal-form analysis is presented which shows that the boundary-value problem can be reduced to an integrable system of ordinary differential equations plus a remainder term containing nonlocal terms of higher order for || small. This normal form system has been studied thoroughly by several authors (Iooss &Kirchgässner [8],Iooss &Pérouème [10],Dias &Iooss [5]). It admits a pair of solitary-wave solutions which are reversible in the sense ofKirchgässner [11]. By applying a method introduced in [11], it is shown that this pair of reversible solitary waves persists for the boundary-value problem, and that the decay at infinity of these solitary waves is at least like 1/|x|. 相似文献
6.
7.
Hoffmann-Emery F Hilpert H Scalone M Waldmeier P 《The Journal of organic chemistry》2006,71(5):2000-2008
A new efficient synthesis of two novel classes of NK1 receptor antagonists, among them befetupitant and netupitant, starting from 6-chloronicotinic acid is described. The introduction of the o-tolyl substituent at C4 of the pyridine ring was achieved by a one-pot selective 1,4-Grignard addition/oxidation sequence to 6-chloronicotinic acid or a derivative of it. The scope of this addition/oxidation sequence was examined. It was also shown that the carboxylic function can be converted to a methyl amino group by a Hofmann rearrangement followed by reduction. Furthermore, a new high-yielding synthesis of 2-(3,5-bistrifluoromethylphenyl)-2-methyl propionic acid based on the carbonylation of the tertiary alcohol obtained by Grignard addition of 3,5-bis(trifluoromethyl)bromobenzene to acetone was established. 相似文献
8.
9.
Dhamodharan K. Aneesh T. Pius Anitha 《Journal of Radioanalytical and Nuclear Chemistry》2019,319(3):1127-1133
Journal of Radioanalytical and Nuclear Chemistry - In dissolution studies involving plutonium oxide, oxides of cerium are employed as a non radioactive surrogate. A reductive dissolution of cerium... 相似文献
10.