全文获取类型
收费全文 | 2365篇 |
免费 | 84篇 |
国内免费 | 23篇 |
专业分类
化学 | 1465篇 |
晶体学 | 7篇 |
力学 | 42篇 |
数学 | 399篇 |
物理学 | 559篇 |
出版年
2023年 | 9篇 |
2022年 | 27篇 |
2021年 | 28篇 |
2020年 | 38篇 |
2019年 | 29篇 |
2018年 | 30篇 |
2017年 | 36篇 |
2016年 | 61篇 |
2015年 | 59篇 |
2014年 | 61篇 |
2013年 | 121篇 |
2012年 | 186篇 |
2011年 | 176篇 |
2010年 | 123篇 |
2009年 | 110篇 |
2008年 | 158篇 |
2007年 | 164篇 |
2006年 | 167篇 |
2005年 | 203篇 |
2004年 | 138篇 |
2003年 | 124篇 |
2002年 | 115篇 |
2001年 | 19篇 |
2000年 | 23篇 |
1999年 | 15篇 |
1998年 | 15篇 |
1997年 | 15篇 |
1996年 | 33篇 |
1995年 | 17篇 |
1994年 | 17篇 |
1993年 | 19篇 |
1992年 | 11篇 |
1991年 | 5篇 |
1990年 | 8篇 |
1989年 | 12篇 |
1988年 | 5篇 |
1987年 | 4篇 |
1986年 | 7篇 |
1985年 | 12篇 |
1984年 | 10篇 |
1983年 | 10篇 |
1982年 | 9篇 |
1981年 | 10篇 |
1980年 | 5篇 |
1979年 | 7篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1973年 | 5篇 |
1972年 | 3篇 |
1970年 | 2篇 |
排序方式: 共有2472条查询结果,搜索用时 15 毫秒
141.
Microcionamides A and B, bioactive peptides from the philippine sponge Clathria (Thalysias) abietina
Davis RA Mangalindan GC Bojo ZP Antemano RR Rodriguez NO Concepcion GP Samson SC de Guzman D Cruz LJ Tasdemir D Harper MK Feng X Carter GT Ireland CM 《The Journal of organic chemistry》2004,69(12):4170-4176
Microcionamides A (1) and B (2) have been isolated from the Philippine marine sponge Clathria (Thalysias) abietina. These new linear peptides are cyclized via a cystine moiety and have their C-terminus blocked by a 2-phenylethylenamine group. Their total structures, including absolute stereochemistry, were determined by a combination of spectral and chemical methods. Compound 1 was shown to slowly isomerize about the C-36/C-37 double bond when stored in DMSO. Microcionamides A (1) and B (2) exhibited significant cytotoxicity against the human breast tumor cells lines MCF-7 and SKBR-3 and displayed inhibitory activity against Mycobacterium tuberculosis H(37)Ra. 相似文献
142.
143.
Shen M Li G Lu BZ Hossain A Roschangar F Farina V Senanayake CH 《Organic letters》2004,6(22):4129-4132
[reaction: see text] The first practical and economical process for synthesis of 2,3-disubstituted indole compounds has been developed with high regioselectivity by palladium-catalyzed indolization of 2-bromo- or chloroanilines and their derivatives with internal alkynes. 相似文献
144.
Chris Macmeikan 《Proceedings of the American Mathematical Society》2004,132(6):1575-1580
Let be an mp arrangement in a complex algebraic variety with corresponding complement and intersection poset . Examples of such arrangements are hyperplane arrangements and toral arrangements, i.e., collections of codimension 1 subtori, in an algebraic torus. Suppose a finite group acts on as a group of automorphisms and stabilizes the arrangement setwise. We give a formula for the graded character of on the cohomology of in terms of the graded character of on the cohomology of certain subvarieties in .
145.
Bharitkar S Hilmes P Kyriakakis C 《The Journal of the Acoustical Society of America》2004,116(6):3491-3497
Traditionally, multiple listener room equalization is performed to improve sound quality at all listeners, during audio playback, in a multiple listener environment (e.g., movie theaters, automobiles, etc.). A typical way of doing multiple listener equalization is through spatial averaging, where the room responses are averaged spatially between positions and an inverse equalization filter is found from the spatially averaged result. However, the equalization performance, will be affected if there is a mismatch between the position of the microphones (which are used for measuring the room responses for designing the equalization filter) and the actual center of listener head position (during playback). In this paper, we will present results on the effects of microphone-listener mismatch on spatial average equalization performance. The results indicate that, for the analyzed rectangular configuration, the region of effective equalization depends on (i) the distance of a listener from the source, (ii) the amount of mismatch between the responses, and (iii) the frequency of the audio signal. We also present some convergence analysis to interpret the results. 相似文献
146.
We demonstrate a novel method of generating a multiwavelength pulse train by use of time-lens compression. In addition to pulse compression, this time lens simultaneously displaces the pulses according to their center wavelengths, resulting in a temporally evenly spaced multiwavelength pulse train. We further demonstrate a new aberration-correction technique based on the temporal analog of a spatial correction lens to improve the quality of the compressed pulses. Through the use of cw distributed-feedback lasers and electro-optic phase modulators, the all-fiber system allows complete tunability of temporal spacing, spectral profile, and repetition rate. 相似文献
147.
Hamilton CJ 《Natural product reports》2004,21(3):365-385
This review covers advances/developments in the use of enzymes in synthetic mono-/oligo-saccharide chemistry published in the literature between January 2001 and June 2003. Particular attention is paid to the use of aldolases, ketolases, glycosidases, glycosynthases, lipases, esterases and coupled multi-enzyme biotransformations and 132 references are cited. 相似文献
148.
We propose a novel ultrafast photonic analog-to-digital converter that uses the soliton self-frequency shift in an optical fiber as an optical power-to-frequency conversion mechanism and a set of interleaving spectral filters as the optical comparators. Our method does all the signal processing in the optical domain and requires binary receivers in only the electronic domain. In contrast to the usual exponential scaling, the simultaneous binary search architecture that we propose results in a flash analog-to-digital converter with remarkable linear scaling between the number of comparators and the number of bits resolved. 相似文献
149.
Randall H. Skelton Chris D. Boone Peter F. Bernath Bernard Pinchemel 《Journal of Molecular Spectroscopy》2003,219(1):1-12
The A′1Π-X1Σ+ near infrared system of strontium oxide (SrO) was observed at high spectral resolution by measuring the chemiluminescence from a Broida flow reactor using a Fourier transform spectrometer. In total, 32 bands from , , were measured within the spectral region at a resolution of . Vibrational levels of the upper state were observed up to vA′=4, and more than 5600 rotational lines were assigned. Incorporating previously published high resolution data for the A1Σ+-X1Σ+ system, a global fit to both data sets yields improved Dunham constants for the ground state and for the lower vibrational levels (vA′=0, 1, and 2) of the A′1Π state. Because perturbations arising from interactions with the b3Σ+ and A1Σ+ states affect the higher vibrational levels of the A′1Π state more strongly, levels vA′=3 and 4 were represented by effective band constants in the fits. RKR potentials for the X1Σ+,A′1Π, and b3Σ+ states have been generated utilizing all the available data, Franck-Condon factors have been calculated for the A′1Π-X1Σ+ system, and A′1Π∼b3Σ+ and A′1Π∼A1Σ+ perturbations are discussed. 相似文献
150.
We show how to describe the coupling of electrons to nonuniform magnetic fields in the framework of the widely used norm-conserving pseudopotential approximation for electronic structure calculations. Our derivation applies to magnetic fields that are smooth on the scale of the core region. The method is validated by application to the calculation of the magnetic susceptibility of molecules within density functional theory (DFT) in the local density approximation. Our results are compared with high-quality all-electron DFT results obtained using Gaussian basis sets and another recently proposed pseudopotential formalism. 相似文献