排序方式: 共有35条查询结果,搜索用时 15 毫秒
21.
Lindsay M. Miller Pit Pillatsch Einar Halvorsen Paul K. Wright Eric M. Yeatman Andrew S. Holmes 《Journal of sound and vibration》2013
A passively self-tuning resonator configuration is presented in this study. Three different prototype beam–mass systems were built and tested and all successfully displayed passive self-tuning behavior when driven by vibrations at frequencies ranging from 45 to 140 Hz and accelerations ranging from 0.007 to 2g. All three systems were able to achieve tuning within their operating regime when driven at a single frequency, as well as maintain a tuned condition as frequency was stepped up or down, demonstrating a bandwidth between 6 and 40 Hz. One application of such a passively self-tuning system is in vibration energy harvesting, where it is critical for performance that the harvester device resonance frequency matches the input vibration frequency, yet the input frequency may change over time and is not known a priori. The self-tuning resonator demonstrated in this paper can enable the energy harvesting system to adjust to the varying input frequencies and thereby increase the energy harvested over time. 相似文献
22.
Steffen Treiling Cui Wang Christoph Frster Florian Reichenauer Jens Kalmbach Pit Boden Joe P. Harris Luca M. Carrella Eva Rentschler Ute Resch‐Genger Christian Reber Michael Seitz Markus Gerhards Katja Heinze 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(50):18243-18253
Photoactive metal complexes employing Earth‐abundant metal ions are a key to sustainable photophysical and photochemical applications. We exploit the effects of an inversion center and ligand non‐innocence to tune the luminescence and photochemistry of the excited state of the [CrN6] chromophore [Cr(tpe)2]3+ with close to octahedral symmetry (tpe=1,1,1‐tris(pyrid‐2‐yl)ethane). [Cr(tpe)2]3+ exhibits the longest luminescence lifetime (τ=4500 μs) reported up to date for a molecular polypyridyl chromium(III) complex together with a very high luminescence quantum yield of Φ=8.2 % at room temperature in fluid solution. Furthermore, the tpe ligands in [Cr(tpe)2]3+ are redox non‐innocent, leading to reversible reductive chemistry. The excited state redox potential and lifetime of [Cr(tpe)2]3+ surpass those of the classical photosensitizer [Ru(bpy)3]2+ (bpy=2,2′‐bipyridine) enabling energy transfer (to oxygen) and photoredox processes (with azulene and tri(n‐butyl)amine). 相似文献
23.
Matthias Dorn Jens Kalmbach Pit Boden Ayla Kruse Chahinez Dab Christian Reber Gereon Niedner-Schatteburg Stefan Lochbrunner Markus Gerhards Michael Seitz Katja Heinze 《Chemical science》2021,12(32):10780
In spite of intense, recent research efforts, luminescent transition metal complexes with Earth-abundant metals are still very rare owing to the small ligand field splitting of 3d transition metal complexes and the resulting non-emissive low-energy metal-centered states. Low-energy excited states decay efficiently non-radiatively, so that near-infrared emissive transition metal complexes with 3d transition metals are even more challenging. We report that the heteroleptic pseudo-octahedral d2-vanadium(iii) complex VCl3(ddpd) (ddpd = N,N′-dimethyl-N,N′-dipyridine-2-yl-pyridine-2,6-diamine) shows near-infrared singlet → triplet spin–flip phosphorescence maxima at 1102, 1219 and 1256 nm with a lifetime of 0.5 μs at room temperature. Band splitting, ligand deuteration, excitation energy and temperature effects on the excited state dynamics will be discussed on slow and fast timescales using Raman, static and time-resolved photoluminescence, step-scan FTIR and fs-UV pump-vis probe spectroscopy as well as photolysis experiments in combination with static quantum chemical calculations. These results inform future design strategies for molecular materials of Earth-abundant metal ions exhibiting spin–flip luminescence and photoinduced metal–ligand bond homolysis.Vanadium is an abundant and cheap metal but near-infrared luminescent vanadium complexes are extremely rare with largely unexplored photophysics and photochemistry. We delineate the photodynamics of VCl3(ddpd) to infer novel design strategies. 相似文献
24.
Sencadas V Martins P Pitães A Benelmekki M Gómez Ribelles JL Lanceros-Mendez S 《Langmuir : the ACS journal of surfaces and colloids》2011,27(11):7241-7249
This work reports on the nucleation of the β-phase of poly(vinylidene fluoride) (PVDF) by incorporating CoFe(2)O(4) and NiFe(2)O(4) nanoparticles, leading in this way to the preparation of magnetoelectric composites. The fraction of filler nanoparticles needed to produce the same β- to α-phase ratio in crystallized PVDF is 1 order of magnitude lower in the cobalt ferrite nanoparticles. The interaction between nanoparticles and PVDF chains induce the all-trans conformation in PVDF segments, and this structure then propagates in crystal growth. The nucleation kinetics is enhanced by the presence of nanoparticles, as corroborated by the increasing number of spherulites with increasing nanoparticle content and by the variations of the Avrami's exponent. Further, the decrease of the crystalline fraction of PVDF with increasing nanoparticle content indicates that an important fraction of polymer chains are confined in interphases with the filler particle. 相似文献
25.
Othman M Genapathy S Liew PS Ch'ng QT Loh HS Khoo TJ Wiart C Ting KN 《Natural product research》2011,25(19):1857-1864
The world's rainforests hold untold potential for drug discovery. Rainforest plants are thought to contain evolved defensive active metabolites of greater diversity compared to plants from temperate regions. In recent years, the interest and overall output from pharmaceutical companies on novel antibacterial agents has diminished at a time when there is a critical need for them to fight the threat of resistance. In this study, we have investigated the antimicrobial properties of 21 flowering plants from 16 different families against six bacterial strains consisting of two Gram negative and four Gram positive. Using the pour plate disc diffusion technique, almost all extracts from these plants were found to be active against some of the bacterial strains tested. The most interesting and active plants with broad spectrum activities include Duabanga grandiflora, Acalypha wilkesiana and Pseuduvaria macrophylla where the minimum inhibitory concentration, minimum bactericidal concentration and phytochemical analysis were carried out. This is the first report describing the antimicrobial and phytochemical properties of D. grandiflora and P. macrophylla. Our findings support the utilisation of higher plant species in the search for new antimicrobial molecules to combat new emerging infective diseases and the problem of drug resistant pathogens. 相似文献
26.
Akash Kaithal Pit van Bonn Markus Hlscher Walter Leitner 《Angewandte Chemie (International ed. in English)》2020,59(1):215-220
Highly selective β‐methylation of alcohols was achieved using an earth‐abundant first row transition metal in the air stable molecular manganese complex [Mn(CO)2Br[HN(C2H4PiPr2)2]] 1 ([HN(C2H4PiPr2)2]=MACHO‐iPr). The reaction requires only low loadings of 1 (0.5 mol %), methanolate as base and MeOH as methylation reagent as well as solvent. Various alcohols were β‐methylated with very good selectivity (>99 %) and excellent yield (up to 94 %). Biomass derived aliphatic alcohols and diols were also selectively methylated on the β‐position, opening a pathway to “biohybrid” molecules constructed entirely from non‐fossil carbon. Mechanistic studies indicate that the reaction proceeds through a borrowing hydrogen pathway involving metal–ligand cooperation at the Mn‐pincer complex. This transformation provides a convenient, economical, and environmentally benign pathway for the selective C?C bond formation with potential applications for the preparation of advanced biofuels, fine chemicals, and biologically active molecules 相似文献
27.
Dr. Pit J. Boden Patrick Di Martino-Fumo Tobias Bens Sophie T. Steiger Daniel Marhöfer Prof. Dr. Dr. Gereon Niedner-Schatteburg Prof. Dr. Biprajit Sarkar 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(51):e202201038
This work tackles the photochemistry of a series of mononuclear Cr0, Mo0 and W0 carbonyl complexes containing a bidentate mesoionic carbene ligand of the 1,2,3-triazol-5-ylidene type. FTIR spectroscopy, combined with density functional theory calculations, revealed a clean photo-induced reaction in organic solvents (acetonitrile, pyridine, valeronitrile) to give mainly one photoproduct with monosubstitution of a carbonyl ligand for a solvent molecule. The highest photodissociation quantum yields were reached for the Cr0 complex under UV irradiation (266 nm). Based on previous investigations, the kinetics of the dark reverse reactions have now been determined, with reaction times of up to several hours in pyridine. Photochemical studies in the solid state (KBr matrix, frozen solution) also showed light-induced reactivity with stabilization of the metastable intermediate with a free coordination site at very low temperature. The identified reactive species emphasizes a mechanism without ligand–sphere reorganization. 相似文献
28.
Dr. Bhupendra Goswami Dr. Thomas J. Feuerstein Dr. Ravi Yadav Dr. Sergei Lebedkin Pit J. Boden Sophie T. Steiger Prof. Dr. Gereon Niedner-Schatteburg Prof. Dr. Markus Gerhards Prof. Dr. Manfred M. Kappes Prof. Dr. Peter W. Roesky 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(61):15110-15119
The synthesis of copper and zinc complexes of four variably substituted iminophosphonamide ligands is presented. While the copper complexes form ligand-bridged dimers, the zinc compounds are monomeric. Due to different steric demand of the ligand the arrangement of the ligands within the dimeric complexes varies. Similar to the structurally related iminophosphonamide complexes of alkali metals and calcium, the steady-state and time-resolved photoluminescence (PL) of four of the seven compounds studied here as solids in a temperature range of 5–295 K can be described within the scheme of thermally activated delayed fluorescence (TADF). Accordingly, they exhibit bright blue-green phosphorescence at low temperatures (<100 K), which turns into delayed fluorescence by increasing the temperature. However, unusually, the fluorescence is practically absent in two copper complexes which otherwise still conform to the TADF scheme. In these cases, the excited singlet states decay essentially non-radiatively and their thermal population from the corresponding low-lying triplet states efficiently quenches PL (phosphorescence). Three other copper and zinc complexes only exhibit prompt fluorescence, evidencing a wide variation of photophysical properties in this class of compounds. The excited states of the copper complex with especially pronounced phosphorescence quenching were also investigated by low-temperature time-resolved infrared spectroscopy and quantum chemical calculations. 相似文献
29.
Dr. Merten Grupe Pit Boden Patrick Di Martino-Fumo Dr. Xin Gui Cecilia Bruschi Roumany Israil Marcel Schmitt Dr. Martin Nieger Prof. Dr. Markus Gerhards Prof. Dr. Wim Klopper Dr. Christoph Riehn Dr. Claudia Bizzarri Prof. Dr. Rolf Diller 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(61):15252-15271
Chemical and spectroscopic characterization of the mononuclear photosensitizers [(DPEPhos)Cu(I)(MPyrT)]0/+ ( CuL , CuLH ) and their dinuclear analogues ( Cu2L’ , Cu2L'H2 ), backed by (TD)DFT and high-level GW-Bethe-Salpeter equation calculations, exemplifies the complex influence of charge, nuclearity and structural flexibility on UV-induced photophysical pathways. Ultrafast transient absorption and step-scan FTIR spectroscopy reveal flattening distortion in the triplet state of CuLH as controlled by charge, which also appears to have a large impact on the symmetry of the long-lived triplet states in Cu2L’ and Cu2L'H2 . Time-resolved luminescence spectroscopy (solid state), supported by transient photodissociation spectroscopy (gas phase), confirm a lifetime of some tens of μs for the respective triplet states, as well as the energetics of thermally activated delayed luminescence, both being essential parameters for application of these materials based on earth-abundant copper in photocatalysis and luminescent devices. 相似文献