Coagulation of the Suspended Organic Colloids Using the Electroflocculation Technique

Electroflotation is an unconventional separation process owing its name to the bubbles generation method (i.e., electrolysis of the aqueous medium) caused by the hydrogen and hydroxide development. Collecting the colloidal particles in surface water has been a long-term issue all over the world, because of their adverse influence. In the present research, the electroflocculation technique have been use to collect the humus particles throughout the polluted wastewater. The uses of different chemical additives namely, Al₂(SO₄)₃, Al(OH)₃, CaCl₂, CaO, and Na₂SiO₃ were also successfully examined and enhanced the electroflocculation technique. Although high negatively surface electrical charge of humus causes difficulties in the conventional flocculation and coagulation technique, it enhances the flocculation process when the electroflocculation techniques have been used. The results of both Jar test and electroflocculation technique are further compared. It can be concluded that the polluted water were fully decontaminated (i.e., all of the suspended colloids through the water were removed) by using the electroflocculation technique. The removal rate after electroflocculation test were 91.8%, 98%, 93.5%, 85.3%, 95.4%, and 94% for neutral, Al₂(SO₄)₃, Al(OH)₃, CaCl₂, CaO, and Na₂SiO₃, respectively. While the removal rate after Jar test were 84.8%, 83.79%, 71.44%, 84.83%, 77.09%, and 77.09% for neutral, Al₂(SO₄)₃, Al(OH)₃, CaCl₂, CaO, and Na₂SiO₃, respectively.     

Copolymerization of ethylene α-olefin using MgCl2-ethanol adduct catalysts

The effects of the type and concentration of comonomers 1-hexene and 1-octene in the copolymerization of ethylene were investigated using pre polymerized Ziegler-Natta (catalyst a) and without pre polymerized (catalyst b) catalysts in the presence of hydrogen as a chain transfer agent. The properties of produced polymers were characterized by a set of techniques: (SEM), (EDX), (DSC), (GPC). TIBA and DEAC were used as co catalysts. The results of microscopic and SEM images showed the morphology and structure of catalysts (a) and (b) and the obtained spherical polymers. In the presence of 1-hexene, activity of catalyst (a) was at its maximum. The comonomer 1-octene at 32 mmol presented its activity (1.7 × 10³ g polymer/(g cat.h)) and after that, the activities decreased. Copolymerization of ethylene and 1-hexene by catalyst (b) showed higher activity (1.6 × 10³ g polymer/ polymer/(g cat.h)) at 40 mmol concentration of 1-hexene in comparison to catalyst (a).     

Synthesis and characterization of niobium-promoted cobalt/iron catalysts supported on carbon nanotubes for the hydrogenation of carbon monoxide

Bimetallic Co /Fe catalysts supported on carbon nanotubes( CNTs) were prepared,and niobium( Nb) was added as promoter to the 70 Co ∶30Fe /CNT catalyst. The physicochemical properties of the catalysts were characterized,and the catalytic performances were analyzed at the same operation conditions( H_2 ∶CO( volume ratio) = 2 ∶1,p = 1 MPa,and t = 260 ℃) in a tubular fixed-bed microreactor system. The addition of Nb to the bimetallic catalyst decreases the average size of the oxide nanoparticles and improves the reducibility of the bimetallic catalyst. Evaluation of the catalyst performance in a Fischer-Tropsch reaction shows that the catalyst results in high selectivity to methane,and the selectivity to C_(5+) increased slightly in the bimetallic catalyst unlike that in the monometallic catalysts. The addition of 1% Nb to the bimetallic catalyst increases CO conversion and selectivity to C_(5+). Meanwhile,a decrease in methane selectivity is observed.     

Synthesis of 3,3‐Disubstituted Oxindoles via a Three‐Component Condensation Reaction in H2O

An efficient method has been developed for the synthesis of a novel series of unsymmetrically 3,3‐disubstituted oxindoles in good‐to‐high yields by a one‐pot three‐component condensation reaction of 2‐hydroxynaphthalene‐1,4‐dione, an isatin, and a barbituric acid derivative, in H₂O, and with p‐toluenesulfonic acid as a catalyst, at 90°. The effects of solvent, temperature, and the amount of catalyst on the yield of the reaction have been investigated. Additionally, the influence of hydrophilicity and hydrophobicity of the reactants on the selectivity of products has been examined.     

Realization of an interacting two-valley AlAs bilayer system

By using different widths for two AlAs quantum wells comprising a bilayer system, we force the X-point conduction-band electrons in the two layers to occupy valleys with different Fermi contours, electron effective masses, and g factors. Since the occupied valleys are at different X points of the Brillouin zone, the interlayer tunneling is negligibly small despite the close electron layer spacing. We demonstrate the realization of this system via magnetotransport measurements and the observation of a phase-coherent, bilayer nu=1 quantum Hall state flanked by a reentrant insulating phase.     

Compactification and signature transition in Kaluza-Klein spinor cosmology

We study the classical and quantum cosmology of a 4 + 1-dimensional space-time with a non-zero cosmological constant coupled to a self-interacting massive spinor field. We consider a spatially flat Robertson-Walker universe with the usual scale factor R (t) and an internal scale factor a (t) associated with the extra dimension. For a free spinor field the resulting equations admit exact solutions, whereas for a self-interacting spinor field one should resort to a numerical method for exhibiting their behavior. These solutions give rise to a degenerate metric and exhibit signature transition from a Euclidean to a Lorentzian domain. Such transitions suggest a compactification mechanism for the internal and external scale factors such that a ∼ R⁻¹ in the Lorentzian region. The corresponding quantum cosmology and the ensuing Wheeler-DeWitt equation have exact solutions in the mini-superspace when the spinor field is free, leading to wavepackets undergoing signature change. The question of stabilization of the extra dimension is also discussed.     

Spin-0 and spin-1/2 particles in a constant scalar-curvature background

We study the Klein-Gordon and Dirac equations in the presence of a background metric ds²=−dt²+dx²+e^−2gx(dy²+dz²) in a semi-infinite lab (x>0). This metric has a constant scalar-curvature R=6g² and is produced by a perfect fluid with equation of state p=−ρ/3. The eigenfunctions of spin-0 and spin-1/2 particles are obtained exactly, and the quantized energy eigenvalues are compared. It is shown that both of these particles must have nonzero transverse momentum in this background. We show that there is a minimum energy E²_min=m²c⁴+g²c²?² for bosons (E_KG>E_min), while the fermions have no specific ground state (E_Dirac>mc²).     

Tuning of tetrel bonds interactions by substitution and cooperative effects in XH3Si···NCH···HM (X = H,F, Cl,Br; M = Li,Na, BeH and MgH) complexes

In this work, the interplay between the tetrel bond and the dihydrogen bond is investigated in ternary XH₃Si···NCH···HM complexes, where X = H, F, Cl, Br and M = Li, Na, BeH, MgH. The nature of Si···N and H···H interactions is studied by molecular electrostatic potential (MEP), noncovalent interaction and electron localisation function analyses. All binding distances in the ternary complexes are shorter than those of isolated XH₃Si···NCH and NCH···HM systems. That is, the two types of interactions have a cooperative effect on each other. The results of the MEP analysis indicate that the enhancement of the Si···N and H···H bonds can mainly be attributed to the electrostatic interaction. The plot of the reduced density gradient versus sign (λ₂)ρ indicates that the location of the spike associated with each interaction in the ternary systems moves slightly towards the negative (λ₂)ρ values with respect to the binary systems. This confirms that both Si···N and H···H interactions in the ternary complexes are strengthened by the presence of other. Besides, cooperative effects lead to a considerable change in the ¹⁴N nuclear quadrupole coupling constant values of the ternary complexes relative to the XH₃Si···NCH complexes.