Thermodynamic basis for viscoelastic and non-isothermal fracture mechanics

Stability criteria for crack propagation have been analysed which are based on the second law of thermodynamics. The isothermal case has been studied both for elastic and viscoelastic materials. The non-isothermal criteria have been considered with particular attention to a fast adiabatic loading process.The thermodynamic constitutive equations which are demanded and their relationships with the elastic energy have been analyzed.     

Quantum ratchets in dissipative chaotic systems

Using the method of quantum trajectories, we study a quantum chaotic dissipative ratchet appearing for particles in a pulsed asymmetric potential in the presence of a dissipative environment. The system is characterized by directed transport emerging from a quantum strange attractor. This model exhibits, in the limit of small effective Planck constant, a transition from quantum to classical behavior, in agreement with the correspondence principle. We also discuss parameter values suitable for the implementation of the quantum ratchet effect with cold atoms in optical lattices.     

Partially dynamic maintenance of minimum weight hyperpaths

We address the problem of dynamically maintaining minimum weight hyperpaths in a directed hypergraph in a decremental setting. For such a problem, we provide a new efficient algorithm that works for a wide class of hyperpath weight measures. This algorithm explicitly updates minimum weight hyperpaths in

Full-size image

worst case time under a sequence of L hyperarc weight increments and hyperarc deletions, where C is the maximum weight of minimum hyperpaths in and is the size of the representation of the hypergraph. Hyperpath weight measures are only required to belong to the class of strict weakly superior functions.     

Nitrogen,phosphorus and organics removal in two vertical flow experimental wetlands receiving pretreated municipal wastewater

Pollutants removal in two vertical flow experimental wetlands receiving pre-treated municipal wastewater was investigated. Laboratory investigations using microcosms were also carried out in order to identify key processes regulating pollutants removal. Results obtained from experimental wetlands seem to confirm the ability of a single stage installation, where nitrification and denitrification processes are jointly optimised using a gravel medium, always wet but not saturated with water. Results obtained from microcosm investigations show the prominent role of O2 supply, of microbial activity and of bio-available C from vegetal metabolism in the nitrogen removal.     

On existence of undominated pure strategy Nash equilibria in anonymous nonatomic games: a generalization

In this paper, we generalize the exitence result for pure strategy Nash equilibria in anonymous nonatomic games. By working directly on integrals of pure strategies, we also generalize, for the same class of games, the existence result for undominated pure strategy Nash equilibria even though, in general, the set of pure strategy Nash equilibria may fail to be weakly compact. Received August 2001     

A sensitive and specific precursor ion scanning approach in liquid chromatography/electrospray ionization tandem mass spectrometry to detect methylprednisolone acetate and its metabolites in rat urine

A new, simple, sensitive and specific liquid chromatography/electrospray ionization tandem mass spectrometric (LC/ESI‐MS/MS) method in precursor ion scanning (PIS) mode has been developed for the rapid detection of methylprednisolone acetate (MPA) and its metabolites in rat urine. A suitable product ion specific for methylprednisolone (MP) and MPA was selected after a fragmentation study on 20 (cortico)steroids at different collision energies (5–40 eV). Urine samples were simply treated with acetonitrile then dried in a SpeedVac system. The method was validated and compared with other PIS methods for detecting corticosteroids in human urine. It was more sensitive, with limit of detection (LOD) and lower limit of quantitation (LLOQ), respectively, of 5 and 10 ng mL^?1. The method was applied for the analysis of rat urine collected before and after (24, 48, 72 h) intra‐articular (IA) injection of a marketed formulation of MPA (Depo‐Medrol®). MS/MS acquisitions were taken at different collision energies for the precursor ions of interest, detected in PIS mode, to verify the MP‐related structure. Six different metabolites were detected in rat urine, and their chemical structures were assigned with a computational study. Copyright © 2010 John Wiley & Sons, Ltd.     

Experimental analysis of the flow field around a propeller–rudder configuration

The problem of an isolated free-running propeller–rudder combination is tackled in the present paper. The activity concerns phase-averaged velocity measurements by LDV along two transversal planes of the wake, just in the front and behind the rudder. In addition, visualizations of the chordwise interaction between the tip vortex filaments and the rudder, performed using a time resolved CMOS camera, are presented. The major phenomena that affect the performance of a rudder in the race of a propeller, with special emphasis on unsteady-flow aspects, are highlighted in this paper.     

A biofunctional polymeric coating for microcantilever molecular recognition

An innovative route to activate silicon microcantilevers (MCs) for label free molecular recognition is presented. The method consists in coating the underivatized MCs with a functional ter-polymer based on N,N-dimethylacrylamide (DMA) bearing N-acryloyloxysuccinimide (NAS) and 3-(trimethoxysilyl)propyl-methacrylate (MAPS), two functional monomers that confer to the polymer the ability to react with nucleophilic species on biomolecules and with glass silanols, respectively. The polymer was deposited onto MCs by dip coating. Polymer coated MCs were tested in both static and dynamic modes of actuation, featuring detection of DNA hybridization as well as protein/protein interaction. In the dynamic experiments, focused on protein detection, the MCs showed an average mass responsivity of 0.4 Hz/pg for the first resonant mode and of 2.5 Hz/pg for the second resonant mode. The results of the static experiments, dedicated to DNA hybridization detection, allowed for direct estimation of the DNA duplex formation energetics, which resulted fully consistent with the nominal expected values. These results, together with easiness and cheapness, high versatility, and excellent stability of the recognition signal, make the presented route a reliable alternative to standard SAM functionalization (for microcantilevers (MCs) and for micro-electro-mechanical systems (MEMS) in general).