Fifteen years of nuclear techniques application to suspended particulate matter studies

Acute and chronic exposures to Airborne Particulate Matter (APM) have been linked, in epidemiological studies, to increased mortality and to a wide spectrum of respiratory and cardiovascular disorders. One factor that highly influences the toxicity of APM is its chemical composition. Nuclear Analytical Techniques (NATs) can be advantageously used in the determination of the particles element composition due to their multielement capability in association with low detection limits. Therefore, the characterization of APM by these techniques contributes to the identification of emission sources and, consequently, to the assessment of the effectiveness of the current air pollution abatement strategies. The main goal of this paper was to present the achievements obtained within 15 years of activities related with the use of NATs on the analysis of APM sampled in outdoor, indoor and industrial environments. The results presented in this work confirmed the relevance of NATs as efficient analytical techniques not only in the characterization of APM, but also in source apportionment, identification of long range transport and health assessment studies.     

In situ Raman and in situ XRD analysis of PdO reduction and Pd° oxidation supported on γ-Al2O3 catalyst under different atmospheres

Reduction of Pd° and decomposition of palladium oxide supported on γ-alumina were studied at atmospheric pressure under different atmospheres (H(2), CH(4), He) over a 4 wt% Pd/Al(2)O(3) catalyst (mean palladium particle size: 5 nm with 50% of small particles of size below 5 nm). During temperature programmed tests (reduction, decomposition and oxidation) the crystal domain behaviour of the PdO/Pd° phase was evaluated by in situ Raman spectroscopy and in situ XRD analysis. Under H(2)/N(2), the reduction of small PdO particles (<5 nm) occurs at room temperature, whereas reduction of larger particles (>5 nm) starts at 100 °C and is achieved at 150 °C. Subsequent oxidation in O(2)/N(2) leads to reoxidation of small crystal domain at ambient temperature while oxidation of large particles starts at 300 °C. Under CH(4)/N(2), the small particle reduction occurs between 240 and 250 °C while large particle reduction is fast and occurs between 280 and 290 °C. Subsequent reoxidation of the catalyst reduced in CH(4)/N(2) shows that small and large particle oxidation of Pd° starts also at 300 °C. Under He, no small particle decomposition is observed probably due to strong interactions between particles and support whereas large particle reduction occurs between 700 and 750 °C. After thermal decomposition under He, the oxidation starts at 300 °C. Thus, the reduction phenomenon (small and large crystal domain) depends on the nature of the reducing agent (H(2), CH(4), He). However, whatever the reduction or decomposition treatment or the crystal domain, Pd° oxidation starts at 300 °C and is completed only at temperatures higher than 550 °C. Under lean conditions, with or without water, the palladium consists of reduced sites of palladium (Pd°, Pd(δ+) with δ < 2 or PdO(x) with x < 1) randomly distributed on palladium particles.     

Simultaneous Determination of Caffeine and Acetylsalicylic Acid in Pharmaceutical Formulations Using a Boron‐Doped Diamond Film Electrode by Differential Pulse Voltammetry

This work presents a simple, fast and low‐cost method for simultaneous determination of acetylsalicylic acid (ASA), without alkaline hydrolysis and caffeine (CF) in pharmaceutical formulations using a boron‐doped diamond as the working electrode through differential pulse voltammetry. A good repeatability was reached for 20 measurements, with a low relative standard deviation of less than 1.0 %. The calibration curves presented a great linear correlation coefficient for both drugs (R=0.999) with a limit of detection of 1.6×10^?7 mol L^?1 for CF and 2.3×10^?7 mol L^?1 for ASA. The system was validated in comparison with the official method.     

A fourth‐order method for numerical integration of age‐ and size‐structured population models

In many applications of age‐ and size‐structured population models, there is an interest in obtaining good approximations of total population numbers rather than of their densities. Therefore, it is reasonable in such cases to solve numerically not the PDE model equations themselves, but rather their integral equivalents. For this purpose quadrature formulae are used in place of the integrals. Because quadratures can be designed with any order of accuracy, one can obtain numerical approximations of the solutions with very fast convergence. In this article, we present a general framework and a specific example of a fourth‐order method based on composite Newton‐Cotes quadratures for a size‐structured population model. © 2008 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2009     

Palythine–threonine,a major novel mycosporine-like amino acid (MAA) isolated from the hermatypic coral Pocillopora capitata

Using a high-resolution reverse-phase liquid chromatography method we found that the tissues of the hermatypic coral Pocillopora capitata (collected in Santiago Bay, Mexico) contain a high diversity of primary and secondary mycosporine-like amino acids (MAAs) typical of some reef-building coral species: mycosporine–glycine, shinorine, porphyra-334, mycosporine–methylamine–serine, mycosporine–methylamine–threonine, palythine–serine, palythine and one additional novel predominant MAA, with an absorbance maximum of 320 nm. Here we document the isolation and characterization of this novel MAA from the coral P. capitata. Using low multi-stage mass analyses of deuterated and non deuterated compounds, high-resolution mass analyses (Time of Flight, TOF) and other techniques, this novel compound was characterized as palythine–threonine. Palythine–threonine was also present in high concentrations in the corals Pocillopora eydouxi and Stylophora pistillata indicating a wider distribution of this MAA among reef-building corals. From structural considerations we suggest that palythine–threonine is formed by decarboxylation of porphyra-334 followed by demethylation of mycosporine–methylamine–threonine.     

Synthesis and liquid crystalline properties of low molecular mass compounds containing the 1,4-bis(5-phenyl-1,3,4-oxadiazolyl)benzene unit

The synthesis and characterization of low molecular mass compounds containing 1,4-bis(5-phenyl-1,3,4-oxadiazolyl)benzene is reported. All compounds are fluorescent in solution. Due to the flat shape of the conjugated unit, smectic-like packing is observed at high temperatures for some of the synthesized compounds. Moreover the insertion of a lateral flexible alkoxy unit strongly destabilizes the smectic order whilst promoting the appearance of a nematic phase in the case of the shortest methoxy unit. The mesogenic character of this unit may be of interest in the synthesis of liquid crystalline polymeric systems, taking advantage of both the fluorescent properties and the peculiar molecular structure of the liquid crystalline state.     

On the energetics of the Gamow-Teller resonances

It is suggested that the energy difference between the Gamow-Teller and Fermi resonances is given in units of MeV, by ${}^{\mathrm{E}}\text{GT}\text{?}{}^{\mathrm{E}}\text{F}\text{=26A}{}^{\mathrm{<mtext>?</mtext><mtext>1</mtext><mtext>3</mtext>}}\text{?18.5 (N ? Z)/A}$. The consequences of this result on the strength of the spin and isospin-dependent residual interaction, as well as on the effective axial-vector coupling constant, are discussed.     

On the numerical computation of Generalized Burmester Points

This note describes a procedure for plane higher-curvature path analysis and synthesis. All coefficients have been written in terms of elementary instantaneous invariants. This facilitates the numerical computation of Generalized Burmester Points for a moving link of a planar mechanism in a non-symmetric position. FORTRAN subroutines have been written and a numerical example is provided.

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Sommario Si descrive una procedura di analisi e sintesi per meccanismi piani generatori di traiettoria con approssimazione del quarto ordine. Nella formulazione adottata, l'impiego degli invarianti istantanei elementari consente di valutare analiticamente i termini delle equazioni per la ricerca dei punti generalizzati di Burmester. Sono state implementate subroutines in linguaggio FORTRAN ed è stato sviluppato un esempio numerico.

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Nomenclature P _o velocity pole - inflection circle diameter - angle of rotation of the moving body - r _f ,r _m radii of curvature of the fixed and moving polodes, respectively - dl infinitesimal arc length measured on the polode - a,b coordinates ofP _o , in the canonical reference system¹ - a _i ,b _i i-th derivatives ofa andb, respectively, computed at the initial position (i.e. =0). These are the elementary instantaneous invariants - h,* polar coordinates of the moving point in the canonical reference system (0 ) - radius of curvature of the point-path trajectory - _E radius of curvature of the evolute of the point-path trajectory - _E ^/(2) radius of curvature of the evolute of the evolute of the point-path trajectory A canonical reference system is a rectangular right-handed cartesian system having they-axis directed toward inflexion pole, origin in the velocity pole.