A counterexample to the reconstruction of <Emphasis Type="Italic">ω</Emphasis>-categorical structures from their endomorphism monoid

We present an example of two countable ω-categorical structures, one of which has a finite relational language, whose endomorphism monoids are isomorphic as abstract monoids, but not as topological monoids—in other words, no isomorphism between these monoids is a homeomorphism. For the same two structures, the automorphism groups and polymorphism clones are isomorphic, but not topologically isomorphic. In particular, there exists a countable ω-categorical structure in a finite relational language which can neither be reconstructed up to first-order biinterpretations from its automorphism group, nor up to existential positive bi-interpretations from its endomorphism monoid, nor up to primitive positive bi-interpretations from its polymorphism clone.     

Gas-phase fragmentation studies of cyclic oligo-β-(1→6)-D-glucosamines by electrospray ionization mass spectrometry using a hybrid high-resolution mass spectrometer

Positive and negative ion high-resolution electrospray ionization mass spectra (MS and MS₂) of cyclooligo-β-(1→6)-D-glucosamines and cyclooligo-β-(1→6)-N-acetyl-D-glucosamines were acquired and interpret. It was shown that the cleavages of glycosidic bonds are the main processes in the decay of protonated and metallated molecules. In addition, elimination of the water molecules (and ammonia for cyclooligo-β-(1→6)-D-glucosamines) was observed along with other processes including the unknown skeletal rearrangement. A primary fragmentation of the negatively charged ions (deprotonated molecules) differed from that of the positively charged ones.