全文获取类型
收费全文 | 31268篇 |
免费 | 5606篇 |
国内免费 | 3320篇 |
专业分类
化学 | 22210篇 |
晶体学 | 352篇 |
力学 | 1813篇 |
综合类 | 141篇 |
数学 | 3004篇 |
物理学 | 12674篇 |
出版年
2024年 | 135篇 |
2023年 | 694篇 |
2022年 | 1218篇 |
2021年 | 1384篇 |
2020年 | 1407篇 |
2019年 | 1399篇 |
2018年 | 1183篇 |
2017年 | 1060篇 |
2016年 | 1601篇 |
2015年 | 1532篇 |
2014年 | 1965篇 |
2013年 | 2410篇 |
2012年 | 2874篇 |
2011年 | 2895篇 |
2010年 | 1883篇 |
2009年 | 1792篇 |
2008年 | 2000篇 |
2007年 | 1742篇 |
2006年 | 1634篇 |
2005年 | 1289篇 |
2004年 | 985篇 |
2003年 | 771篇 |
2002年 | 758篇 |
2001年 | 587篇 |
2000年 | 467篇 |
1999年 | 595篇 |
1998年 | 513篇 |
1997年 | 503篇 |
1996年 | 494篇 |
1995年 | 427篇 |
1994年 | 345篇 |
1993年 | 282篇 |
1992年 | 284篇 |
1991年 | 225篇 |
1990年 | 202篇 |
1989年 | 153篇 |
1988年 | 95篇 |
1987年 | 79篇 |
1986年 | 109篇 |
1985年 | 73篇 |
1984年 | 37篇 |
1983年 | 44篇 |
1982年 | 28篇 |
1981年 | 22篇 |
1980年 | 7篇 |
1979年 | 4篇 |
1975年 | 1篇 |
1959年 | 1篇 |
1957年 | 4篇 |
1923年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
241.
针对工业设备中比例溢流阀调压特性不易测量的难点问题,提出"实验测量与分析模块化"和"数据三维可视化"的测控思路,设计了新的比例溢流阀调压特性实验方案和基于虚拟仪器LabVIEW与MATLAB相结合的测量系统,实现了对多点压力信号的实时采集和对数据信号的线性度、组合时频、三维可视化等多样分析;实验表明:所测比例溢流阀的线性度与测试精度分别达到2.47%和0.01%;并准确捕捉到100ms(毫秒级)内调压信息;实测证明该测量系统设计合理,突显了其自动化测量与智能化分析的优点,为今后比例阀的开发与工程实测拓宽研究思路、提供参考依据。 相似文献
242.
We performed a systematic study on the exchange bias in (1 1 0)-orientated Bi0.9La0.1FeO3/La0.5Ca0.5MnO3 (BLFO/LCMO) heterostructure with a fixed BLFO film thickness of 600 nm and different LCMO layers ranging from t=0 to 30 nm. The LCMO is found to be weakly ferromagnetic, with the Curie temperature descending from ∼225 K to 0 as the layer thickness decreases from 30 nm to 3 nm. The main magnetic contributions come from the BLFO film, and the areal magnetization ratio is 1:0.07 for t=5 nm and 1:0.82 for t=30 nm for BLFO to LCMO at the temperature of 5 K. Further experiments show the presence of significant exchange bias, and it is, at the temperature of 10 K, ∼40 Oe for t=0 and ∼260 Oe for t=30 nm. The exchange bias reduces dramatically upon warming and disappears above the blocking temperature of the spin-glasslike behavior observed in the samples. The possible origin for exchange bias is discussed. 相似文献
243.
P. Zhao D.S. Liu Y. Zhang Y. Su H.Y. Liu S.J. Li G. Chen 《Solid State Communications》2012,152(12):1061-1066
Using first-principles density functional theory and non-equilibrium Green's function formalism for quantum transport calculation, we have investigated the electronic transport properties of heteronanotubes by joining a zigzag (6,0) carbon nanotube and a zigzag (6,0) boron nitride nanotube with different atomic compositions and joint configurations. Our results show that the atomic composition and joint configuration affect strongly the electronic transport properties. Obvious negative differential resistance behavior and large rectifying behavior are obtained in the heterostructure with certain composition and joint configuration. Moreover, tube length and tube radius can affect strongly the observed NDR and rectifying behaviors. The observed negative differential resistance and rectifying behaviors are explained in terms of the evolution of the transmission spectrum with applied bias combined with molecular projected self-consistent Hamiltonian states analysis. 相似文献
244.
A series of novel bis-pyrazoline derivatives were synthesized by the reaction of chalcone and (sulfonylbis(3,1-phenylene))bis(hydrazine) in 20–34% yields. The structures of the compounds were determined by IR, 1H NMR, HRMS spectra, and a representative compound 3b was confirmed based on the X-ray crystallographic analysis. Absorption and fluorescence spectra of these compounds in dichloromethane solution were investigated. The results showed that the emission maxima varied from 415 to 444 nm mainly depending on C3 substituents of pyrazoline moiety. The compounds had higher quantum yields, when C3 substituent was an electron-withdrawing p-chlorophenyl group. Moreover, absorption spectra and emission spectra exhibited a blue-shift and a red-shift with increasing the polarity of solvents, respectively. Fluorescent molecules happened to collide with each other and resulted in quench of the fluorescence when the concentration increased over to 10?5 M. 相似文献
245.
Applicability of the angular properties of scatter elements as a tool to achieve improved slow light performance with small group velocity dispersion and large bandwidth in photonic crystal waveguides is investigated. A polyatomic photonic crystal waveguide, including two scatter elements with different geometrical shapes in each primitive cell, is proposed to investigate the feasibility of our method. Numerical results show that a versatile control of the dispersion relation of slow light modes, with large normalized delay-bandwidth products ranging from 0.2085 to 0.3394, can be obtained using a unique geometrical parameter. 相似文献
246.
通过理论分析和数值计算证明了闭合PCM结构可以在窄边和宽边两个横方向上对接近真实情形的带状注束流进行有效约束,实现电子注的长距离稳定传输.提出了匹配电子注宽边方向横向磁聚焦力与带状注内空间电荷力的方法,这可用于确定闭合PCM聚焦结构的纵向周期长度以及截面尺寸.所做计算还显示出闭合PCM结构横截面的宽边方向尺度可以独立调节以达到最优的匹配.此外,进一步证明了偏置PCM结构不能有效约束带状电子注.本工作表明闭合PCM结构用于限制带状注束流具有很大潜力并且有助于指导实际的工程实践. 相似文献
247.
Signals of ultracold plasma are observed by two-photon
ionization of laser-cooled caesium atoms in a magneto-optical trap.
Recombination of ions and electrons into Rydberg atoms during the
expansion of ultracold plasma is investigated by using
state-selective field ionization spectroscopy. The dependences of
recombination on initial electron temperature (1--70 K) and initial
ion density ($ \sim $10$^{10}$ cm$^{ - 3})$ are investigated. The
measured dependence on initial ion density is $N^{1.547\pm 0.004}$
at a delay time of 5 $\mu $s. The recombination rate rapidly
declines as initial electron temperature increases when delay time
is increased. The distributions of Rydberg atoms on different values
of principal quantum number $n$, i.e. $n=30$--60, at an initial
electron temperature of 3.3 K are also investigated. The main
experimental results are approximately explained by the three-body
recombination theory. 相似文献
248.
249.
The experiments have been performed with a semi-continuous batch reactor to investigate the degradation efficiency of nitrobenzene in aqueous solution by ultrasound with the different orthogonal dual frequencies catalytic ozonation. The introduction of ultrasound can enhance the degradation efficiency of nitrobenzene compared to the results obtained from the processes of ozonation alone and ultrasound alone. The degradation of nitrobenzene is found to be zero-order in the two systems of ultrasound alone, and the reactions follow the pseudo-first-order kinetic model in the processes of ozone alone and ozone/ultrasound. The investigation confirms that the degradation of nitrobenzene follows the mechanism of hydroxyl radical (•OH) oxidation, and the enhancement function is even more pronounced in the presence of ultrasound with the greater difference between the orthogonal dual frequencies due to the obvious synergetic effect between ozone and ultrasound, which increases the utilization efficiency of ozone, and accelerates the initiation of •OH and the formation of H2O2, resulting in the rapid formation of an increasing diversity of byproducts and the advancement degree of mineralization of total organic carbon (TOC). The oxidative byproducts have been, respectively identified in the different processes selected, including o, p, m-nitrophenols, phenol, malonic acid, 4-nitrocatechol, nitrate ion, maleic acid, oxalic acid, hydroquinone, p-quinone, 1,2,3-trihydroxy-5-nitrobenzene and acetic acid. 相似文献
250.
A new noninvasive method is proposed for optically imaging blood under skin. A mini-mirror is used to guide the light incident onto the skin surface, while blocking specularly reflected light from the tissue. Moreover, by using two linear polarizers at right angles, the specular reflection can be reduced further, while also blocking the rough surface scattered light. A circular polarizer may be used to obtain the same effect. As a result, the blood flow beneath the surface of skin can be visualized clearly. The effect of the mini-mirror is also analyzed theoretically and experimentally. 相似文献