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981.
In this work, the melting behaviors of nonisothermally and isothermally melt‐crystallized poly(L ‐lactic acid) (PLLA) from the melt were investigated with differential scanning calorimetry (DSC) and temperature‐modulated differential scanning calorimetry (TMDSC). The isothermal melt crystallizations of PLLA at a temperature in the range of 100–110 °C for 120 min or at 110 °C for a time in the range of 10–180 min appeared to exhibit double melting peaks in the DSC heating curves of 10 °C/min. TMDSC analysis revealed that the melting–recrystallization mechanism dominated the formation of the double melting peaks in PLLA samples following melt crystallizations at 110 °C for a shorter time (≤30 min) or at a lower temperature (100, 103, or 105 °C) for 120 min, whereas the double lamellar thickness model dominated the formation of the double melting peaks in those PLLA samples crystallized at a higher temperature (108 or 110 °C) for 120 min or at 110 °C for a longer time (≥45 min). © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 466–474, 2007 相似文献
982.
Nikulin S. S. Akatova I. N. Kondrat'eva N. A. 《Russian Journal of Applied Chemistry》2003,76(4):652-655
The influence of the charge of a metal cation and the nature of a coagulant on the recovery of butadiene-styrene rubber and properties of rubber stocks and vulcanizates was examined. 相似文献
983.
Shawn Shih 《中国化学会会志》2003,50(4):815-822
A large class of stereochemcial and related interactions in organic chemistry are repulsive and others are attractive, but the relative orientation of two methyl groups and the amount of energy required to twist one relative to the other (the hindered rotation energy barriers), or the alignment of such a group with respect to a conjugated ring to which it is attached (widely attributed to a mechanism called “hyperconjugation”) are estimated to be small in compared with the total energy of the molecule. We used theories of both isotropic and anisotropic proton hyperfine interactions in the π‐electron systems developed in the early sixties. They are approximated by the magnetic dipole nteractions between each proton and an electron spin magnetization that is distributed in 2s and 2p Slater atomic orbitals center on carbon atoms. We have extended these theories to the non‐planar olefinic cation radicals, which are very important in biochemistry as well as in petroleum catalysis. A three dimensional electron spin density equation has been developed in this paper to handle some Jahn‐Teller vibronic molecules. The new electron spin density equation related the observed proton hyperfine splittings to the non‐planar structures of the open‐chain alkene cation radicals generated by radiolysis and various chemical oxidation methods. The spin densities and the conformational calculations based on valence bond theory and symmetry principles are compared with some more elaborated molecular orbital calculations in the literature. The localized valence bond approaches are better in accord with our experimental results. The anomalous line‐width effect of the four methyl groups observed in the 2,3‐dimethyl‐2‐butene cation radicals also confirmed the positive sign of the electron‐proton hyperfine constant of hyper‐conjugation mechanism. A methyl substituent attached to a conjugated molecule often behaves as if it formed part of the region of conjugation; the charge appears to flow from the methyl group into the π electron system and it may also give rise to an appreciable dipole moment. Methylation also gives rise to an appreciable dipole moment, and the resultant red shift of electronic absorption bands is of some importance in the design of dye molecules. 相似文献
984.
985.
The effect of an applied magnetic field on an inhomogeneous superconductor is studied and the value of the upper critical magnetic field Hc3 at which superconductivity can nucleate is estimated. In addition, the authors locate the concentration of the order parameter, which depends on the inhomogeneous term a(x). Unlikely to the homogeneous case, the order parameter may concentrate in the interior of the superconducting material, due to the influence of the inhomogeneous term a(x). 相似文献
986.
T. I. Khabakhpasheva 《Fluid Dynamics》2003,38(4):592-600
The problem of surface wave diffraction on a floating elastic plate is considered. The relation between the parameters of the elastic vibrations of the plate and the transmitted and reflected wave amplitudes is investigated. It is shown that the maximum amplitudes of the plate stresses and deflections depend nonmonotonically on the incident wave frequency and are reached simultaneously with the maxima of both the transmission coefficient and the length of the wave penetrating into the plate. This makes it possible to use the transmission coefficient as a parameter for investigating the maximum and minimum amplitudes of the hydroelastic vibrations of the plate. As an example, this criterion is used to minimize the vibrations of a plate whose leading edge is elastically connected to the bottom. 相似文献
987.
Zhen‐Feng Chen Hong‐Li Zhou Hong Liang Yan Li Ren‐Gen Xiong Xiao‐Zeng You 《应用有机金属化学》2003,17(11):883-884
The centrosymmetric binuclear structure of [Pb2(H‐Norf)2(ONO2)4]shows the geometry around each lead(II) atom to be distorted trigonal bipyramidal with Pb–O distances ranging from 2.357(3) to 2.769(4) Å. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
988.
In this paper, we study Steinberg unitary Lie conformal algebras, which are universal central extensions of unitary Lie conformal
algebras. We describe the kernels of these extensions by means of skew-dihedral homology.
__________
Translated from Fundamentalnaya i Prikladnaya Matematika, Vol. 11, No. 2, pp. 135–155, 2005. 相似文献
989.
We study the generalization of the Willmore functional for surfaces in the three-dimensional Heisenberg group. Its construction is based on the spectral theory of the Dirac operator entering into theWeierstrass representation of surfaces in this group. Using the surfaces of revolution we demonstrate that the generalization resembles the Willmore functional for the surfaces in the Euclidean space in many geometrical aspects. We also observe the relation of these functionals to the isoperimetric problem. 相似文献
990.
V. A. Sadovnichy V. V. Alexandrov E. Soto T. B. Alexandrova T. G. Astakhova R. Vega N. V. Kulikovskaya V. I. Kurilov S. S. Migunov N. E. Shulenina 《Journal of Mathematical Sciences》2007,146(3):5938-5947
A mathematical model of the system composed of two sensors, the semicircular canal and the sacculus, is suggested. The model
is described by three lines of blocks, each line of which has the following structure: a biomechanical block, a mechanoelectrical
transduction mechanism, and a block describing the hair cell ionic currents and membrane potential dynamics. The response
of this system to various stimuli (head rotation under gravity and falling) is investigated. Identification of the model parameters
was done with the experimental data obtained for the axolotl (Ambystoma tigrinum) at the Institute of Physiology, Autonomous
University of Puebla, Mexico. Comparative analysis of the semicircular canal and sacculus membrane potentials is presented.
__________
Translated from Fundamentalnaya i Prikladnaya Matematika, Vol. 11, No. 7, pp. 207–220, 2005. 相似文献