首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   37854篇
  免费   10154篇
  国内免费   1890篇
化学   42942篇
晶体学   369篇
力学   660篇
综合类   33篇
数学   2330篇
物理学   3564篇
  2024年   6篇
  2023年   109篇
  2022年   149篇
  2021年   310篇
  2020年   1365篇
  2019年   2688篇
  2018年   1124篇
  2017年   747篇
  2016年   3509篇
  2015年   3661篇
  2014年   3609篇
  2013年   4229篇
  2012年   3166篇
  2011年   2409篇
  2010年   3007篇
  2009年   2974篇
  2008年   2522篇
  2007年   1914篇
  2006年   1585篇
  2005年   1742篇
  2004年   1512篇
  2003年   1379篇
  2002年   2070篇
  2001年   1442篇
  2000年   1353篇
  1999年   463篇
  1998年   134篇
  1997年   128篇
  1996年   105篇
  1995年   87篇
  1994年   65篇
  1993年   38篇
  1992年   48篇
  1991年   46篇
  1990年   27篇
  1989年   20篇
  1988年   22篇
  1987年   23篇
  1986年   16篇
  1985年   12篇
  1984年   18篇
  1983年   6篇
  1982年   7篇
  1981年   4篇
  1980年   11篇
  1978年   6篇
  1976年   8篇
  1975年   5篇
  1972年   5篇
  1971年   2篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
It is proved that the variety of relevant disjunction lattices has the finite embeddability property. It follows that Avron's relevance logic RMI min has a strong form of the finite model property, so it has a solvable deducibility problem. This strengthens Avron's result that RMI min is decidable. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
52.
Fiber-optic reflex sensor for in-line production measurement   总被引:1,自引:0,他引:1  
The paper describes experiments concerning distance measurement with fiber-optic sensor and improvement of the measurement principle. The sensor probe was well-designed with a small structure and multi-function. The novel optical fiber probe arrangement as well as the possibilities of use for complex measurement problems are explained using the measurement of an internal screw thread as an example. The experimental results show that the measurement uncertainty of the thread minor diameter can reach ±10 μm, and the stability of the measurement system is better than 0.07%.  相似文献   
53.
ROBUST GLOBAL EXPONENTIAL STABILITY OF UNCERTAIN IMPULSIVE SYSTEMS   总被引:2,自引:0,他引:2  
By using the quasi-Lyapunov function, some sufficient conditions of global exponential stability for impulsive systems are established, which is the basis for the following discussion. Then, by employing Riccati inequality and Hamilton-Jacobi inequality approach, some sufficient conditions of robust exponential stability for uncertain linear/nonlinear impulsive systems are derived, respectively. Finally, some examples are given to illustrate the applications of the theory.  相似文献   
54.
55.
56.
A graph G is N2locally connected if for every vertex ν in G, the edges not incident with ν but having at least one end adjacent to ν in G induce a connected graph. In 1990, Ryjá?ek conjectured that every 3‐connected N2‐locally connected claw‐free graph is Hamiltonian. This conjecture is proved in this note. © 2004 Wiley Periodicals, Inc. J Graph Theory 48: 142–146, 2005  相似文献   
57.
In the title compound, catena‐poly[lithium‐μ3‐ethyl­ene­diphos­phon­ato], [Li(C2H7O6P2)]n, the supra­molecular monoclinic (C2/c) structure consists of one‐dimensional lithium chains [Li⋯Li = 2.7036 (8) Å] that are embedded within ethyl­ene­diphosphon­ate anions linked by strong symmetric hydrogen bonds [O⋯O = 2.473 (3) Å]. The Li atoms and the H atom in the symmetric hydrogen bond reside on twofold rotation axes and there is an inversion center at the mid‐point of the C—C bond of the ethylenediphosphonate ligand.  相似文献   
58.
The inhomogeneous Dirichlet problems concerning divergence form elliptic equations are studied. Optimal regularity requirements on the coefficients and domains for the W1,p theory, 1 < p < ∞, are obtained. The principal coefficients are supposed to be in the John‐Nirenberg space with small BMO seminorms. The domain is a Reifenberg domain. These conditions for the W1,p theory not only weaken the requirements on the coefficients but also lead to a more general geometric condition on the domains. In fact, these domains might have fractal dimensions. © 2004 Wiley Periodicals, Inc.  相似文献   
59.
Wang  Qing-Lun  Zhao  Bin  Liao  Dai-Zheng  Yan  Shi-Ping  Cheng  Peng  Jiang  Zong-Hui 《Transition Metal Chemistry》2003,28(3):326-330
The copper(II) complex Na2[Cu(pba)] · 6H2O has been synthesized and its structure determined. It consists of a novel two-dimensional network of [Cu(pba)]2– anions connected to each other through the sodium ion as a bridge. Spectroscopic and magnetic properties have been measured and a spin distribution calculation has been carried out with the GAUSSIAN-94. Theoretical calculations indicate the rather larger spin density on nitrogen atoms should be responsible for the satellite lines appearing beside the main hyperfine coupling signs of copper(II). The antiferromagnetic interaction may be due to the intermolecular interaction and/or different copper(II) ions through the Na+ bridge in the same layer.  相似文献   
60.
A new MnIII‐Schiff base complex, [MnL(OH2)](ClO4) ( 1 ) (H2L = N, N′‐bis‐(3‐Br‐5‐Cl‐salicylidene)‐1, 2‐diimino‐2‐methylethane), an inorganic model of the catalytic center (OEC, Oxygen Evolving Complex) in photosystem II (PSII), has been synthesized and characterized by elemental analysis, IR and EPR spectroscopy, mass spectrometry, magnetic susceptibility measurement and the study of its redox properties by cyclic and normal pulse voltammetry. This complex mimics reactivity (showing a relevant photolytic activity), and also some structural characteristics (parallel‐mode MnIII EPR signal from partially assembled OEC cluster) of the natural OEC. The complex 1 was found to rearrange in solution into a crystallographically solved square‐pyramidal complex, [MnLL′] ( 2 ) (HL′ = 6‐bromo‐4‐chloro‐2‐cyanophenol), through a process, which probably liberates radical species (detected by EPR), and provokes a C—N bond cleavage in the ligand. A photo‐radical mechanism is discussed to explain this rearrangement.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号