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81.
Pierre Asselin Yacine Belkhodja Atef Jabri Alexey Potapov Ad van der Avoird 《Molecular physics》2018,116(23-24):3642-3655
ABSTRACTFive ortho and para bands of the ν2 umbrella mode of the NH3–Ar van der Waals complex have been recorded at high resolution using jet-cooled infrared laser spectroscopy. A rovibrational analysis provides accurate band centres and upper state rotational constants for the Πs(j?=?1,k?=?0)?←?Σa(j,k?=?0) and Σs(j?=?1,k?=?0)?←?Σa(j,k?=?0) ortho bands. The puzzling para bands observed in the region of the lower and upper components of the inversion splitting doublet have been assigned by comparison with rovibrational and tunnelling levels and transitions calculated ab initio. The latter calculations are based on the four-dimensional potential energy surface reported by Loreau et al. [J. Chem. Phys. 141, 224303 (2014)], which takes explicitly into account the umbrella motion of the ammonia molecule. The very good agreement found between Πs/a,lower(j?=?1,k?=?1)?←?Σa(j?=?1,k?=?1) and Πs/a,upper(j?=?1,k?=?1)?←?Σs(j?=?1,k?=?1) experimental and calculated transitions has been exploited to determine precisely two different inversion splittings in the ν2 state (32.003(1) and 36.008(1)?cm?1) from extrapolated Q(0) line frequencies and to obtain a qualitative picture of Coriolis couplings present in both the ν2?=?0 and ν2?=?1 states. 相似文献
82.
Franz Wautier Sabine Wislet-Gendebien Grazyna Chanas Bernard Rogister Pierre Leprince 《BMC neuroscience》2007,8(1):104
Background
Bone marrow stromal cells and radial glia are two stem cell types with neural phenotypic plasticity. Bone marrow mesenchymal stem cells can differentiate into osteocytes, chondrocytes and adipocytes, but can also differentiate into non-mesenchymal cell, i.e. neural cells in appropriate in vivo and in vitro experimental conditions. Likewise, radial glial cells are the progenitors of many neurons in the developing cortex, but can also generate astrocytes. Both cell types express nestin, an intermediate filament protein which is the hallmark of neural precursors. 相似文献83.
Jocelyn D Laughton Philippe Bittar Yves Charnay Luc Pellerin Enikö Kovari Pierre J Magistretti Constantin Bouras 《BMC neuroscience》2007,8(1):35
Background
For a long time now, glucose has been thought to be the main, if not the sole substrate for brain energy metabolism. Recent data nevertheless suggest that other molecules, such as monocarboxylates (lactate and pyruvate mainly) could be suitable substrates. Although monocarboxylates poorly cross the blood brain barrier (BBB), such substrates could replace glucose if produced locally. 相似文献84.
The core-shell structure of a range of acrylic-acrylic latexes has been investigated by combining different specimen preparation methods with transmission electron microscopy (TEM), dark-field scanning transmission electron microscopy (DSTEM) and low-voltage scanning electron microscopy (LV-SEM), including the first reported use of LV-SEM to observe composite latex particles at ambient and subambient temperatures. Spin-coating of liquid latex dispersions directly onto TEM grids or SEM stubs is shown to be a relatively straightforward mean of avoiding film formation during specimen preparation. In conjunction with double staining techniques, it has been found to be particularly convenient for characterizing the fine structure of particles with diameters down to below 100 nm. 相似文献
85.
Bermejo D Martínez RZ Loubignac E Boudon V Pierre G 《Journal of Molecular Spectroscopy》2000,201(1):164-171
High-resolution Raman spectra of the nu(2) band of SF(6) have been recorded at a temperature of 195 K (dry ice) and a pressure of 39 mbar. These spectra were analyzed using a new set of programs specially written for XY(6) molecules. These programs, called HTDS (highly spherical top data system) in reference to the set of programs called STDS (spherical top data system written for XY(4) molecules) can be freely accessible through ftp (user anonymous) at jupiter.u-bourgogne.fr or on the web at the URL http://www.u-bourgogne.fr/LPUB/shTDS.html. The study of nu(2) was made using a Hamiltonian developed through the third order. Four parameters were determined. The standard deviation obtained using about 559 data up to J < 61 is 0.0021 cm(-1). This result is used to refine by simultaneous analysis the nu(2) and nu(2) + nu(6) bands of SF(6). This new fit allows the determination for the first time of some nu(6) parameters. The values obtained for this band (forbidden in Raman and in infrared) will be used to study the infrared hot bands in the nu(3) and nu(4) regions. Copyright 2000 Academic Press. 相似文献
86.
X-ray photoemission spectra, resistivity and susceptibility of CeNi2Sb2 and CeCu2Sb2 were measured and are discussed. The results indicate that these alloys are Kondo systems. For comparison of the valence band properties, the spectra of the isostructural alloys of RT2X2-type with R = La, Gd, T = Cu, Ni and X = Sn, Sb were investigated, too. 相似文献
87.
Pierre Pigeaud 《Reports on Mathematical Physics》1978,14(2):261-284
The theory of Jordan-Thiry is investigated by using a five-dimensional Riemannian manifold V5 which admits a one-parameter group of isometries. The set of trajectories is supposed to represent the space-time of Relativity.The use of the induced metric in the quotient space leads to essential difficulties. It is necessary to consider a conformal metric and to modify the energy tensor in order to obtain the classical results of relativistic celestial mechanics. Moreover, the conformal metric brings out the evident interpretation of the fifteenth potential like a massless scalar field.A mass term referring to the scalar field is introduced; then the gravitational, electromagnetic, and mesonic scalar fields are unified through the metric of V5. Several results make the new theory very coherent; in particular, the exact relativistic equations of motion are obtained asymptotically when the matter density vanishes.Exact solutions are searched. The classical Schwarzschild solution and neighbouring solutions are valid in the interior of the matter. Special non-static solutions are also obtained; some of these may be interpreted locally as describing the “collapse” of neutron stars; others ones, analogous to Robertson's metric, can be used to build a cosmology of the unified field. 相似文献
88.
Electroreflectance spectra at normal incidence of (100) and (110) faces of gold and copper monocrystals are given, in the spectral range from 0.22–0.7 μm. The fractional change in reflectance is different with (110) faces when light is polarized parallel to the [001] direction and parallel to the [] direction while no anisotropy is seen on (100) faces. This shows that electroreflectance is a powerful tool to investigate metal surfaces where the optical electrons are sensitive to the distribution of the surface atoms. 相似文献
89.
90.
Philippe Bertani Jsus Raya Pierre Reinheimer Rgis Gougeon Luc Delmotte Jrme Hirschinger 《Solid state nuclear magnetic resonance》1999,13(4):255-229
19F/29Si Hartmann–Hahn continuous wave cross-polarization (CP) has been applied under fast magic-angle spinning (MAS) to a powder sample of octadecasil. Strong oscillations occur during CP on a sideband matching condition between the isolated 29Si–19F spin pairs formed by the silicons in the D4R units and the fluoride anions. The magnitude of the dipolar coupling constant was deduced directly from the line-splitting between the intense singularities of the Pake-like patterns obtained by Fourier transformation of the oscillatory polarization transfer. The corresponding Si–F internuclear distance, r=2.62±0.05 Å, is found to be in very good agreement with the X-ray crystal structure and the value of 2.69±0.04 Å recently reported from rotational echo double resonance (REDOR) and transferred echo double resonance (TEDOR) nuclear magnetic resonance (NMR) experiments. Furthermore, the CP technique is still reliable under fast MAS where both REDOR and TEDOR sequences suffer from severe artefacts due to finite pulse lengths. In octadecasil, a spinning frequency of 14 kHz is shown to be necessary for an effective suppression of 19F–19F spin diffusion. The influences of experimental missettings and radiofrequency (RF) field inhomogeneity are taken into account. 相似文献