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排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
A 2D HgII coordination polymer containing ligands 1,2,4‐triazole (Htrz) and thiocyanate, [Hg(μ3‐trz)(SCN)]n ( 1 ) has been synthesized and characterized by elemental analysis and IR spectroscopy. The single‐crystal X‐ray data show the coordination number of Hg atoms is four and the ligand trz? acts as a three‐fold donor. The thermal stability of compound 1 was studied by thermal gravimetric and differential thermal analyses. The composition and formation of the complex in methanol solution were found to be in support of its solid state structure. 相似文献
992.
A tomographic reconstruction method based on Monte Carlo random searching guided by the information contained in the projections
of radiographed objects is presented. In order to solve the optimization problem, a multiscale algorithm is proposed to reduce
computation. The reconstruction is performed in a coarse-to-fine multigrid scale that initializes each resolution level with
the reconstruction of the previous coarser level, which substantially improves the performance. The method was applied to
a real case reconstructing the internal structure of a small metallic object with internal components, showing excellent results. 相似文献
993.
The influence of the well width fluctuations on the dependence of the binding energy of excitonic complexes in quantum wells is studied by using the path-integral Monte-Carlo technique. The results are compared with available experimental data and a good agreement is found.Postdoctoral researcher of FWO-Vlaanderen 相似文献
994.
Th. Münzel A. Wynter Blyth Kützing Ch. Girard 《Analytical and bioanalytical chemistry》1882,21(1):436-438
995.
A. Lehmann 《Analytical and bioanalytical chemistry》1882,21(1):414-415
996.
Electron spin resonance (ESR) study was done on calcite encrustation on Fili neotectonic fault surface, Greece. Normally such
calcite encrustations on fault surfaces are not observed. Significantly, the ESR study has detected the presence of nitrate
NO32− radical in this calcite encrustation, havingg
⊥=2.0063±0.0001 and hyperfine coupling constantA
⊥=3.44 mT, the second such detection of nitrate NO32− radical following a sample from Scott Glacier, Antarctica. From isochronal thermal annealing measurement the NO32− radical was found to be quite stable, only fully annealed at 475°C. This study also shows that the ESR, as a tool, can be
suitably applied to date the age of formation of the calcite encrustation with SO3− as an ESR dating signal by additive γ-ray irradiation. A preliminary estimation indicates the age of formation of calcite
precipitation at Fili fault, Greece to be about 5600 years. 相似文献
997.
E. Rodriguez E. Jimenez G.J. Jacob A.A.R. Neves C.L. Cesar L.C. Barbosa 《Physica E: Low-dimensional Systems and Nanostructures》2005,26(1-4):361
Multilayer PbTe quantum dots (QDs) and SiO2 were grown by pulsed laser deposition (PLD) and Plasma enhanced chemical vapor deposition (PECVD) techniques. The crystalline structure, QD size and size dispersion were observed by high-resolution transmission electron microscopy (HRTEM) measurements. This technique allows one to grow PbTe QDs as small as 1.8 nm diameter and 0.6 nm size dispersion. The whole structure can be used in a Fabry–Perot cavity for an optical device operating at the mid-infrared region. 相似文献
998.
A switching of the S-type in the 20–200 μm thick polycrystalline n-CdTe:In layers with resistance of 103–106 Ω·cm is studied. The electric instability in the layers is found to be due to the electron-thermal breakdown mechanism. The
dependence of the switching threshold parameters on the intensity of exposure can be used for fabrication of infrared-radiation
controlled electric switches on the basis of n-CdTe:In layers.
__________
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 28–30, June, 2005. 相似文献
999.
S. V. Semikolenov K. A. Dubkov E. V. Starokon' D. E. Babushkin G. I. Panov 《Russian Chemical Bulletin》2005,54(4):948-956
The kinetics and mechanism of noncatalytic liquid-phase oxidation of but-1-ene and but-2-ene with nitrous oxide in a benzene
solution in the temperature range from 180 to 240°C were studied. Oxidation proceeds via the 1,3-dipolar cycloaddition mechanism to form carbonyl compounds. Both of these reactions occur with close rates and activation
energies and have the first orders with respect to the alkene and N2O. A considerable fraction (39%) of but-1-ene involved in oxidation undergoes cleavage at the double bond yielding propanal
and an equivalent amount of methylene, the latter producing ethylcyclopropane and cycloheptatriene. The oxidation of but-2-ene
proceeds with a minimum bond cleavage and affords methyl ethyl ketone with 84% selectivity. Regularities of the oxidation
of terminal and internal alkenes C2—C8 with nitrous oxide were analyzed using the previously published data.
__________
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 925–933, April, 2005. 相似文献
1000.