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181.
Dr. Eva‐Maria Rummel Prof. Dr. Piero Mastrorilli Dr. Stefano Todisco Prof. Mario Latronico Dr. Gábor Balázs Dr. Alexander V. Virovets Prof. Dr. Manfred Scheer 《Angewandte Chemie (International ed. in English)》2016,55(42):13301-13305
By employing silver salts with a weakly coordinating anion Ag[A] ([A]=[FAl{OC12F15}3], [Al{OC(CF3)3}4]), two phosphaalkynes could be coordinated side‐on to a bare silver(I) center to form the unprecedented homoleptic complexes [Ag(η2‐P≡CtBu)2][FAl{OC12F15}3] ( 1 ) and [Ag(η2‐P≡CtBu)2][Al{OC(CF3)3}4] ( 2 ). DFT calculations show that the perpendicular arrangement in 1 is the minimum energy structure of the coordination of the two phosphaalkynes to a silver atom, whereas for 2 a unique square‐planar coordination mode of the phosphaalkynes at Ag+ was found. Reactions with donor molecules yield the trigonally planar coordinated silver salts [((CH3)2CO)Ag(η2‐P≡CtBu)2][FAl{OC12F15}3] ( 3 ) and [(C7H8)2Ag(η2‐P≡CtBu)][FAl{OC12F15}3] ( 4 ). All of the compounds were comprehensively characterized in solution and in the solid state. 相似文献
182.
Mariachiara Pastore Celestino Angeli Renzo Cimiraglia 《Theoretical chemistry accounts》2007,118(1):35-46
The vertical electronic spectrum of the thiophene molecule is investigated by means of second and third order multireference
perturbation theory (NEVPT). Single-state and quasi-degenerate NEVPT calculations of more than 25 singlet excited states have
been performed. The study is addressed to the theoretical characterization of the four lowest-energy valence states, as well as the 3s, 3p and 3d Rydberg states. In addition, the excitation energies of two and valence states are also reported. For almost all the excited states, coupled cluster calculations (CCSD and CCSDR(3)) have
been also carried out, using the same geometry and basis set used for the NEVPT ones, in order to make the comparison between
the results of the two methods meaningful. A remarkable accordance between the NEVPT and CC excitation energies is found.
The present results, over all, confirm the experimental assignments but, above all, represent an important contribution to
the assignments of some low-energy states, valence and Rydberg, for which a firm interpretation is not available in the literature. 相似文献
183.
Regli L Bordiga S Busco C Prestipino C Ugliengo P Zecchina A Lamberti C 《Journal of the American Chemical Society》2007,129(40):12131-12140
Insertion of B atoms into an Al-free zeolitic framework with CHA topology results in the formation of B-SSZ-13 zeotype with Si/B = 11. B K-edge NEXAFS testifies that B forms [B(OSi)4] units in a Td-like geometry (sp3-hybridized B atoms). According to B K-edge NEXAFS and IR, template burning results in the formation of [B(OSi)3] units in a D3h-like geometry (sp2-hybridized B atoms) with a break of a B-O-Si bond and the formation of a Si-OH group. The activated material contains B(III) Lewis acid centers able to specifically coordinate bases like NH3. Such [B(OSi)3] units are reactive toward ammonia, resulting in the formation of B-NH2 surface functionality inside the pores of B-SSZ-13 already under mild conditions, i.e., 35 mbar of NH3 at 373 K for 30 min and without crystallinity degradation. A minor fraction of Si-NH2 cannot be excluded owing to the presence of two IR doublets at 3500 and 3430 cm-1 and at 1600 and 1550 cm-1. Ab initio B3LYP/6-31+G(d,p) calculations on a cluster model, supported by a single-point MP2 on B3LYP/6-31+G(D,P) optimized structures, found the break by NH3 of a B-O-Si bond of the [B(OSi)3] unit with formation of [SiOH] and [H2N-B(OSi)2] species to be energetically favored. Comparison between experimental and computed frequency shifts shows them to be in semiquantitative agreement. The high stability of the B-NH2 surface functionality is probed by N K-edge NEXAFS spectra collected under UHV conditions. These findings can open a new route in the preparation of shape selective solid basic catalysts. 相似文献
184.
Cariati E Macchi R Roberto D Ugo R Galli S Casati N Macchi P Sironi A Bogani L Caneschi A Gatteschi D 《Journal of the American Chemical Society》2007,129(30):9410-9420
Mixed M(II)/M(III) metal oxalates, as "stripes" connected through strong hydrogen bonding by para-dimethylaminobenzaldeide (DAMBA) and water, form an organic-inorganic 2D network that enables segregation in layers of the cationic organic NLO-phore trans-4-(4-dimethylaminostyryl)-1-methylpyridinium, [DAMS+]. The crystalline hybrid materials obtained have the general formula [DAMS]4[M2M'(C2O4)6].2DAMBA.2H2O (M = Rh, Fe, Cr; M' = Mn, Zn), and their overall three-dimensional packing is non-centrosymmetric and polar, therefore suitable for second harmonic generation (SHG). All the compounds investigated are characterized by an exceptional SHG activity, due both to the large molecular quadratic hyperpolarizability of [DAMS+] and to the efficiency of the crystalline network which organizes [DAMS+] into head-to-tail arranged J-type aggregates. The tunability of the pairs of metal ions allows exploiting also the magnetic functionality of the materials. Examples containing antiferro-, ferro-, and ferri-magnetic interactions (mediated by oxalato bridges) are obtained by coupling proper M(III) ions (Fe, Cr, Rh) with M(II) (Mn, Zn). This shed light on the role of weak next-nearest-neighbor interactions and main nearest-neighbor couplings along "stripes" of mixed M(II)/M(III) metal oxalates of the organic-inorganic 2D network, thus suggesting that these hybrid materials may display isotropic 1D magnetic properties along the mixed M(II)/M(III) metal oxalates "stripes". 相似文献
185.
We introduce a simple spherical model whose structural properties are similar to the ones generated by models with directional interactions, by employing a binary mixture of large and small hard spheres, with a square-well attraction acting only between particles of different sizes. The small particles provide the bonds between the large ones. With a proper choice of the interaction parameters, as well as of the relative concentration of the two species, it is possible to control the effective valence. Here we focus on a specific choice of the parameters which favors tetrahedral ordering and study the equilibrium static properties of the system in a large window of densities and temperatures. Upon lowering the temperature we observe a progressive increase in local order, accompanied by the formation of a four-coordinated network of bonds. Three different density regions are observed: At low density the system phase separates into a gas and a liquid phase; at intermediate densities a network of fully bonded particles develops; at high densities--due to the competition between excluded volume and attractive interactions--the system forms a defective network. The very same behavior has been previously observed in numerical studies of nonspherical models for molecular liquids, such as water, and in models of patchy colloidal particles. Different from these models, theoretical treatments devised for spherical potentials, e.g., integral equations and ideal mode coupling theory for the glass transition, can be applied in the present case, opening the way for a deeper understanding of the thermodynamic and dynamic behavior of low valence molecules and particles. 相似文献
186.
In this paper we provide a full classification of the non-negative solutions types for a class or two-dimensional bilinear cooperative aud predator-prey systems in terms of two bifurcation parameters. 相似文献
187.
Gianluca Ciardelli Alfonsina Rechichi Piero Cerrai Mario Tricoli Niccoletta Barbani Paolo Giusti 《Macromolecular Symposia》2004,218(1):261-272
Degradable segmented poly(ether-ester-urethanes) of variable segment chemistry and content were synthesized and characterized. Polycaprolactone diol, a series of poly(ether-ester) block copolymers, and a diisocyanate giving non toxic degradation products were used to form the prepolymer. Cyclohexane dimethanol and a L–phenylalanine–based diester (Phe diester) were used as chain extenders. The influence of α-chimotrypsin on the degradation was investigated by exposing the polymers to buffer and enzyme solutions for 12 days. The SEM, SEC, and gravimetric results showed that a significant erosion of the Phe diester containing polymer compared with the control polyurethane occurred in the presence of the enzyme but not in a normal buffer solution. 相似文献
188.
We prove a global existence result for a semilinear degenerate hyperbolic Cauchyproblem with large data, in the case ofa subcritical defocusing power nonlinearity, in 1 and 2 space dimensions. 相似文献
189.
Ilse Manet Luca Francini Stefano Masiero Silvia Pieraccini GianPiero Spada Giovanni Gottarelli 《Helvetica chimica acta》2001,84(7):2096-2107
The self‐assembly of guanosine (G) derivatives in the presence of alkali‐metal ions gives octameric or polymeric aggregates composed of stacked G quartets. This process is studied for some lipophilic G derivatives by means of ESI‐MS. The ESI‐MS results are discussed in the light of complementary information obtained from NMR and SANS (small‐angle neutron scattering) studies. ESI‐MS gives an excellent picture of the self‐assembly process and gives new information on the effect of different cations and anions on the dimensions of the assembled species, information that could not have been obtained with SANS and NMR alone. 相似文献
190.