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71.
The combined relaxation and vanishing Debye length limit for the hydrodynamic model for semiconductors is considered in both the unipolar and the bipolar case. The resulting limit problems are non‐linear drift driven hyperbolic equations. We make use of non‐standard entropy functions and the related entropy productions in order to obtain uniform estimates. In the bipolar case additional time‐dependent L∞‐type estimates, available from the existence theory, are needed in order to control the entropy production terms. Finally, strong convergence of the electric field allows the limit towards the limiting problem. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
72.
A new reversible, redox active diiminopyridine ligand (1Fc) containing pendant ferrocene functionalities was isolated and fully characterized. The reaction of 1Fc with chalcogen pseudohalides of sulfur, selenium, and tellurium yielded the respective N,N',N″-chelated chalcogen dications. Phosphorus chemistry proceeded in a related manner but, in this case, by the direct addition of 1Fc with PI(3) to yield the N,N',N″-chelated P(I) cation. These species represent the first synthesized main group complexes involving a redox active diiminopyridine ligand containing pendant ferrocenes. Electrochemical studies of the free ligand shows a reversible two-electron process. The chelated phosphorus cation, however, displayed three events, the first being a quasi-reversible two-electron process, involving the oxidation at the P(I) center, resulting in a P(III) cation. The subsequent reversible one- and two-electron processes arise from the ligand framework and pendant ferrocenes, respectively. 相似文献
73.
74.
Bergamini G Ceroni P Fabbrizi P Cicchi S 《Chemical communications (Cambridge, England)》2011,47(48):12780-12782
A dendrimer with a [Ru(bpy)(3)](2+) (bpy = 2,2'-bipyridine) complex as a core and four diphenylanthracene units at the periphery was prepared from a scaffold based on a bipyridyl ligand bearing four terminal alkyne groups. Upon green light excitation, the dendrimer shows blue luminescence even in a rigid matrix at 77 K thanks to the dendritic multichromophoric structure. 相似文献
75.
Pierangelo Fabbrizzi Francesca Bianchini Gloria Menchi Silvia Raspanti Antonio Guarna Andrea Trabocchi 《Tetrahedron》2014
Fragment-based drug discovery is a valuable tool in hit identification, as well as the combination of different small fragments showing a minimal binding activity against biological receptors or enzymes to give merged hits. A high number of fragments on the same scaffold improve the probability to find a candidate showing single- or multi-target affinities. A rapid and versatile approach for synthesizing libraries of densely fragment-functionalized scaffolds is reported. Many fragments were assembled in few steps around a triazole ring starting from amino alcohols and other readily available building blocks. A binding assay against integrin αvβ3 was used as a test-bed in order to demonstrate the potential of such an approach in hit discovery strategies. 相似文献
76.
Simone Capaccioli Daniele Prevosto Mauro Lucchesi Masoud Amirkhani Pierangelo Rolla 《Journal of Non》2009,355(10-12):753-758
The structural relaxation dynamics of two molecular glass-forming systems have been analyzed by means of dielectric spectroscopy, under cooling and compression conditions. The relation of the dynamic slowing down with the reduction of the configurational entropy, SC, as predicted by Adam and Gibbs (AG), was also investigated. As SC is not directly accessible by experiments, it was estimated, following a common procedure in literature, from the excess entropy Sexc of the supercooled liquid with respect to the crystal, determined from calorimetric and expansivity measurements over the same T–P range of dynamics investigation. The AG relation, predicting linear dependence between the logarithmic of structural relaxation time and the reciprocal of the product of temperature with configurational entropy, was successfully tested. Actually, a bilinear relation between Sexc and SC was found, with different proportionality factors in isothermal and isobaric conditions. Using such results, we derived an equation for predicting the pressure dependence of the glass transition temperature, in good accordance with the experimental values in literature. 相似文献
77.
78.
Halogen bonding is discussed as an interaction that is capable of overcoming the reluctance shown by fluorinated compounds towards interactions with hydrocarbons. This non-covalent interaction is sufficiently strong to enact formation of supramolecular architectures where perfluorocarbons, hydrocarbons, and inorganic salts are self-assembled. Examples are discussed which exemplify the consistency and versatility of this interaction in affording numerous and structurally different hybrid materials. The importance of fluorine in determining the overall packing of the formed architectures is also highlighted. 相似文献
79.
Carmine Coluccini Pierangelo Metrangolo Marco Parachini Dario Pasini Giuseppe Resnati Pierpaolo Righetti 《Journal of polymer science. Part A, Polymer chemistry》2008,46(15):5202-5213
Well‐defined macromolecules have been obtained through free‐radical cyclopolymerization and cyclocopolymerization of difunctional and acrylic‐like monomers, which contained “push‐pull” supramolecular chromophores, able to form 1:1 complexes with Eu3+ ions in solution. The monomeric molecular modules are built around bismalonate crown ethers in a convergent fashion, in which one of the malonate moiety is derivatized as the ylidene malonate push‐pull fragment, and the other malonate moiety is elaborated to introduce two polymerizable and acrylic‐like substituents. The free‐radical induced cyclopolymerization of these monomers, or their cyclocopolymerization with UV/Vis “silent” but structurally related monomers, afforded macromolecular architectures characterized by GPC, NMR and DSC techniques. UV/Vis titration studies, performed with Eu(OTf)3 as the supramolecular probe, revealed how adjacent chromophores within the polymeric backbone are virtually independent from each other, and how the binding ability towards the probe of these multivalent, highly packed cyclopolymeric architectures, although reduced, is still clearly detectable. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 5202–5213, 2008 相似文献
80.
Feimin?Huang Pierangelo?Marcati Ronghua?PanEmail author 《Archive for Rational Mechanics and Analysis》2005,176(1):1-24
We study the asymptotic behavior of a compressible isentropic flow through a porous medium when the initial mass is finite. The model system is the compressible Euler equation with frictional damping. As t, the density is conjectured to obey the well-known porous medium equation and the momentum is expected to be formulated by Darcys law. In this paper, we give a definite answer to this conjecture without any assumption on smallness or regularity for the initial data. We prove that any L weak entropy solution to the Cauchy problem of damped Euler equations with finite initial mass converges, strongly in Lp with decay rates, to matching Barenblatts profile of the porous medium equation. The density function tends to the Barenblatts solution of the porous medium equation while the momentum is described by Darcys law.This revised version was published in April 2005. The volume number has now been inserted into the citation line. 相似文献