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ABSTRACTIn this work, some ‘equivalent’ models for the simulation of efficiency response of a High-Purity Germanium (HPGe) detector, installed inside a ‘low background’ bunker in the Engineering Department of the University of Palermo, were developed. The main feature was to attribute the uncertainties of the model to only one of the parameters, the dead layer of the detector, keeping unchanged the other data provided by the manufacturer. With this technique, using the Monte Carlo PENELOPE code in the 2011 version, the efficiency response was evaluated and compared with the previous one performed with MCNP5 code.The validation of equivalent models is performed by comparing the simulation results with that of experimental spectrometric measurements of calibrated point sources and characterized volumetric sources such as a Marinelli beaker and an air filter reduced to a ‘packet-sample’.The use of equivalent models makes the evaluation of efficiency curves with a Monte Carlo code easier and faster, and requires only a few experimental values for validation. 相似文献
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The term halogen bonding describes the tendency of halogen atoms to interact with lone pair possessing atoms. The binding features and structural properties of halogen bonding are discussed and applied to drive the intermolecular self-assembly of hydrocarbons and perfluorocarbons in chemo-, site-, and enantioselective supramolecular synthesis. The halogen bonding is thus an effective and reliable tool in crystal engineering at the disposal of the supramolecular chemist. 相似文献
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Dr. Daniele Maiolo Dr. Andrea Pizzi Dr. Alessandro Gori Dr. Lara Gazzera Dr. Nicola Demitri Dr. Alessandro Genoni Dr. Fulvio Baggi Dr. Fabio Moda Prof. Dr. Giancarlo Terraneo Prof. Dr. Francesca Baldelli Bombelli Prof. Dr. Pierangelo Metrangolo Prof. Dr. Giuseppe Resnati 《ChemistryOpen》2020,9(2):253-260
Here, we demonstrate that introduction of halogen atoms at the tyrosine 10 phenol ring of the DSGYEV sequence derived from the flexible amyloid-β N-terminus, promotes its self-assembly in the solid state. In particular, we report the crystal structures of two halogen-modified sequences, which we found to be stabilized in the solid state by halogen-mediated interactions. The structural study is corroborated by Non-Covalent Interaction (NCI) analysis. Our results prove that selective halogenation of an amino acid enhances the supramolecular organization of otherwise unstructured biologically-relevant sequences. This method may develop as a general strategy for stabilizing highly polymorphic peptide regions. 相似文献
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Pierangelo Marcati Manuela Molinari 《NoDEA : Nonlinear Differential Equations and Applications》2009,6(2):119-132
In this paper we first prove short time existence of a classical solution for the problem which describes the evolution by
Gaussian curvature of a strictly convex hypersurface in . Then we give a proof of the existence of a viscosity solution for this problem in such a way as to define a generalized
motion existing for each time.
Received November 24, 1997 相似文献
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Liantonio R Metrangolo P Meyer F Pilati T Navarrini W Resnati G 《Chemical communications (Cambridge, England)》2006,(17):1819-1821
Two homologues of supramolecular Borromean rings were obtained based on the halogen-bonding-driven self-assembly of iodide ions with telechelic diiodoperfluoroalkanes. 相似文献