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The piston problem is investigated in the case where the length of the cylinder is infinite (on both sides) and the ratio m/M is a very small parameter, where m is the mass of one particle of the gaz and M is the mass of the piston. Introducing initial conditions such that the stochastic motion of the piston remains in the average at the origin (no drift), it is shown that the time evolution of the fluids, analytically derived from Liouville equation in a previous work, agrees with the Second Law of thermodynamics. We thus have a non equilibrium microscopical model whose evolution can be explicitly shown to obey the two laws of thermodynamics. 相似文献
24.
Christian J. Bordé Claus Lämmerzahl Ernst M. Rasel 《General Relativity and Gravitation》2004,36(10):2193-2196
25.
Stefan Pitsch Sebastian Wendeborn Ramanarayanan Krishnamurthy Armin Holzner Mark Minton Martin Bolli Christian Miculca Norbert Windhab Ronald Micura Michael Stanek Bernhard Jaun Albert Eschenmoser 《Helvetica chimica acta》2003,86(12):4270-4363
Pyranosyl‐RNA (‘p‐RNA’ ) is an oligonucleotide system isomeric to natural RNA and composed of the very same building blocks as RNA. Its generational, chemical, and informational properties are deemed to be those of an alternative nucleic acid system that could have been a candidate in Nature's evolutionary choice of the molecular basis of genetic function. We consider the study of the chemistry of p‐RNA as etiologically relevant in the sense that knowledge of its structural, chemical, and informational properties on the chemical level offers both a perspective and reference points for the recognition of specific structural assets of the RNA structure that made it the (supposedly) superior system among possible alternatives and, therefore, the system that became part of biology as we know it today. The paper describes the chemical synthesis of β‐d‐ (and L )‐ribopyranosyl‐(4′→2′)‐oligonucleotide sequences, presents a resume of their structural and chemical properties, and cautiously discusses what we may and may not have learned from the pyranosyl isomer of RNA with respect to the conundrum of RNA's origin. 相似文献
26.
In the framework of ARMA models, we consider testing the reliability of the standard asymptotic covariance matrix (ACM) of the least-squares estimator. The standard formula for this ACM is derived under the assumption that the errors are independent and identically distributed, and is in general invalid when the errors are only uncorrelated. The test statistic is based on the difference between a conventional estimator of the ACM of the least-squares estimator of the ARMA coefficients and its robust HAC-type version. The asymptotic distribution of the HAC estimator is established under the null hypothesis of independence, and under a large class of alternatives. The asymptotic distribution of the proposed statistic is shown to be a standard χ2 under the null, and a noncentral χ2 under the alternatives. The choice of the HAC estimator is discussed through asymptotic power comparisons. The finite sample properties of the test are analyzed via Monte Carlo simulation. 相似文献
27.
Christian Richter 《Elemente der Mathematik》1998,53(4):149-158
28.
Christian Steglich 《Results in Mathematics》1995,27(1-2):188-193
While in Euclidean, equiaffine or centroaffine differential geometry there exists a unique, distinguished normalization of a regular hypersurface immersion x: M n → An+1, in the geometry of the general affine transformation group, there only exists a distinguished class of such normalizations, the class of relative normalizations. Thus, the appropriate invariants for speaking about affine hypersurfaces are invariants of the induced classes, e.g. the conformai class of induced metrics and the projective class of induced conormal connections. The aim of this paper is to study such invariants. As an application, we reformulate the fundamental theorem of affine differential geometry. 相似文献
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30.
Christian Bär 《Communications in Mathematical Physics》1997,188(3):709-721
We prove that the nodal set (zero set) of a solution of a generalized Dirac equation on a Riemannian manifold has codimension
2 at least. If the underlying manifold is a surface, then the nodal set is discrete. We obtain a quick proof of the fact that
the nodal set of an eigenfunction for the Laplace-Beltrami operator on a Riemannian manifold consists of a smooth hypersurface
and a singular set of lower dimension. We also see that the nodal set of a Δ-harmonic differential form on a closed manifold
has codimension 2 at least; a fact which is not true if the manifold is not closed. Examples show that all bounds are optimal.
Received: 28 October 1996 / Accepted: 3 March 1997 相似文献