“(Diphosphine)Nickel”‐Catalyzed Negishi Cross‐Coupling: An Experimental and Theoretical Study

The use of a strongly donating “(bis‐dialkylphosphine)Ni” fragment promotes the catalytic coupling of a large range of ArCl and ArZnCl derivatives under mild conditions. Stoichiometric mechanistic investigations and DFT calculations prove that a Ni⁰/Ni^II cycle is operative in this system.     

Dissipative periodic systems and symmetric interpolation in Schur classes

Matrix-valued functions analytic and contractive in the open unit disk (Schur functions) play an important role in system theory. They represent transfer functions of causal time-invariant dissipative systems. In this paper we show how a Schur function can still be associated to a k-periodic system. This function satisfies a certain symmetry condition (conditions (1.7) for k=2 and (4.4) for general k). We study a general bitangential interpolation problem for the Schur functions satisfying this symmetry condition.