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41.
The absorption and fluorescence spectra of carbaryl (CB), carbofuran (CF) and carbendazim (MBC) have been studied. Fluorescence lifetime and fluorescence quantum yields are also reported as well as the influence of pH, solvent and presence of humic acids on fluorescence. The limit of detection (LD) of the three compounds has been measured by direct analysis by laser-induced fluorescence (LIF) using a pulsed YAG laser with an Optical Parametric Oscillator (OPO) as excitation source and an Intensified Charged Coupled Device (ICCD) camera for the fluorescence detection. Instrumental LD found for CB, for MBC and for CF are respectively 4, 50 and 1000 ng L−1. In tap water, the LD obtained is 800 ng L−1 for MBC and 20,000 ng L−1 for CF. For CB, the use of a time shift between excitation and emission allows to reach a LD of 20 ng L−1 in tap water.  相似文献   
42.
The present work adapts a recent grating theory called “Fast Fourier factorization” to cylindrical coordinates in order to study microstructured optical fibers (MOFs). Compared with the classical differential method, this new differential method takes into account the truncation of Fourier series and the discontinuities of the fields across the diffracting surface with the help of new factorization rules. The main advantage of this method is that the directrix of the diffracting cylindrical surface is arbitrary and permits anisotropic and inhomogeneous media although its numerical application needs longer computation time, compared with other well-known numerical methods. The S-propagation algorithm is used to avoid numerical contaminations. The numerical results are validated and compared with the well-established Multipole method in the case of a MOF with six circular cylinders. Further, a new cross-sectional profile (with sectorial inclusions) that the Multipole method cannot consider is studied.  相似文献   
43.
The quantum probability flux of a particle integrated over time and a distant surface gives the probability for the particle crossing that surface at some time. We prove the free flux-across-surfaces theorem, which was conjectured by Combes, Newton and Shtokhamer (Phys. Rev. D. 11 (1975), 366), and which relates the integrated quantum flux to the usual quantum mechanical formula for the cross-section. The integrated quantum flux is equal to the probability of outward crossings of surfaces by Bohmian trajectories in the scattering regime.  相似文献   
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The concept of a twisted crossed product associated to a non-classical C*-dynamical system is introduced and studied. The relationship between a covariant projective representation of the system and the corresponding induced representation of the twisted crossed product is investigated, particularly from the point of view of determining when the induced representation is faithful. Conditions are given on the C*-dynamical system that ensure nuclearity, simplicity or primeness of the twisted crossed product.  相似文献   
49.
Consider anM/M/1 queueing system with server vacations where the server is turned off as soon as the queue gets empty. We assume that the vacation durations form a sequence of i.i.d. random variables with exponential distribution. At the end of a vacation period, the server may either be turned on if the queue is non empty or take another vacation. The following costs are incurred: a holding cost ofh per unit of time and per customer in the system and a fixed cost of each time the server is turned on. We show that there exists a threshold policy that minimizes the long-run average cost criterion. The approach we use was first proposed in Blanc et al. (1990) and enables us to determine explicitly the optimal threshold and the optimal long-run average cost in terms of the model parameters.  相似文献   
50.
The temperature dependence of ρxx is studied in the vicinity of the quantum Hall to quantum Hall insulator transition (ν=1→0) in InSb/InAlSb based 2DESs. ρxx displays a symmetric temperature dependence about the transition with on the QH side and on the insulating side. A plot of 1/T0 for successive ν displays power-law divergence with 1/T0∝|ν−νc|−γ,2 with γ=2.2±0.3. This critical behavior in addition to the behavior expected of the quantum transport regime confirms that the QH/QHI transition is indeed a good quantum phase transition.  相似文献   
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