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991.
Alan J. Crowe Peter J. Smith Philip G. Harrison 《Journal of organometallic chemistry》1980,204(3):327-331
A series of cationic tributyltin complexes with a tetraphenylborate counter anion, [Bu3SnL2]+BPh4,?, where L = DMSO, Ph3PO, Ph3,AsO, pyO or DMF, and L2 = diphosO2, has been prepared and their 119mSn Mössbauer spectra investigated. These indicate that the triorganotin cation occupies a pentacoordinate trigonal bipyramidal geometry with equatorial organic groups when L = monodentate donor, whilst the bidentate diphosO2 ligand produces a mer-R3SnX2 stereochemistry about tin. 相似文献
992.
Prof. Dr. Antoaneta D. Stefanova Philip I. Iotov Dimcho I. Dimitrov 《Monatshefte für Chemie / Chemical Monthly》1975,106(3):723-728
The liquid phase oxidation of 1.2.4.5-tetramethylbenzene catalysed by cobaltous acetate and promoted by KBr in acetic acid was kinetically studied. In view of deriving the kinetic equation for the absorption of oxygen, a number of experiments were carried out. The values of the activation energy and of the preexponentA=1014 were determined as well. The resulting kinetic equation: $$ - \frac{{d\left[ {O_2 } \right]}}{{d\tau }} = 10^{14} \cdot \exp \left( { - \frac{{84,460 \times 10^3 }}{{RT}}} \right) \cdot C_{C_6 H_2 (CH_3 )_4 }^{0,5} \cdot C_{Co(OAc)_2 }^{0,5} \cdot C_{KBr}^{0,5} $$ is in accordance with the theoretically derived expression of this type. 相似文献
993.
994.
A reasoning model, based on the logic of argumentation, is described. The model represents argumentation as a directed graph in which nodes and arcs can be colored using an ordinal set of weightings and in which the attributes of both nodes and arcs can be modified. It is thus able to deal with the undercutting or augmenting of arguments. Weightings can be propagated through the graph to generate unique weightings for any node or arc. The model is able to deal with contradiction. It can incorporate numerical methods and is able to handle qualitative and quantitative reasoning. 相似文献
995.
T. Hanumaiah G.S.R. Rao C.P. Rao K.V.J. Rao Heather J. Cowe Philip J. Cox R.Alan Howie David S. Marshall Ronald H. Thompson 《Tetrahedron》1985,41(3):635-642
From the root bark of Ventilago maderaspatana (Rhamnaceae) five isofuranonaphthoquinones have been isolated. Ventilone-A is 4,9-dihydro-5,8-dihydroxy-6,7-methylenedioxy-1-methylnaphtho[2,3-c] furan-4,9-dione and B is the 5-methyl ether. Ventilone-C has the structure 1,3,4,9-tetrahydro-8-hydroxy-5-methoxy-6, 7-methylenedioxy-1-methylnaphtho[2,3-c]furan-4,9-dione, D is the isomeric 8-methyl ether, and E is the 5,8-dimethyl ether. Structures were determined by spectroscopic methods, and X-ray crystallographic analysis of ventilone-C. 相似文献
996.
The electrochemical reduction of uracil in dimethyl sulfoxide was investigated, using d.c.and a.c. polarography, cyclic voltammetry, and controlled potential electrolysis. Uracil is reduced in a one-electron step (E1/2=?2.3 V); the apparent number of electrons transferred (n) decreases from one at infinite dilution to one-half at concentrations above 1mM. The concentration dependent n-value is due to proton transfer by the parent compound to the radical anion formed on reduction. Such a proton transfer, which has been observed for 2-hydroxypyrimidine, deactivates part of the uracil, which would otherwise be available for reduction, by formation of the more difficultly reducible conjugate base. The uracil anion forms insoluble mercury salts, producing two oxidation waves (E1/2 of ?0.1 and ?0.3 V); the latter wave is due to formation of a passivating film on the electrode. Digital simulations indicate that the protonation rate exceeds 105M?1 s?1 and that, at low uracil concentration, some of the free radical formed on protonation is further reduced. At concentrations exceeding 1 mM, all of the free radical dimerizes. The effect of added acids and base on the electrochemical behavior is described. 相似文献
997.
Lead can be determined by atomic absorption spectroscopy at 3 wavelengths. The relative sensitivities are 1:1.5:300. No interferences were found from the cations studied. Anionic interferences were numerous and extensive, but were removed by adding EDTA. The use of a “T” -piece increased the sensitivity of atomic absorption when flame atomizers were used. However, extreme care was necessary in controlling flame conditions both with respect to oxygen-fuel ratio and the type of solvent used. The absorption by combustion products in the flame was high, and in many cases, much greater than that of the lead itself.The most sensitive conditions for the determination of lead appeared to be as follows: wavelength, 2170 A; solvent, aqueous or organic; flame, oxy-hydrogen, with the hydrogen atomizing the sample (reversed from normal). Aflame adapter enabled detection limits of 0.013 p.p.m. to be reached. 相似文献
998.
The synthesis and structural characterization of the compounds MesAlCl(2)(THF) (1), MesAlCl(2) (2), MesAl(H)Cl(THF) (3a), MesAl(H)Cl (4a), and (MesAlH(2))(2) (5) (Mes = 2,4,6-t-Bu(3)C(6)H(2)(-)) are described as well as those for two compounds 3b and 4b that are analogs of 3a and 4a but have H:Cl ratios that are less than 1:1. All compounds were characterized by (1)H, (13)C NMR, and IR spectroscopy, and 1, 2, 3a, and 4b were additionally characterized by X-ray crystallography. Compound 1 is best synthesized by the reaction of [(THF)(2)LiH(3)AlMes](2) (6) with 6 equiv of Me(3)SiCl. A more conventional route involving the addition of (THF)(2)LiMes to 2 equiv of AlCl(3) in toluene usually affords a mixture of 1 and AlCl(3).THF. Recrystallization of 1 from n-hexane results in a species that has less than 1 equiv of THF per MesAlCl(2). The THF free complex 2 may be obtained in quantitative yield by heating 1 for 20 min at 90 degrees C under reduced pressure. Compound 3a may be obtained by treating a 1:1 mixture of MesLi(THF)(2) and LiAlH(4) with 2 equiv of Me(3)SiCl or by the addition of slightly less than 4 equiv of Me(3)SiCl to 6. The THF can be removed from 3a by sublimation to give 4a. The related compounds 3b and 4b, which display an aluminum-bound H:Cl ratio that is deficient in H, can be obtained by reactions with slightly more than 2 equiv of Me(3)SiCl. Crystal data at 130 K with Cu Kalpha (lambda = 1.541 78 ?) radiation: 1, C(22)H(37)AlCl(2)O, a = 11.889(3) ?, b = 9.992(3) ?, c = 19.704(5) ?, orthorhombic, space group Pca2(1), Z = 4, R = 0.068 for 1556 (I > 2sigma(I)) data; 2, C(18)H(29)AlCl(2), a = 12.147(5) ?, b = 18.042(6) ?, c = 17.771(7) ?, beta = 95.77(3) degrees, monoclinic, space group P2(1)/n,Z = 8, R = 0.032 for 4610 (I > 2sigma(I)) data; 3a, C(22)H(38)AlClO, a = 16.887(7) ?, b = 16.333(6) ?, c = 8.739(3) ?, beta = 101.41(3) degrees, monoclinic, space group P2(1)/c, Z = 4, R = 0.073 for 2752 (I > 2sigma(I)) data; 4b, C(18)H(29.64)AlCl(1.36), a = 12.077(3) ?, b = 17.920(3) ?, c = 17.634(5) ?; beta = 95.21(2) ?, monoclinic, space group P2(1)/n,Z = 8, R = 0.070 for 4261 (I > 2sigma(I)) data. 相似文献
999.
Conformational models covering an energy range of 3 kcal/mol were calculated for (13S)‐tetradecano‐13‐lactone ( 3 ), (12S)‐12‐methyltridecano‐13‐lactone ( 4 ), and (12S,13R)‐12‐methyltetradecano‐13‐lactone ( 8 ), starting from a semiempirical Monte‐Carlo search with AM1 parametrization, and subsequent optimization of the 100 best conformers at the 6‐31G*/B3LYP and then the TZVP/B3LYP level of density‐functional theory. CD Spectra for these models were calculated by the time‐dependent DFT method with the same functional and basis sets as for the ground‐state calculations and Boltzmann weighting of the individual conformers. The good correlation of the calculated and experimental spectra substantiates the interpretation of these conformational models for the structure–odor correlation of musks. Furthermore, the application of the quadrant rule in the estimation of the Cotton effect for macrolide conformers is critically discussed. 相似文献
1000.
Brands KM Payack JF Rosen JD Nelson TD Candelario A Huffman MA Zhao MM Li J Craig B Song ZJ Tschaen DM Hansen K Devine PN Pye PJ Rossen K Dormer PG Reamer RA Welch CJ Mathre DJ Tsou NN McNamara JM Reider PJ 《Journal of the American Chemical Society》2003,125(8):2129-2135
An efficient stereoselective synthesis of the orally active NK(1) receptor antagonist Aprepitant is described. A direct condensation of N-benzyl ethanolamine with glyoxylic acid yielded a 2-hydroxy-1,4-oxazin-3-one which was activated as the corresponding trifluoroacetate. A Lewis acid mediated coupling with enantiopure (R)-1-(3,5-bis(trifluoromethyl)phenyl)ethan-1-ol afforded a 1:1 mixture of acetal diastereomers which was converted into a single isomer via a novel crystallization-induced asymmetric transformation. The resulting 1,4-oxazin-3-one was converted via a unique and highly stereoselective one-pot process to the desired alpha-(fluorophenyl)morpholine derivative. Interesting and unexpected [1,2]-Wittig and [1,3]-sigmatropic rearrangements were identified during the optimization of these key steps. In the final step, a triazolinone side chain was appended to the morpholine core. The targeted clinical candidate was thus obtained in 55% overall yield over the longest linear sequence. 相似文献