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21.
Jien Wu Xiao-Fang Cheng Leslie J. Harrison Swee-Hock Goh Keng-Yeow Sim 《Tetrahedron letters》2004,45(52):9657-9659
Examination of the aerial parts of a Chinese herbal medicine yielded a novel metabolite, perforatumone 1, which is characterized by its unique carbon skeleton. Its structure was determined by detailed spectroscopic analysis. 相似文献
22.
23.
Leslie P Steffe 《The Journal of Mathematical Behavior》2003,22(3):237-295
A case study of two 5th-Grade children, Jason and Laura, is presented who participated in the teaching experiment, Children’s Construction of the Rational Numbers of Arithmetic. The case study begins on the 29th of November of their 5th-Grade in school and ends on the 5th of April of the same school year. Two basic problems were of interest in the case study. The first was to provide an analysis of the concepts and operations that are involved in the construction of three fractional schemes: a commensurate fractional scheme, a fractional composition scheme, and a fractional adding scheme. The second was to provide an analysis of the contribution of interactive mathematical activity in the construction of these schemes. The phrase, “commensurate factional scheme” refers to the concepts and operations that are involved in transforming a given fraction into another fraction that are both measures of an identical quantity. Likewise, “fractional composition scheme” refers to the concepts and operations that are involved in finding how much, say, 1/3 of 1/4 of a quantity is of the whole quantity, and “fractional adding scheme” refers to the concepts and operations involved in finding how much, say, 1/3 of a quantity joined to 1/4 of a quantity is of the whole quantity. Critical protocols were abstracted from the teaching episodes with the two children that illustrate what is meant by the schemes, changes in the children’s concepts and operations, and the interactive mathematical activity that was involved. The body of the case study consists of an on-going analysis of the children’s interactive mathematical activity and changes in that activity. The last section of the case study consists of an analysis of the constitutive aspects of the children’s constructive activity, including the role of social interaction and nonverbal interactions of the children with each other and with the computer software we used in teaching the children. 相似文献
24.
A new flow electrical conductance instrument was constructed and tested on dilute NaCl solutions up to 458 K, and on more
concentrated solutions (maximum 0.436 mol⋅kg−1) at 373 K. The results of the new instrument agreed with those of previous authors within the estimated experimental errors.
The model of Bernard et al. (J. Phys. Chem. 96, 3833–3840 (1992), MSA) was found to represent the high-temperature results without introducing an ion-pairing equilibrium constant. The Fuoss–Hsia
conductance equation as given by Fernandez-Prini was found to represent the dilute concentrations with Λ° (NaCl) as the only adjustable parameter. It was found that Λ° (NaCl) could be expressed as a function of solvent viscosity and density by using three parameters found by regression of
literature results between 278.15 and 523 K. This equation along with the FHFP theory permits the equivalent conductivity
of dilute sodium chloride solutions to be calculated within the accuracy of the existing experimental measurements. 相似文献
25.
The potential role of ultrasound in differentiating solid and cystic swellings of the true vocal fold 总被引:3,自引:0,他引:3
John S. Rubin Stuart Lee John McGuinness Ian Hore David Hill Leslie Berger 《Journal of voice》2004,18(2):231-235
This study was designed to investigate the potential role of ultrasound in the diagnosis of cysts of the true vocal fold. Materials and Methods: Grayscale ultrasound of the larynx was carried out in 29 patients with a swelling of the true vocal fold and dysphonia. The findings were then compared with those at subsequent microlaryngoscopy, in the majority of cases. Results and Conclusions: Whereas preoperative laryngeal ultrasound correctly predicted the surgical findings of a cystic lesion in only 5 of 11 cases, it correctly identified that no cyst was present in 15 of 16 instances when this had been queried. This study suggests that ultrasound may have some role in investigation of unilateral vocal fold pathology, but that further fine-tuning of the technique may be necessary. 相似文献
26.
After describing simplified equations exspressing the temparature dependency of the viscosity of carrier gases (helium, nitrogen and hydrogen ) relative to a base value, absolute relationships based on the kinetic theory of gases are discussed. Comparative data obtained using various calculation methods are given and are compared to measured values. Based on the kinetic relationshipsm, of viscosity. Finally, the influence of pressure on the viscosity is also briefly discussed. As a supplement, Viscosity data are tabulated for the three gases in the range of 0°C to 400°C in increments of 2 K, calculated using the kinetic relationships. 相似文献
27.
Ying‐Hung So Pamela Foster Jang‐Hi Im Philip Garrou Jack Hetzner Edmund Stark Kayla Baranek 《Journal of polymer science. Part A, Polymer chemistry》2006,44(5):1591-1599
Divinylsiloxane‐bisbenzocyclobutene (DVS‐bisBCB) polymer has very low dielectric constant and dissipation factor, good thermal stability, and high chemical resistance. The fracture toughness of the thermoset polymer is moderate due to its high crosslink density. A thermoplastic elastomer, polystyrene–polybutadiene–polystyrene triblock copolymer, was incorporated into the matrix to enhance its toughness. The cured thermoset matrix showed different morphology when the elastomer was added to the B‐staged prepolymer or when the elastomer was B‐staged with the DVS‐bisBCB monomer. Small and uniformly distributed elastomer domains were detected by transmission electron micrographs (TEM) in the former case, but TEM did not detect a separate domain in the latter case. A high percentage of the polystyrene–polybutadiene–polystyrene triblock copolymer could be incorporated into the DVS‐bisBCB thermoset matrix by B‐staging the triblock copolymer with the BCB monomer. The elastomer increased the fracture toughness of DVS‐bisBCB polymer as indicated by enhanced elongation at break and increased K1c values obtained by the modified edge‐lift‐off test. Elastomer modified DVS‐bisBCB maintained excellent electrical properties, high Tg and good thermal stability, but showed higher coefficient of linear thermal expansion values. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1591–1599, 2006 相似文献
28.
Philip E. Gibbs 《International Journal of Theoretical Physics》1996,35(6):1037-1062
To accommodate topology change, the symmetry of space-time must be extended from the diffeomorphism group of a manifold to the symmetric group acting on the discrete set of space-time events. This is the principle ofevent-symmetric space-time. I investigate a number of physical toy models with this symmetry to gain some insight into the likely nature of event-symmetric space-time. In the more advanced models the symmetric group is embedded into larger structures such as matrix groups which provide scope to unify space-time symmetry with the internal gauge symmetries of particle physics. I also suggest that the symmetric group of space-time could be related to the symmetric group acting to exchange identical particles, implying a unification of space-time and matter. I end with a definition of a new type of loop symmetry which is important in event-symmetric superstring theory. 相似文献
29.
Summary Bhattacharya, Chernoff and Yang (1983) proposed a nonparametric estimate for the slope of a regression lineY =
o
X + V subjected to the truncationYy
0. The estimate corresponds to the zero-crossing of a random functionS
n
(). In this paper an estimate for the asymptotic variance of the estimate of the slope is proposed and the rate of convergence is given. The proofs rest heavily on the local behavior ofS
n
() in the neighborhood of the true value o. 相似文献
30.
以硅溶胶和氧氯化锆为硅源和锆源,采用水热合成的方法制得具有ZSM-5结构的Zr-Si分子筛;用0.5mol/L的硫酸处理该分子筛,并在550℃焙烧,制得具有ZSM-5结构的SO4^2-/ZrO2-SiO2分子筛型的固体超强酸。采用XRD、SEM、TG、IR、NH3-PHD和指示剂法对其结构和酸性进行表征。结果表明,该SO4^2-/ZrO2-SiO2具有ZSM-5结构和超强酸性,其酸强度大于-13.75,且具有良好的热稳定性。 相似文献