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51.
Pham Huu Ly 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(12):1931-1937
Abstract This paper deals with the grafting of acyl chloride capped liquid natural rubber (LNR–COCl) onto carbon black by the reaction of the acyl chloride group with the phenolic hydroxyl group on the surface. LNR–COCl was prepared by the reaction of hydroxyl-terminated liquid natural rubber (HTNR) with adipoyl dichloride. The percentage of grafting was estimated to be 18–21% depending on the grafting temperature and the molecular weight of HTNR used. It increased with an increase in the molecular weight of LNR–COCl. The LNR grafted onto carbon black was investigated by IR spectroscopy and by hydrolysis with a dilute THF solution of KOH. It was shown that LNR grafted onto the carbon black surface with ester bonds. 相似文献
52.
53.
Hai Pham Tuan Hans-Gerd Janssen Ellen M. Kuiper-van Loo Harm Vlap 《Journal of separation science》1995,18(9):525-534
Determination of trace concentrations of sulfur components in natural gas is a true analytical challenge. Only analytical procedures based on gas chromatography can meet the sensitivity and accuracy requirements dictated by environmental regulation institutions and modern chemical industry. In the present contribution the sample pretreatment and chromatographic separation steps have been evaluated and optimized based on the use of a flamebased sulfur chemiluminescence detector (SCD) for target compound detection. The proposed instrument consists of a programmed temperature vaporizing (PTV) injector employing a liner packed with Chromosorb 104, a 4 μm thick film apolar column and a flame-based SCD. Using a 13 mL sample loop the detection limit achievable with the new method is 3 μg S/m3. The precision of replicate measure. ments is generally in the range of 5–15% relative standard deviation. Lower detection limits can be achieved by preconcentrating larger sample volumes, e.g. 100 mL. 相似文献
54.
Binh Khanh Mai Prof. Yongho Kim 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(11):3568-3572
55.
Geometric and electronic structures, vibrational properties, and relative stabilities of niobium clusters Nb(n), n = 7-12, are studied using both DFT (BPW91 and M06 functionals) and CCSD(T) calculations with the cc-pVnZ-PP basis set. In each cluster, various lower-lying states are very close in energy in such a way that the ground state cannot be unambiguously established by DFT computations. Nb clusters tend to prefer the lowest possible spin state as the ground state, except for Nb(12) ((3)A(g)). The optimal structure of the cluster at a certain size does not simply grow from that of the smaller one by adding an atom randomly. Instead, the Nb clusters prefer a close-packed growth behavior. Nb(10) has a spherically aromatic character, high chemical hardness and large HOMO-LUMO gap. Electron affinities, ionization energies, binding energy per atom, and the stepwise dissociation energies are evaluated. Energetic properties exhibit odd-even oscillations. Comparison with experimental values shows that both BPW91 and M06 functionals are reliable in predicting the EA and IE values, but the BPW91 is deficient in predicting the binding and dissociation energies. We re-examine in particular the experimental far IR spectra previously recorded using the IR-MPD and free electron laser spectrometric techniques and propose novel assignments for Nb(7) and Nb(9) systems. The IR spectra of the anions are also predicted. 相似文献
56.
In the copolymerization of vinyl acetate (A) with either vinyl chloride (C) or vinylidene chloride (V), an internal transfer (backbiting) reaction—of the C- or V-ended radi-cals on an antepenultimate A unit—is proposed to be responsible for the deviation of the copolymerization kinetics from the Lewis and Mayo theory. The deviations disappear if A is replaced by isopropenylacetate [Ip], Then one gets, for the Ip -C copolymerization. rI p =0.35 and :rc=2.4, and for I -V copolymerization, rI p=0.13 and rv=5.9. The internal transfer reaction causes the formation of branches which may be evidenced by NMR analysis of constant composition suspension A-C copolymers. A kinetic scheme is proposed and the corresponding reactivity ratios derived rA=0.29, rc=1.60, r=0.3 (radical resulting from the transfer reaction), and kT=1500 (rate constant of the transfer reaction at 50°C). The distribution of branches is calculated together with the sequence distribution functions for the .A. or Cunits. 相似文献
57.
α-n-amylcinnamaldehyde (jasminaldehyde) was obtained with 82 % yield by solid-liquid phase transfer catalysis without solvent within 3 days at room temperature. By use of domestic microwave irradiation, the same yield was obtained within 1 minute at a power of 600 W. 相似文献
58.
Regioselective hydrolysis of cocaine led, according to the reaction conditions, either to benzoylecgonine or to ecgonine methyl ester. Acylation with benzoylecgonine was readily achieved when benzotriazolyloxytrisdimethylamino-phosphonium (BOP) was used as a coupling agent. 相似文献
59.
Nguyen Huu Dinh Hoang Thi Tuyet Lan Tran Thi Thu Trang Pham Van Hoan 《Journal of heterocyclic chemistry》2012,49(4):814-822
A novel hydrazide, 2‐methoxy‐4‐(3‐methyfuroxan‐4‐yl)‐5‐nitrophenoxyacetylhydrazine, was prepared from isoeugenoxyacetic acid. The hydrazide was condensed with aromatic aldehydes to give a series of 20 hydrazide‐hydrazones incorporating the furoxan ring. The structure of obtained compounds was determined by analytical and spectral data. It was demonstrated that the two sets of resonance signals in the 1H‐NMR and 13C‐NMR spectra of the examined hydrazide‐hydrazones are caused by EN–C(O) and ZN–C(O) conformers. The energy barriers for the conformation exchange were determined by 1H‐NMR‐measurement at various temperatures. Among seven tested hydrazide‐hydrazones, four compounds exhibit inhibition activities in vitro on human epidermis carcinoma (KB‐cell) with IC50 = 47, 68, 79, and 103 μg/mL. 相似文献
60.
Pham TN Hinchley SL Rankin DW Liptaj T Uhrín D 《Journal of the American Chemical Society》2004,126(40):13100-13110
We have developed methodology for the determination of solution structures of small molecules from residual dipolar coupling constants measured in dilute liquid crystals. The power of the new technique is demonstrated by the determination of the structure of methyl beta-d-xylopyranoside (I) in solution. An oriented sample of I was prepared using a mixture of C(12)E(5) and hexanol in D(2)O. Thirty residual dipolar coupling constants, ranging from -6.44 to 4.99 Hz, were measured using intensity-based J-modulated NMR techniques. These include 15 D(HH), 4 (1)D(CH), and 11 (n)D(CH) coupling constants. The accuracy of the dipolar coupling constants is estimated to be < +/- 0.02 Hz. New constant-time HMBC NMR experiments were developed for the measurement of (n)D(CH) coupling constants, the use of which was crucial for the successful structure determination of I, as they allowed us to increase the number of fitted parameters. The structure of I was refined using a model in which the directly bonded interatom distances were fixed at their ab initio values, while 16 geometrical and 5 order parameters were optimized. These included 2 CCC and 6 CCH angles, and 2 CCCC and 6 CCCH dihedral angles. Vibrationally averaged dipolar coupling constants were used during the refinement. The refined solution structure of I is very similar to that obtained by ab initio calculations, with 11 bond and dihedral angles differing by 0.8 degrees or less and the remaining 5 parameters differing by up to 3.3 degrees . Comparison with the neutron diffraction structure showed larger differences attributable to crystal packing effects. Reducing the degree of order by using dilute liquid crystalline media in combination with precise measurement of small residual dipolar coupling constants, as shown here, is a way of overcoming the limitation of strongly orienting liquid crystals associated with the complexity of (1)H NMR spectra for molecules with more than 12 protons. 相似文献