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161.
162.
The exterior degree of a pair of finite groups (G, N), which is a generalization of the exterior degree of finite groups, is the probability for two elements (g, n) in (G, N) such that g ? n = 1. In the present paper, we state some relations between this concept and the relative commutatively degree, capability and the Schur multiplier of a pair of groups. 相似文献
163.
Alcohols and Phenols are protected efficiently with dihydropyran(DHP) in the presence of catalytic amounts of zirconium tetrachloride in dichloromethane. Deprotection of THP-ethers is also afforded in a methanolic solution at room temperature. 相似文献
164.
Oximes were oxidized to the corresponding carbonyl compounds in good to high yields by environmentally friendly and green oxidant,H_2O_2 catalyzed by montmorillonite K-10 supported cobalt(Ⅱ) chloride. 相似文献
165.
Majid Moghadam Iraj Mohammadpoor-Baltork Valiollah Mirkhani Shahram Tangestaninejad Mohammad Abdollahi-Alibeik Behrooz H. Yousefi Hadi Kargar 《Monatshefte für Chemie / Chemical Monthly》2007,138(6):579-583
Summary. Small assemblies of 2-imidazolines and bisimidazolines from appropriate nitriles and ethylenediamine with catalytic amounts
of P2S5 employing a microwave assisted protocol were prepared. Sonication of this system also led to successful synthesis of 2-imidazolines
and bisimidazolines. Another advantage of these systems is the ability to carry out large scale reactions. 相似文献
166.
Dr. Katherine G. Young Behnam Najafi William M. Sant Prof. Sonia Contera Prof. Ard A. Louis Prof. Jonathan P. K. Doye Prof. Andrew J. Turberfield Dr. Jonathan Bath 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(37):16076-16080
DNA self-assembly allows the construction of nanometre-scale structures and devices. Structures with thousands of unique components are routinely assembled in good yield. Experimental progress has been rapid, based largely on empirical design rules. Herein, we demonstrate a DNA origami technique designed as a model system with which to explore the mechanism of assembly. The origami fold is controlled through single-stranded loops embedded in a double-stranded DNA template and is programmed by a set of double-stranded linkers that specify pairwise interactions between loop sequences. Assembly is via T-junctions formed by hybridization of single-stranded overhangs on the linkers with the loops. The sequence of loops on the template and the set of interaction rules embodied in the linkers can be reconfigured with ease. We show that a set of just two interaction rules can be used to assemble simple T-junction origami motifs and that assembly can be performed at room temperature. 相似文献
167.
Majid Moghadam Iraj Mohammadpoor‐Baltork Shahram Tangestaninejad Valiollah Mirkhani Ahmad Reza Khosropour S. Abdolmanaf Taghavi 《应用有机金属化学》2011,25(9):687-694
In the present work, the application of electron‐deficient tetraphenylporphyrinatovanadium(IV) trifluoromethanesulfonate, [VIV(TPP)(OTf)2], in the trimethylsilylation of alcohols and phenols with hexamethydisilazane (HMDS) is reported. This new V(IV) catalyst was used as an efficient catalyst for silylation of not only primary alcohols but also sterically hindered secondary and tertiary alcohols with HMDS. Trimethylsilylation of phenols with HMDS was also performed to afford the desired Trimethylsilyl ethers (TMS) ethers. The chemoselectivity of this method was also investigated. This catalyst can be reused several times without loss of its activity. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
168.
Omid Bagheri Faranak Sadegh Majid Moghadam Shahram Tangestaninejad Valiollah Mirkhani Iraj Mohammadpoor‐Baltork Mahsa Safiri 《应用有机金属化学》2014,28(5):337-346
The tetrakis(4‐N‐methylpyridinium)porphyrinatopalladium(II) iodide, [Pd(TMPyP)]I4, supported on Dowex 50WX8 and Amberlite IR‐120 ion‐exchange resins, was used as heterogeneous, recyclable and active catalyst for the Suzuki–Miyaura and Heck cross‐coupling reactions. These catalysts were applied to coupling of various aryl halides with phenylboronic acid and styrene in Suzuki and Heck reactions, respectively, and the corresponding products were obtained in excellent yields and short reaction times. The catalysts could be recovered easily by simple filtration and reused several times without significant loss of their catalytic activity. The catalysts were characterized by diffuse‐reflectance UV–visible spectroscopy and scanning electron microscopy, and their stability was confirmed by TGA. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
169.