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91.
T. M. Ivanova M. I. Bazanov A. V. Petrov R. V. Linko K. M. Dyumaev 《Russian Journal of Inorganic Chemistry》2006,51(12):1945-1948
The electronic structure of cobalt complexes with bi-, tri-, and tetradentate ligands and the mutual influence of ligands in them have been studied by X-ray photoelectron spectroscopy. The Co2p, N1s, and O1s photoelectron spectra have been studied. Unlike low-spin Co(III) complexes, the high-spin Co(II) compound exhibits a strong satellite line in the Co2p spectrum. For the high-spin Co(II) compound having unpaired 3d electrons, the Co2p 1/2-Co2p 3/2 spin-orbit splitting is larger than that in the low-spin Co(III) complexes. All cobalt complexes under consideration contain strongly bound dioxygen, which can be considered an inherent structural unit. 相似文献
92.
Perfluoropentadienes and perfluoro-2,4-hexadienes react with tetrafluoroethylene with SbF5 as the catalyst at 20–50°C to give higher perfluorinated dienes.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 920–923, April, 1990. 相似文献
93.
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95.
We develop a novel model of the QCD matter critical endpoint by matching the deconfinement phase transition curve with the nil line of the bag surface tension coefficient. As a result, this leads to a new structure of the leading singularities of isobaric partition, and in contrast to all previous studies of such models, the deconfined phase in our approach is defined not by an essential singularity of the isobaric partition function but its simple pole. As an unexpected result, we find out that the first order phase transition in this model is the surface tension induced transition. The sufficient conditions of its existence are analyzed and the possible physical consequences are discussed. 相似文献
96.
P. O. Petrov E. S. Tuchina M. V. Kulikova V. I. Kochubei V. V. Tuchin 《Optics and Spectroscopy》2013,115(2):161-165
The effect of blue (405 nm) radiation of a light-emitting diode in combination with titanium(IV) and iron(III) oxide nanoparticles on S. aureus 209 P, S. simulans, and D. hominis bacteria is studied. It is shown that, upon irradiation of bacteria by blue (405 nm) light, Fe2O3 nanoparticles have a stronger (by 5–30%) antibacterial effect than TiO2 nanoparticles. 相似文献
97.
The New Data for the Reaction of Arylenedioxy Trihalogenophosphoranes with Alkyl- and Arylacetylenes
Vladimir F. Mironov Alfiya A. Shtyrlina Ravil R. Petrov Tamara A. Baronova Fedor F. Alekseev Elena N. Varaksina 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6-7):1381-1385
The new data concerning the reaction between substituted arylenedioxy trihalogenophosphoranes and monoalkyl- or arylacetylenes are summarized. The reaction leads to formation of six-membered heterocycles-2-oxo-4-R-benzo[ e ]-1,2-oxaphosphorin-3-enes. The substituent effects in the phosphorane and acetylene molecules on the ipso -substitution and halogenation regiochemistry are discussed. The ipso -substitution of tert -butyl group on chlorine and the exchange of bromine on chlorine and iodine on hydrogen have been observed, along with formation of benzophosphorines. The interaction of tetrachloro- ortho -benzoquinone with phosphorus trichloride and arylacetylenes is proposed as a new modification of the reaction leading to the formation of benzo[ e ]-1,2-oxaphosphorines. The structures of some benzo[ e ]-1,2-oxaphosphorines are determined by the single crystal X-ray diffraction. 相似文献
98.
K. Olimov V. V. Glagolev K. G. Gulamov S. L. Lutpullaev A. R. Kurbanov A. K. Olimov V. I. Petrov A. A. Yuldashev 《Physics of Atomic Nuclei》2013,76(7):881-882
New experimental data on the cross sections for the yield of excited 6Li* and 7Li* nuclei and on their contributions to the production of 4He + 2H and 4He+3H light dinuclear systems in 16O p collisions at a momentumof 3.25 A GeV/c per nucleon are presented. 相似文献
99.
100.
Yu. D. Zavartsev M. V. Zavertyaev A. I. Zagumenniy A. F. Zerrouk V. A. Kozlov S. A. Kutovoi N. V. Pestovskii A. A. Petrov S. Yu. Savinov 《Bulletin of the Lebedev Physics Institute》2016,43(11):336-339
Optical and luminescence characteristics of Lu2+2ySi1-yO5+y (LFS) scintillation crystals are studied before and after irradiation with doses to 45 Mrad from a 60Co source. LFS crystals were doped with Ce3+, Sc3+, Ca2+, and Y3+ ions with various concentrations. The dependence of the radiation resistance of LFS crystals on Ce ion concentration is detected. For the crystal of composition Ce:Sc:Ca:Y:LFS, it was found that its optical transmission (OT) and pulsed cathodoluminescence (PCL) spectra before irradiation do not differ from the spectra measured after irradiation with a dose of 45 Mrad within experimental error. The nature of the radiation resistance of rare-earth lutetium oxyorthosilicates (LFS) is discussed. 相似文献