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排序方式: 共有168条查询结果,搜索用时 15 毫秒
61.
Pappas C Tarantilis PA Daliani I Mavromoustakos T Polissiou M 《Ultrasonics sonochemistry》2002,9(1):19-23
A comparative study of classical and ultrasound-assisted extraction and purification of cellulose from kenaf (Hibiscus cannabinus L.) and eucalyptus (Eucalyptus rodustrus Sm.), has been conducted. The isolated cellulose samples were studied by diffuse reflectance infrared Fourier transform spectroscopy and 13C nuclear magnetic resonance (13C-NMR) spectroscopy and the crystallinity was also determined. The use of ultrasound decreased the total time of treatment, in addition the purity of the obtained cellulose was very high. 相似文献
62.
In this paper, we analyze the recursive merge sort algorithm and quantify the deviation of the output from the correct sorted order if the outcomes of one or more comparisons are in error. The disorder in the output sequence is quantified by four measures: the number of runs, the smallest number of integers that need to be removed to leave the sequence sorted, the number of inversions, and the smallest number of successive exchanges needed to sort the sequence. For input sequences whose length is large compared to the number of errors, a comparison is made between the robustness to errors of bubble sort, straight insertion sort, and recursive merge sort. 相似文献
63.
The adsorption of, the still widely used, herbicide atrazine on model soil components, such as humic acid and humic acid-silica gel mixtures, was investigated in a series of batch experiments, under different experimental conditions (ionic strength, temperature, and pH). The investigation aimed at obtaining an estimate of the contribution of each of the soil components on the adsorption of atrazine from aqueous solutions. The kinetics of atrazine adsorption on humic acid showed two steps: a fast step, of a few hours duration, and a second slow step, which continued for weeks. The kinetics of adsorption data gave a satisfactory fit to the Elovich equation. Τhe adsorption of atrazine on the test substrates was found to be reversible in all cases. The atrazine uptake data on the test substrates were fitted best with the Freundlich adsorption isotherm. The ionic strength of the atrazine aqueous solutions did affect the amount of the atrazine adsorbed on the test substrates, suggesting that electrostatic forces between atrazine molecules and soil play a significant role in the adsorption process. An increase of temperature resulted in a decrease of atrazine adsorption on humic acid at low atrazine equilibrium concentrations. However, for higher levels of equilibrium concentrations (≥3 mg/L) the amount of atrazine adsorbed onto the test substrate increased as temperature increased. The calculated isosteric enthalpies of adsorption ranged between slightly exothermic at low atrazine uptake and slightly endothermic at high atrazine uptake, all values being in the range of physisorption. 相似文献
64.
Fragment-based lead discovery has undergone remarkable changes over the last 15 years. During this time, the pharmaceutical
industry has changed dramatically as well, and continued evolution of the industry is assured. These changes present many
challenges but also several opportunities for executing fragment-based drug design. This article will explore some of the
more significant changes in the industry and how they may affect future discovery efforts related to fragment-based initiatives. 相似文献
65.
Emmanouil E. Zachariadis Christos D. Tarantilis Chris T. Kiranoudis 《European Journal of Operational Research》2013
The present article examines a vehicle routing problem integrated with two-dimensional loading constraints, called 2L-CVRP. The problem is aimed at generating the optimal route set for satisfying customer demand. In addition, feasible loading arrangements have to be determined for the transported products. To solve 2L-CVRP, we propose a metaheuristic solution approach. The basic advantage of our approach lies at its compact structure, as in total, only two parameters affect the algorithmic performance. To optimize the routing aspects, we propose a local-search method equipped with an effective diversification component based on the regional aspiration criteria. The problem’s loading requirements are tackled by employing a two-dimensional packing heuristic which repetitively attempts to develop feasible loading patterns. These attempts are effectively coordinated via an innovative, simple-structured memory mechanism. The overall solution framework makes use of several memory components for drastically reducing the computational effort required. The performance of our metaheuristic development has been successfully evaluated on benchmark instances considering two distinct versions of the loading constraints. More specifically, the algorithm managed to improve or match the majority of best known solution scores for both problem versions. 相似文献
66.
Rossi C Boss A Haap M Martirosian P Claussen CD Schick F 《Magnetic resonance imaging》2009,27(4):489-496
This study investigated the feasibility of an MRI protocol providing whole-body T2* maps at 1.5 T. Seven healthy volunteers (mean age=30.1+/-3.7, three women and four men) and two patients (both male, 53 and 46 years old) affected by transfusion-dependent anemias participated in the study. Coronally oriented images of five subsequent body levels were acquired using a fat-suppressed multiecho 2D gradient-echo sequence (12 echo times ranging from 4.8 to 76.3 ms were selected) and afterwards composed. Parametrical T2* maps of the whole body were reconstructed on a pixel-by-pixel basis. For both, healthy volunteers and patients, representative T2* values were computed from extended regions of interest (ROIs). Good-quality whole-body T2* maps were computed in all volunteers and patients. In healthy volunteers, T2* values were assessed in the cerebral white (58.5+/-4.2 ms) and gray (81.4+/-5.5 ms) matter, liver (34.3+/-7.0 ms), spleen (63.5+/-3.3 ms), kidneys (65.4+/-10.3 ms) and skeletal muscles (~30 ms). The liver presented faster relaxation rates in males as compared to females. One patient (serum ferritin concentration=927 microg/dl) showed shortened T2* values in liver (3.6+/-5.5 ms), spleen (3.1+/-4.8 ms), kidneys (11.1+/-7.1 ms) and muscles (25.1+/-3.4 ms). The second patient (serum ferritin concentration=346 microg/dl) presented reduced T2* values in liver (3.9+/-7.3 ms), spleen (20.1+/-9.8 ms) and kidneys (24.6+/-7.7 ms). The presented technique may find clinical application in the assessment of the iron burden in the entire body, and in monitoring of chelation therapies in patients treated with frequent blood transfusions. 相似文献
67.
Sakharam P. Waghmare Petros Pousinis David P. Hornby Mark J. Dickman 《Journal of chromatography. A》2009,1216(9):1377-1382
DNA/RNA chromatography presents a versatile platform for the analysis of nucleic acids. Although the mechanism of separation of double stranded (ds) DNA fragments is largely understood, the mechanism by which RNA is separated appears more complicated. To further understand the separation mechanisms of RNA using ion pair reverse phase liquid chromatography, we have analysed a number of dsRNA and single stranded (ss) RNA fragments. The high-resolution separation of dsRNA was observed, in a similar manner to dsDNA under non-denaturing conditions. Moreover, the high-resolution separation of ssRNA was observed at high temperatures (75 °C) in contrast to ssDNA. It is proposed that the presence of duplex regions/secondary structures within the RNA remain at such temperatures, resulting in high-resolution RNA separations. The retention time of the nucleic acids reflects the relative hydrophobicity, through contributions of the nucleic sequence and the degree of secondary structure present. In addition, the analysis of RNA using such approaches was extended to enable the discrimination of bacterial 16S rRNA fragments and as an aid to conformational analysis of RNA. RNA:RNA interactions of the human telomerase RNA component (hTR) were analysed in conjunction with the incorporation of Mg2+ during chromatography. This novel chromatographic procedure permits analysis of the temperature dependent formation of dimeric RNA species. 相似文献
68.
P.P. Repoussis D.C. Paraskevopoulos G. Zobolas C.D. Tarantilis G. Ioannou 《European Journal of Operational Research》2009
This paper presents a web-based decision support system (DSS) that enables schedulers to tackle reverse supply chain management problems interactively. The focus is on the efficient and effective management of waste lube oils collection and recycling operations. The emphasis is given on the systemic dimensions and modular architecture of the proposed DSS. The latter incorporates intra- and inter-city vehicle routing with real-life operational constraints using shortest path and sophisticated hybrid metaheuristic algorithms. It is also integrated with an Enterprise Resource Planning system allowing the utilization of particular functional modules and the combination with other peripheral planning tools. Furthermore, the proposed DSS provides a framework for on-line monitoring and reporting to all stages of the waste collection processes. The system is developed using a web architecture that enables sharing of information and algorithms among multiple sites, along with wireless telecommunication facilities. The application to an industrial environment showed improved productivity and competitiveness, indicating its applicability on realistic reverse logistical planning problems. 相似文献
69.
Andrea Mignone Petros Tzeferacos Gianluigi Bodo 《Journal of computational physics》2010,229(17):5896-5920
We present and compare third- as well as fifth-order accurate finite difference schemes for the numerical solution of the compressible ideal MHD equations in multiple spatial dimensions. The selected methods lean on four different reconstruction techniques based on recently improved versions of the weighted essentially non-oscillatory (WENO) schemes, monotonicity preserving (MP) schemes as well as slope-limited polynomial reconstruction. The proposed numerical methods are highly accurate in smooth regions of the flow, avoid loss of accuracy in proximity of smooth extrema and provide sharp non-oscillatory transitions at discontinuities. 相似文献
70.
Ehrlich H Koutsoukos PG Demadis KD Pokrovsky OS 《Micron (Oxford, England : 1993)》2008,39(8):1062-1091
In contrast to biomineralization phenomena, that are among the most widely studied topics in modern material and earth science and biomedicine, much less is systematized on modern view of demineralization. Biomineralized structures and tissues are composites, containing a biologically produced organic matrix and nano- or microscale amorphous or crystalline minerals. Demineralization is the process of removing the inorganic part, or the biominerals, that takes place in nature via either physiological or pathological pathways in organisms. In vitro demineralization processes, used to obtain mechanistic information, consist in the isolation of the mineral phase of the composite biomaterials from the organic matrix. Physiological and pathological demineralization include, for example, bone resorption mediated by osteoclasts. Bioerosion, a more general term for the process of deterioration of the composite biomaterials represents chemical deterioration of the organic and mineral phase followed by biological attack of the composite by microorganisms and enzymes. Bioerosional organisms are represented by endolithic cyanobacteria, fungi, algae, plants, sponges, phoronids and polychaetes, mollusks, fish and echinoids.In the history of demineralization studies, the driving force was based on problems of human health, mostly dental caries. In this paper we summarize and integrate a number of events, discoveries, milestone papers and books on different aspect of demineralization during the last 400 years. Overall, demineralization is a rapidly growing and challenging aspect of various scientific disciplines such as astrobiology, paleoclimatology, geomedicine, archaeology, geobiology, dentistry, histology, biotechnology, and others to mention just a few. 相似文献