Infinite dilution activity coefficient and vapour liquid equilibrium measurements for dimethylsulphide and tetrahydrothiophene with hydrocarbons

The activity coefficients at infinite dilution (γ^∞) of dimethylsulphide (DMS) in four hydrocarbon solvents were measured using the dilutor technique at temperatures between 288 K and 303 K. The four hydrocarbons were hexane, 1-hexene, 2,2,4-trimethylpentane and 2,4,4-trimethyl-1-pentene. The dilutor technique is based on the stripping of the highly diluted solute, i.e. DMS, by a constant flow of inert gas. The gas composition was analysed by gas chromatography and the rate of solute removal was calculated from the area of the peaks.     

Viscoelasticity and water plasticization of polymer-cellulose composite films and paper sheets

Viscoelastic properties of cellulose microfibril—polymer composites and paper sheets were studied with dynamic mechanical analysis as a function of relative humidity in order to assess the bonding properties in cellulosic networks. The amount of associated water in the composites (equilibrium moisture content) was measured by thermogravimetry. Water plasticization was evidenced by DMA both in composite and paper samples. Polymers with high affinity to water, e.g. carboxymethyl cellulose, clearly increased the water plasticization in the composites. The plasticization behavior of paper sheet samples was also influenced by polymers. However, the effect of polymers on the plasticization was different between the composite and the paper samples. The consideration of fiber bonding domain in paper structure as a gel-like layer consisting of cellulose microfibrils, polymers, and associated water can help to unveil some of the complex mechanisms behind the strength in fibrous cellulosic materials.     

Detection of phase biaxiality in liquid crystals by use of the quadrupole shift in 131Xe NMR spectra

An experimental method to unambiguously distinguish between uniaxial and biaxial liquid crystal phases is introduced. The method is based on the second order quadrupole shift (SOQS) observable in 131Xe NMR spectra of xenon dissolved in liquid crystals. It is shown that besides revealing the biaxiality, the 131Xe SOQS offers a novel method to determine the tilt angle in smectic C phases. As an example, the 131Xe SOQS in a ferroelectric liquid crystal is reported. It yields up a biaxial phase in between isotropic and smectic C phases.     

Observation of transverse polarization asymmetries of charged pion pairs in e+e- annihilation near √s = 10.58 GeV

The interference fragmentation function translates the fragmentation of a quark with a transverse projection of the spin into an azimuthal asymmetry of two final-state hadrons. In e(+)e(-) annihilation the product of two interference fragmentation functions is measured. We report nonzero asymmetries for pairs of charge-ordered π(+)π(-) pairs, which indicate a significant interference fragmentation function in this channel. The results are obtained from a 672 fb(-1) data sample that contains 711 × 10(6) π(+)π(-) pairs and was collected at and near the Υ(4S) resonance, with the Belle detector at the KEKB asymmetric-energy e(+)e(-) collider.     

On stretching the interval simplex-permutohedron

A family of polytopes introduced by E.M. Feichtner, A. Postnikov, and B. Sturmfels, which were named nestohedra, consists in each dimension of an interval of polytopes starting with a simplex and ending with a permutohedron. This paper investigates a problem of changing and extending the boundaries of these intervals. An iterative application of Feichtner–Kozlov procedure of forming complexes of nested sets is a solution of this problem. By using a simple algebraic presentation of members of nested sets it is possible to avoid the problem of increasing the complexity of the structure of nested curly braces in elements of the produced simplicial complexes.     

Symmetric Bimonoidal Intermuting Categories and ω × ω Reduced Bar Constructions

A new, self-contained, proof of a coherence result for categories equipped with two symmetric monoidal structures bridged by a natural transformation is given. It is shown that this coherence result is sufficient for ω × ω-indexed family of iterated reduced bar constructions based on such a category.     

Measurement of homonuclear (2)J-couplings from spin-state selective double-/zero-quantum two-dimensional NMR spectra.

(1)H-detected two-dimensional double-/zero-quantum experiments are described for measurement of homonuclear (2)J(HH)-couplings of NH(2) or CH(2) groups in proteins. These experiments utilize multiple-quantum coherence for determination of the size and the absolute sign of the geminal scalar and dipolar couplings in the presence of broad lines. Spectra are simplified by gradient selection and spin-state selective filters.     

Hypergraph polytopes

We investigate a family of polytopes introduced by E.M. Feichtner, A. Postnikov and B. Sturmfels, which were named nestohedra. The vertices of these polytopes may intuitively be understood as constructions of hypergraphs. Limit cases in this family of polytopes are, on the one end, simplices, and, on the other end, permutohedra. In between, as notable members one finds associahedra and cyclohedra. The polytopes in this family are investigated here both as abstract polytopes and as realized in Euclidean spaces of all finite dimensions. The later realizations are inspired by J.D. Stasheff ?s and S. Shnider?s realizations of associahedra. In these realizations, passing from simplices to permutohedra, via associahedra, cyclohedra and other interesting polytopes, involves truncating vertices, edges and other faces. The results presented here reformulate, systematize and extend previously obtained results, and in particular those concerning polytopes based on constructions of graphs, which were introduced by M. Carr and S.L. Devadoss.