Elongation of the molecular probe DDNP with phenylethynylidene or phenyldiazenylidene spacers

In this work, we report the synthesis, X-ray structures, and optical properties of two DDNP analogs containing an unsaturated spacer inserted between the donor N,N-dimethylamino group and the naphthalene ring. The new compounds have longer distances between the donor and acceptor groups and are intended to serve as molecular probes for the assessment of spatial and polarity requirements for binding to protein aggregates found in the central nervous system (CNS) of patients with neurodegenerative diseases.     

Interactions between global and grazing bifurcations in an impacting system

It is well known that the locus of boundary crises in smooth systems contains gaps that give rise to periodic windows. We show that this phenomenon can also be observed in an impacting system, and that the mechanism by which these gaps are created is different. Namely, here gaps are created and disappear at points along the branches of boundary crises where they are intersected by branches of grazing bifurcations. We locate a novel type of double-crisis vertex which we call a grazing-crisis vertex. Additionally, we illustrate several types of basin-boundary metamorphosis that are intricately related with grazing bifurcations.     

Lifetime measurement of the 2(1)+ state in 20C

Establishing how and when large N/Z values require modified or new theoretical tools is a major quest in nuclear physics. Here we report the first measurement of the lifetime of the 2(1)+ state in the near-dripline nucleus 20C. The deduced value of τ(2(1)+)=9.8±2.8(stat)(-1.1)(+0.5)(syst) ps gives a reduced transition probability of B(E2; 2(1)+→0(g.s.)+)=7.5(-1.7)(+3.0)(stat)(-0.4)(+1.0)(syst) e2 fm4 in good agreement with a shell model calculation using isospin-dependent effective charges.     

Characterization of silane layers on modified stainless steel surfaces and related stainless steel-plastic hybrids

The aim of this work was to characterize silane layers on the modified stainless steel surfaces and relate it to the adhesion in the injection-molded thermoplastic urethane-stainless steel hybrids. The silane layers were characterized with scanning electron microscope and transmission electron microscope, allowing the direct quantization of silane layer thickness and its variation. The surface topographies were characterized with atomic force microscope and chemical analyses were performed with X-ray photoelectron spectroscopy. The mechanical strength of the respective stainless steel-thermoplastic urethane hybrids was determined by peel test. Polishing and oxidation treatment of the steel surface improved the silane layer uniformity compared to the industrially pickled surface and increased the adhesion strength of the hybrids, resulting mainly cohesive failure in TPU. XPS analysis indicated that the improved silane bonding to the modified steel surface was due to clean Fe₂O₃-type surface oxide and stronger interaction with TPU was due to more amino species on the silane layer surface compared to the cleaned, industrially pickled surface. Silane layer thickness affected failure type of the hybrids, with a thick silane layer the hybrids failed mainly in the silane layer and with a thinner layer cohesively in plastic.     

Photoemission of spinpolarized electrons from strained GaAsP

Strained layer GaAs_.95P_.05 photo cathodes are presented, which emit electron beams spinpolarized to a degree of P = 75% typically. Quantum yields around QE = 0.4% are observed routinely. The figure of merit P² × QE = 2.3 × 10^–3 is comparable to that of the best strained layer cathodes reported in literature. The optimum wavelength of irradiating light around 830 nm is in convenient reach of Ti:sapphire lasers or diode lasers respectively. The cathodes are produced using MOCVD-techniques. A GaAs_.55P_.45-GaAs_.85P_.15 superlattice structure prevents the migration of dislocations from the substrate and bottom layers to the strained overlayer. The surface is protected by an arsenic layer so that no chemical cleaning is necessary before installation into vacuum. The source of polarized electrons attached to the Mainz race track microtron MAMI works with such cathodes now. More than 1000 hours beamtime have been performed successfully.     

Numerical analysis of a CO2 SFUR laser cavity

Summary In this paper we present a numerical study of the SFUR (self-filtering unstable resonator) cavity resonant modes and numerical results are compared with the experimental data. The numerical code developed for analysing the SFUR cavity will also allow for studying a wider class of resonators, and is therefore a very useful tool in designing new laser cavities.     

Topological geometrodynamics and the solar neutrino problem

A solution of the solar neutrino problem based on certain differences between T(opological) G(eometro) D(ynamics) and the standard model of the electroweak interactions is proposed. First, TGD predicts the existence of a right-handed neutrino inert with respect to ordinary electroweak interactions. Second, the generalization of the massless Dirac equation contains terms mixing differentM ⁴ chiralities, unlike the ordinary massless Dirac equation. This and the observation of anticorrelations of the solar neutrino flux with sunspot number suggest that solar neutrinos are transformed to right-handed neutrinos on the convective zone of the Sun. Third, the compactness ofCP ₂ implies topological field quantization: space-time decomposes into regions, topological field quanta, characterized by a handful of vacuum quantum numbers. In particular, there are topological obstructions for the smooth global imbeddings of magnetic fields and the decomposition of the solar magnetic field into flux tubes is predicted. Finally, every electromagnetically neutral mass distribution is accompanied by a long-rangeZ ⁰ vacuum field. If the vacuum quantum numbers inside the flux tubes of the solar magnetic field are considerably smaller than in the normal phase, theZ ⁰ electric force becomes strong and implies Thomas precession for the spin of the lefthanded component of the neutrino. As a consequence, left-handed neutrinos are transformed to right-handed ones and the process is irreversible, since righthanded neutrinos do not couple toZ ⁰.