EPR study of a place-exchange reaction on Au nanoparticles: two branches of a disulfide molecule do not adsorb adjacent to each other

An EPR study of a place-exchange reaction of a diradical disulfide with butanethiol-protected Au nanoparticles showed that the two branches of the disulfide molecule do not adsorb adjacent to each other on the Au surface. The most likely mechanism includes adsorption of only one branch of the disulfide molecule in the exchange process. The exchange reaction was found to be zeroth-order with respect to the diradical, indicative of a dissociative "SN1"-type mechanism.     

Invariant critical sets of conserved quantities

For a dynamical system we will construct various invariant sets starting from its conserved quantities. We will give conditions under which certain solutions of a nonlinear system are also solutions for a simpler dynamical system, for example when they are solutions for a linear dynamical system. We will apply these results to the example of Toda lattice.     

Capillary electrophoretic analysis of sulfur and cyanicides speciation during cyanidation of gold complex sulfidic ores

A capillary electrophoretic protocol for the separation and quantification of the most important species potentially liberated during the cyanidation of gold sulfide‐rich ores was accomplished in this study. The separation of 11 ions: S₂O₃^2–, Cu(CN)₃^2–, Fe(CN)₆^4–, Fe(CN)₆^3–, SCN^–, Au(CN)₂^–, Ag(CN)₂^–, SO₄^2–, OCN^–, SO₃^2–, and HS^– was achieved using an indirect UV detection method. The robustness of the analytical protocol was tested by analyzing ions speciation during the cyanidation of two gold sulfide‐rich ores. The 1‐h cyanidation of the two ores released up to six complexes into solution: S₂O₃^2–, Cu(CN)₃^2–, SCN^–, Fe(CN)₆^4–, OCN^–, and SO₄^2–. The mineralogy of the ore was found to influence directly the nature and the amount of the dissolved species. Conserving the cyanidation solution for 72 h after sampling resulted in 96% total sulfur recovery. These results allow us to conclude that the analytical protocol developed in this study can become very useful for the optimization of precious‐metals cyanidation plants.     

The Strong Variant of a Barbashin Theorem on Stability of Solutions for Non-autonomous Differential Equations in Banach Spaces

Among others we shall prove that an exponentially bounded evolution family U = {U(t, s)} _t≥s≥0 of bounded linear operators acting on a Banach space X is uniformly exponentially stable if and only if there exists q [1, ∞) such that

Modeling the angular capability of the ball joints in a complex mechanism with two degrees of mobility

The paper puts forward a complex linkage mechanism with two degrees of mobility and three kinematic loops, which is used for the guiding (suspension and steering) system of the vehicles. The geometric parameters and the coordinates frames that define the mechanical system are presented, as well as the specific kinematic functions. For this complex mechanical system, the angular capability of the ball (spherical) joints is defined by two angles. The equations for these angles have been determined by matrix algebra tools, considering the transformation matrices between the bodies reference frames. The diagrams of the angular capability of the ball joints, which are represented in angular coordinates, describe the form, orientation and size of the sockets from the spherical casings. Wears, shocks, functional locks or the compromising of the joint strength can occur if scarce sockets are implemented. The risk points, in which the angular parameters have maximum values, have been determined, the simulation being performed for a real system (vehicle).     

<Emphasis Type="Italic">Saccharomyces cerevisiae</Emphasis> yeast immobilized on marrow stem sunflower and polyacrylamide hydrogels

Biocatalysts with microorganisms immobilized on solid carriers could provide the solution for development of continuous industrial processes for ethanol obtaining by fermentation of sugars. In this study, modified polyacrylamide hydrogels and marrow stem sunflower are used as supports for Saccharomyces cerevisiae yeast immobilization. The obtained structures are used for fermentation of molasses in batch systems. The free yeast cells are used as reference. The modification of polyacrilamide matrix with (2-hydroxyethyl)methacrylate has a positive effect on structure pore uniformity and fermentation performance. The mechanical properties of the obtained biocatalysts are compared. The novel natural matrix has net superior compression strength.

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Silica veils-conductive diamond powder composite as a new propitious substrate for platinum electrocatalysts

An innovative composite was obtained by a straightforward sol-gel procedure, involving boron-doped diamond powder (BDDP) incorporation into a SiO₂ veil (SiO₂V) matrix. Composite-coated glassy carbon plates were used as substrate for Pt electrochemical deposition, and the electrodes thus obtained (Pt/BDDP–SiO₂V) were compared on a relative basis with those prepared in the absence of the silica matrix (Pt/BDDP). SEM measurements have shown that a BDDP substrate promotes Pt cluster formation, whereas on BDDP–SiO₂V, particles are much smaller (ca. 45 nm to ca. 140 nm). The activity for CH₃OH oxidation was checked by cyclic voltammetry, and it was found that at Pt/BDDP–SiO₂V, the main anodic peak is shifted with ca. 0.35 V toward lower potentials, indicating a considerable improvement in the overall process kinetics. Stripping experiments together with long-term polarization measurements demonstrated that when deposited on the BDDP–SiO₂V support, Pt particles are less susceptible to CO poisoning and this behavior was tentatively ascribed to the presence of a higher relative surface concentration of more stable, oxidized platinum species, as evidenced by XPS.     

Thermal behavior of several stable hydrazyl free radicals and of their parent hydrazines

A thermal analysis study has been performed for the stable free radical 2,2-diphenyl-1-picrylhydrazyl and other ten free radical congeners, together with their corresponding parent hydrazines. Qualitative studies on the decomposition products showed that nitrogen dioxide plays a key role. A mechanistic decomposition pathway is also proposed.     

Depicting the dehydration and dehydroxylation processes in very rare hydrogen arsenate minerals

Journal of Thermal Analysis and Calorimetry - The work represents a pioneering attempt to couple TG analysis and hot-stage t-ATR-FTIR spectroscopy to describe the dehydration and dehydroxylation...