Individual extraction constants of some dicarbollylcobaltate anions in the water-nitrobenzene system

Individual extraction constants of nine dicarbollylcobaltate anions in the two-phase water-nitrobenzene system were determined radiometrically assuming that the changes of Gibbs energy of the transfer of the tetraphenylarsonium cation, Ph₄As⁺, and of the tetraphenylborate anion, BPh ₄ ^– , from the aqueous into the nitrobenzene phase are equal. The constants obtained by this method were correlated with Hansch's constants of hydrophobity.     

Extraction separation of Sr2+ from Ba2+ in the system cobalt dicarbollide-polyethylene glycol-nitrobenzene-CCl4-cyclohexaned iaminetetraacetate

The kinetics of Sr and Ba distribution both for extraction and back-extraction processes has been investigated. The influence of the equilibrium pH, the CDTA concentration and the Na/Li ratio on the distribution of the metals to be separated was established. Separation factors (Ba/Sr) achieved were not altered by replacing PEG 400 as the synergic agent by the cheaper technical product Slovafol 909. Practical hints for carrying out the separation for analytical purposes. are given.     

Extraction of cesium and barium by dicarbollide and polyethylene glycol in the presence of alkylammonium cations

The extraction of cesium and barium cations into nitrobenzene and 60% (vol.%) nitrobenzene +40% CCl₄ mixture in the presence of dicarbollide (+Slovafol 909), and primary alkylammonium cations has been studied. Extraction constants determined for three methylammonium cations correlate well with their hydration enthalpies. Reverse order of the hydrophobicity of methylammonium cations (competition with bare Cs⁺ ion) and of their tendency to enter the polyethylene glycol complex (competition with polyethylene glycol complexed Cs⁺ and Ba²⁺ ions) is recorded. The possibility of the regeneration of the organic phase after stripping of Cs⁺ and Ba²⁺ ions with methylammonium cations has been investigated.     

On Lipschitz property of solutions of functional equations

In this work it is proved that under certain conditions the continuous vector-valued solutionsf of the functional equation

Electrochemical behaviour of a series of Fe(III) complexes with tetradentate Schiff base ligands

Summary The electrochemical reduction of the Fe(III) complexes with a series of substituted N,N-Ethylenebisacetonimines was investigated by cyclic voltammetry in acetonitrile solution at a platinum electrode. The substituent does not significantly influence the redox properties of the studied complexes. The symmetry of the redox orbital is responsible for the observed behaviour of the complexes.

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Elektrochemisches Verhalten einer Reihe von Fe(III)-Komplexen mit vierzähnigen Schiffschen Basen als Liganden

Zusammenfassung Die elektrochemische Reduktion der Fe(III)-Komplexe einer Reihe von substituierten N,N-Ethylenbisacetoniminen wurde mittels cyclischer Voltammetrie in Acetonitril an einer Platinelektrode untersucht. Der Substituent beeinflußt die Redoxeigenschaften der untersuchten Komplexe nicht signifikant. Das beobachtete Verhalten der Komplexe wird von der Symmetrie des Redoxorbitals bestimmt.

     

Comparative voltammetric study of 2,4-dinitrophenol (DNP), albumin and DNP-albumin as an analytical approach to the use of DNP as a universal label in immunoelectrochemical assays

A comparative electrochemical study of 2,4-dinitrophenol (DNP), albumin and DNP-albumin has been carried out at a hanging mercury drop electrode, in order to use DNP as a universal label in immunoelectrical assays. Several electrochemical techniques have been used. Differential pulse voltammetry has proved to be the most suitable. Wide dynamic linear ranges (more than three orders of magnitude for DNP-albumin) and low detection limits have been achieved (5 x 10(-10)M, 2 x 10(-10)M, 3 x 10(-12)M for DNP, albumin and DNP-albumin, respectively). Good reproducibility has been obtained in all cases (R.S.D. < 2.2%).     

The relative importance of temperature and isotope effects on the dipole oscillator strength distribution of H2

Summary The calculation of the effects of temperature and isotopic composition on the energy weighted moments of the dipole oscillator strength distribution of H₂ in the random phase approximation to the polarization propagator are reported. It is seen that the effect of isotopic composition is small, while that of temperature is of an order accessible to experiment. We find that all the mean excitation energiesI , for =–1, 0, 1, decrease with temperature as does the dipole oscillator strength momentS() for >0, while the opposite is true for <0. These effects are interpreted in terms of the bond length dependence of the excitation energies.     

Periodic solutions of dry friction problems

Dry friction problems lead to discontinuous differential equations, e.g. to

The complexity of a class of infinite graphs

IfG _k is the family of countable graphs with nok vertex (or edge) disjoint circuits (1<k<) then there is a countableG _k G _k such that every member ofG _k is an (induced) subgraph of some member ofG _k , but no finiteG _k suffices.     

A constructive method for uniform approximation by means of integrated Lagrange interpolation polynomials in the spaceC 1[a,b]

Пусть интерполяционные уз лыa <x ₁ <x ₂ < ... <х _n <b являются корнямиn-го полинома системы полиномов {w _n(x)} _n ^∞ =1, ортогонально й с весомρ(х), 0 < ρ(х) ∈L[a, b], причем 1/ρ(x) ∈L[a, b]. Доказано, что еслиf(х) ∈С ¹ [a, b], то проинтегрированн ые полиномы $$Q_n (x) = \smallint _a^x L_{n - 1} (f',t)dt + f(a)$$ интерполяционных по линомов Лагранжа $$L_{n - 1} (f,x) = \sum\limits_{k = 1}^n {f'(x_k )\frac{{\omega _n (x)}}{{\omega '_n (x_k )(x - x_k )}}}$$ порядкаn?1 функцииf′(x) сходятся равномерно к функцииf(х) в замкнуто м интервале [а,b]. Во второй части стать и, где вместо условия 1/ρ(х) ∈L[a, b] предполагается, чтоρ(х) ∈С ²[а, b],ρ(х) > 0,ρ′ (х) > 0, доказываются подобные утверждени я для проинтегрированных интерполяционных по линомов Лагранжа и для прибли жений рациональными дробя ми. В работе даются неулу чшаемые порядковые о ценки и описываются примене ния полученных результа тов в теории дифферен циальных уравнений.