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121.
We present Doppler resolution limited spectra of the P(J) and R(J) multiplets for J ≦ 10 of the 10-μm CO stretch band of 12CD316OH using a tunable diode laser. Relative frequencies within the multiplets accurate to ±0.0002–0.0005 cm?1 are obtained, but no absolute frequencies are given. We are able to assign most of the hindered rotation and K substructure in these multiplets. The assignments are based on analyses of Stark-difference spectra combined with the ground-state microwave data and the intensity variations which are expected theoretically. The ground and excited state A, K = 1 asymmetry splitting parameters are measured to be δ1″ = (8.5450 ± 0.0080) × 10?3cm?1 and δ1′ = (9.7706 ± 0.0080) × 10?3cm?1, respectively. The ground-state value agrees well with the microwave results. A rapid-scan system for recording data and a computer-aided technique for calibrating and plotting the spectra are described. 相似文献
122.
123.
G. Peters 《Fresenius' Journal of Analytical Chemistry》1967,232(2):132
Ohne Zusammenfassung 相似文献
124.
125.
Gisela Peters 《Fresenius' Journal of Analytical Chemistry》1966,217(6):453-454
Ohne Zusammenfassung 相似文献
126.
Aubert B Barate R Boutigny D Couderc F Karyotakis Y Lees JP Poireau V Tisserand V Zghiche A Grauges-Pous E Palano A Pompili A Chen JC Qi ND Rong G Wang P Zhu YS Eigen G Ofte I Stugu B Abrams GS Borgland AW Breon AB Brown DN Button-Shafer J Cahn RN Charles E Day CT Gill MS Gritsan AV Groysman Y Jacobsen RG Kadel RW Kadyk J Kerth LT Kolomensky YG Kukartsev G Lynch G Mir LM Oddone PJ Orimoto TJ Pripstein M Roe NA Ronan MT Wenzel WA Barrett M Ford KE Harrison TJ Hart AJ Hawkes CM Morgan SE 《Physical review letters》2005,94(13):131801
We search for the decay B0-->rho(0)rho(0) in a data sample of about 227x10(6) Upsilon(4S)-->BB decays collected with the BABAR detector at the PEP-II asymmetric-energy e(+)e(-) collider at SLAC. We find no significant signal and set an upper limit of 1.1x10(-6) at 90% C.L. on the branching fraction. As a result, the uncertainty due to penguin contributions on the Cabibbo-Kobayashi-Maskawa unitarity angle alpha measured in B-->rhorho decays is decreased to 11 degrees at 68% C.L. 相似文献
127.
We experimentally demonstrate the first quantum system entangled in every degree of freedom (hyperentangled). Using pairs of photons produced in spontaneous parametric down-conversion, we verify entanglement by observing a Bell-type inequality violation in each degree of freedom: polarization, spatial mode, and time energy. We also produce and characterize maximally hyperentangled states and novel states simultaneously exhibiting both quantum and classical correlations. Finally, we report the tomography of a 2 x 2 x 3 x 3 system (36-dimensional Hilbert space), which we believe is the first reported photonic entangled system of this size to be so characterized. 相似文献
128.
Peters NA Altepeter JB Branning D Jeffrey ER Wei TC Kwiat PG 《Physical review letters》2004,92(13):133601
Using correlated photons from parametric down-conversion, we extend the boundaries of experimentally accessible two-qubit Hilbert space. Specifically, we have created and characterized maximally entangled mixed states that lie above the Werner boundary in the linear entropy-tangle plane. In addition, we demonstrate that such states can be efficiently concentrated, simultaneously increasing both the purity and the degree of entanglement. We investigate a previously unsuspected sensitivity imbalance in common state measures, i.e., the tangle, linear entropy, and fidelity. 相似文献
129.
This paper describes the reductive hydrogenolysis of a low-spin (S = 1/2) iron(III) imide. Pseudotetrahedral [PhBP3]FeIIIN-p-tolyl is reduced by hydrogen at ambient temperature and pressure in benzene solution. The reduction appears to proceed in a stepwise fashion. An intermediate S = 2 iron(II) anilide, [PhBP3]Fe(N(H)-p-tolyl), is observed and has been independently generated and structurally characterized. Prolonged hydrogenolysis in benzene results in the complete hydrogenolysis of the Fe-N linkage to release H2N-p-tolyl. The major iron-containing product formed from this step is the diamagnetic cyclohexadienyl complex, [PhBP3]Fe(eta5-cyclohexadienyl), which has also been independently prepared and structurally characterized. Evidence is presented to suggest that the final [PhBP3]Fe(eta5-cyclohexadienyl) product is formed via benzene insertion into a reactive [PhBP3]FeII-H intermediate. 相似文献
130.
Lay OP Dubovitsky S Peters RD Burger JP Ahn SW Steier WH Fetterman HR Chang Y 《Optics letters》2003,28(11):890-892
The Modulation Sideband Technology for Absolute Ranging (MSTAR) sensor permits absolute distance measurement with subnanometer accuracy, an improvement of 4 orders of magnitude over current techniques. The system uses fast phase modulators to resolve the integer cycle ambiguity of standard interferometers. The concept is described and demonstrated over target distances up to 1 m. The design can be extended to kilometer-scale separations. 相似文献